Electrical conductivity of solid solution of Co(II)-Zn dihydrophosphate and its thermolysis products
Dependence of the specific electrical conductivity value of the solid solution with composition Co₁-xZnx(H₂PO₄)₂•H₂O(0 < x < 1.0) and products of its partial or complete dehydration from temperature and duration of heat treatment has been investigated. It has been established that they...
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| Published in: | Functional Materials |
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| Date: | 2015 |
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| Format: | Article |
| Language: | English |
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НТК «Інститут монокристалів» НАН України
2015
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| Online Access: | https://nasplib.isofts.kiev.ua/handle/123456789/119376 |
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| Journal Title: | Digital Library of Periodicals of National Academy of Sciences of Ukraine |
| Cite this: | Electrical conductivity of solid solution of Co(II)-Zn dihydrophosphate and its thermolysis products / N.M. Antraptseva, N.V. Solod, V.A. Povshuk // Functional Materials. — 2015. — Т. 22, № 3. — С. 322-326. — Бібліогр.: 8 назв. — англ. |
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Digital Library of Periodicals of National Academy of Sciences of Ukraine| _version_ | 1862713656323604480 |
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| author | Antraptseva, N.M. Solod, N.V. Povshuk, V.A. |
| author_facet | Antraptseva, N.M. Solod, N.V. Povshuk, V.A. |
| citation_txt | Electrical conductivity of solid solution of Co(II)-Zn dihydrophosphate and its thermolysis products / N.M. Antraptseva, N.V. Solod, V.A. Povshuk // Functional Materials. — 2015. — Т. 22, № 3. — С. 322-326. — Бібліогр.: 8 назв. — англ. |
| collection | DSpace DC |
| container_title | Functional Materials |
| description | Dependence of the specific electrical conductivity value of the solid solution with composition Co₁-xZnx(H₂PO₄)₂•H₂O(0 < x < 1.0) and products of its partial or complete dehydration from temperature and duration of heat treatment has been investigated. It has been established that they have considerable proton conductivity (from 1.01•10⁻⁰² - 1.18•10⁻² Ohm⁻¹cm⁻¹ to 7.51•10⁻³ - 9.57•10⁻³ Ohm⁻¹cm⁻¹) in a wide temperature range (80-270°C). The main contribution to their proton conductivity has made mobile protons of the phosphate anion P-OH groups and free phosphoric acid protons, which have produced in the intermediate thermolysis products according to PMR and ³¹P NMR spectrum analysis of Co(II)-Zn dihydrophosphates heat treatment products. Contribution of crystal water protons is minimal.
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| first_indexed | 2025-12-07T17:45:34Z |
| format | Article |
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| id | nasplib_isofts_kiev_ua-123456789-119376 |
| institution | Digital Library of Periodicals of National Academy of Sciences of Ukraine |
| issn | 1027-5495 |
| language | English |
| last_indexed | 2025-12-07T17:45:34Z |
| publishDate | 2015 |
| publisher | НТК «Інститут монокристалів» НАН України |
| record_format | dspace |
| spelling | Antraptseva, N.M. Solod, N.V. Povshuk, V.A. 2017-06-06T17:20:48Z 2017-06-06T17:20:48Z 2015 Electrical conductivity of solid solution of Co(II)-Zn dihydrophosphate and its thermolysis products / N.M. Antraptseva, N.V. Solod, V.A. Povshuk // Functional Materials. — 2015. — Т. 22, № 3. — С. 322-326. — Бібліогр.: 8 назв. — англ. 1027-5495 DOI: http://dx.doi.org/10.15407/fm22.03.322 https://nasplib.isofts.kiev.ua/handle/123456789/119376 Dependence of the specific electrical conductivity value of the solid solution with composition Co₁-xZnx(H₂PO₄)₂•H₂O(0 < x < 1.0) and products of its partial or complete dehydration from temperature and duration of heat treatment has been investigated. It has been established that they have considerable proton conductivity (from 1.01•10⁻⁰² - 1.18•10⁻² Ohm⁻¹cm⁻¹ to 7.51•10⁻³ - 9.57•10⁻³ Ohm⁻¹cm⁻¹) in a wide temperature range (80-270°C). The main contribution to their proton conductivity has made mobile protons of the phosphate anion P-OH groups and free phosphoric acid protons, which have produced in the intermediate thermolysis products according to PMR and ³¹P NMR spectrum analysis of Co(II)-Zn dihydrophosphates heat treatment products. Contribution of crystal water protons is minimal. en НТК «Інститут монокристалів» НАН України Functional Materials Characterization and properties Electrical conductivity of solid solution of Co(II)-Zn dihydrophosphate and its thermolysis products Article published earlier |
| spellingShingle | Electrical conductivity of solid solution of Co(II)-Zn dihydrophosphate and its thermolysis products Antraptseva, N.M. Solod, N.V. Povshuk, V.A. Characterization and properties |
| title | Electrical conductivity of solid solution of Co(II)-Zn dihydrophosphate and its thermolysis products |
| title_full | Electrical conductivity of solid solution of Co(II)-Zn dihydrophosphate and its thermolysis products |
| title_fullStr | Electrical conductivity of solid solution of Co(II)-Zn dihydrophosphate and its thermolysis products |
| title_full_unstemmed | Electrical conductivity of solid solution of Co(II)-Zn dihydrophosphate and its thermolysis products |
| title_short | Electrical conductivity of solid solution of Co(II)-Zn dihydrophosphate and its thermolysis products |
| title_sort | electrical conductivity of solid solution of co(ii)-zn dihydrophosphate and its thermolysis products |
| topic | Characterization and properties |
| topic_facet | Characterization and properties |
| url | https://nasplib.isofts.kiev.ua/handle/123456789/119376 |
| work_keys_str_mv | AT antraptsevanm electricalconductivityofsolidsolutionofcoiizndihydrophosphateanditsthermolysisproducts AT solodnv electricalconductivityofsolidsolutionofcoiizndihydrophosphateanditsthermolysisproducts AT povshukva electricalconductivityofsolidsolutionofcoiizndihydrophosphateanditsthermolysisproducts |