Low-temperature dynamics of matrix isolated methane molecules in fullerite C₆₀. The heat capacity, isotope effects
The heat capacity of the interstitial solid solution (CH₄)₀.₄C₆₀ has been investigated in the temperature interval 1.4–120 K. The contribution of CH4 molecules to the heat capacity of the solution has been separated. The contributions of CH4 and CD4 molecules to the heat capacity of the solutions (C...
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| Veröffentlicht in: | Физика низких температур |
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| Datum: | 2014 |
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Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України
2014
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| Zitieren: | Low-temperature dynamics of matrix isolated methane molecules in fullerite C₆₀. The heat capacity, isotope effects / M.I. Bagatskii, V.G. Manzhelii, V.V. Sumarokov, A.V. Dolbin, M.S. Barabashko, B. Sundqvist // Физика низких температур. — 2014. — Т. 40, № 8. — С. 873-880. — Бібліогр.: 43 назв. — англ. |
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Bagatskii, M.I. Manzhelii, V.G. Sumarokov, V.V. Dolbin, A.V. Barabashko, M.S. Sundqvist, B. 2017-06-07T15:15:31Z 2017-06-07T15:15:31Z 2014 Low-temperature dynamics of matrix isolated methane molecules in fullerite C₆₀. The heat capacity, isotope effects / M.I. Bagatskii, V.G. Manzhelii, V.V. Sumarokov, A.V. Dolbin, M.S. Barabashko, B. Sundqvist // Физика низких температур. — 2014. — Т. 40, № 8. — С. 873-880. — Бібліогр.: 43 назв. — англ. 0132-6414 PACS 65.40.Ba, 65.80.–g, 66.35.+a, 81.05.ub https://nasplib.isofts.kiev.ua/handle/123456789/119588 The heat capacity of the interstitial solid solution (CH₄)₀.₄C₆₀ has been investigated in the temperature interval 1.4–120 K. The contribution of CH4 molecules to the heat capacity of the solution has been separated. The contributions of CH4 and CD4 molecules to the heat capacity of the solutions (CH₄)₀.₄C₆₀ and (CD₄)₀.₄C₆₀ have been compared. It is found that above 90 K the character of the rotational motion of CH4 and CD4 molecules changes from libration to hindered rotation. In the interval 14–35 K the heat capacities of CH₄ and CD₄ molecules are satisfactorily described by contributions of the translational and libration vibrations, as well as the tunnel rotation for the equilibrium distribution of the nuclear spin species. The isotope effect is due to mainly, the difference in the frequencies of local translational and libration vibrations of molecules CH₄ and CD₄. The contribution of the tunnel rotation of the CH₄ and CD₄ molecules to the heat capacity is dominant below 8 K. The isotopic effect is caused by the difference between both the conversion rates and the rotational spectra of the nuclear spin species of CH₄ and CD₄ molecules. The conversion rate of CH₄ molecules is several times lower than that of CD₄ ones. Weak features observed in the curves of temperature dependencies of the heat capacity of CH₄ and CD₄ molecules near 6 and 8 K, respectively, are most likely a manifestation of first-order polyamorphic phase transitions in the orientational glasses of these solutions. The authors are indebted to A.I. Prokvatilov for a fruitful discussion and to G.E. Gadd, S. Moricca, and D. Cassidy for samples preparation. en Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України Физика низких температур Физические свойства криокристаллов Low-temperature dynamics of matrix isolated methane molecules in fullerite C₆₀. The heat capacity, isotope effects Article published earlier |
| institution |
Digital Library of Periodicals of National Academy of Sciences of Ukraine |
| collection |
DSpace DC |
| title |
Low-temperature dynamics of matrix isolated methane molecules in fullerite C₆₀. The heat capacity, isotope effects |
| spellingShingle |
Low-temperature dynamics of matrix isolated methane molecules in fullerite C₆₀. The heat capacity, isotope effects Bagatskii, M.I. Manzhelii, V.G. Sumarokov, V.V. Dolbin, A.V. Barabashko, M.S. Sundqvist, B. Физические свойства криокристаллов |
| title_short |
Low-temperature dynamics of matrix isolated methane molecules in fullerite C₆₀. The heat capacity, isotope effects |
| title_full |
Low-temperature dynamics of matrix isolated methane molecules in fullerite C₆₀. The heat capacity, isotope effects |
| title_fullStr |
Low-temperature dynamics of matrix isolated methane molecules in fullerite C₆₀. The heat capacity, isotope effects |
| title_full_unstemmed |
Low-temperature dynamics of matrix isolated methane molecules in fullerite C₆₀. The heat capacity, isotope effects |
| title_sort |
low-temperature dynamics of matrix isolated methane molecules in fullerite c₆₀. the heat capacity, isotope effects |
| author |
Bagatskii, M.I. Manzhelii, V.G. Sumarokov, V.V. Dolbin, A.V. Barabashko, M.S. Sundqvist, B. |
| author_facet |
Bagatskii, M.I. Manzhelii, V.G. Sumarokov, V.V. Dolbin, A.V. Barabashko, M.S. Sundqvist, B. |
| topic |
Физические свойства криокристаллов |
| topic_facet |
Физические свойства криокристаллов |
| publishDate |
2014 |
| language |
English |
| container_title |
Физика низких температур |
| publisher |
Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України |
| format |
Article |
| description |
The heat capacity of the interstitial solid solution (CH₄)₀.₄C₆₀ has been investigated in the temperature interval 1.4–120 K. The contribution of CH4 molecules to the heat capacity of the solution has been separated. The contributions of CH4 and CD4 molecules to the heat capacity of the solutions (CH₄)₀.₄C₆₀ and (CD₄)₀.₄C₆₀ have been compared. It is found that above 90 K the character of the rotational motion of CH4 and CD4 molecules changes from libration to hindered rotation. In the interval 14–35 K the heat capacities of CH₄ and CD₄ molecules are satisfactorily described by contributions of the translational and libration vibrations, as well as the tunnel rotation for the equilibrium distribution of the nuclear spin species. The isotope effect is due to mainly, the difference in the frequencies of local translational and libration vibrations of molecules CH₄ and CD₄. The contribution of the tunnel rotation of the CH₄ and CD₄ molecules to the heat capacity is dominant below 8 K. The isotopic effect is caused by the difference between both the conversion rates and the rotational spectra of the nuclear spin species of CH₄ and CD₄ molecules. The conversion rate of CH₄ molecules is several times lower than that of CD₄ ones. Weak features observed in the curves of temperature dependencies of the heat capacity of CH₄ and CD₄ molecules near 6 and 8 K, respectively, are most likely a manifestation of first-order polyamorphic phase transitions in the orientational glasses of these solutions.
|
| issn |
0132-6414 |
| url |
https://nasplib.isofts.kiev.ua/handle/123456789/119588 |
| citation_txt |
Low-temperature dynamics of matrix isolated methane molecules in fullerite C₆₀. The heat capacity, isotope effects / M.I. Bagatskii, V.G. Manzhelii, V.V. Sumarokov, A.V. Dolbin, M.S. Barabashko, B. Sundqvist // Физика низких температур. — 2014. — Т. 40, № 8. — С. 873-880. — Бібліогр.: 43 назв. — англ. |
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2025-12-07T16:15:48Z |
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