Helium atom in an external electric field: Exact diagonalization

An exact diagonalization method is applied to solve the quantum-mechanical problem of spinless helium atom in an external electric field of arbitrary magnitude. The basis set for two-electron problem is built from different pair combinations ψnalama(αra)ψnblbmb(αrb) of orthonormalized single-particl...

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Veröffentlicht in:Физика низких температур
Datum:2014
Hauptverfasser: Antsygina, T.N., Chishko, K.A.
Format: Artikel
Sprache:English
Veröffentlicht: Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України 2014
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Online Zugang:https://nasplib.isofts.kiev.ua/handle/123456789/119653
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Zitieren:Helium atom in an external electric field: Exact diagonalization / T.N. Antsygina, K.A. Chishko // Физика низких температур. — 2014. — Т. 40, № 9. — С. 1035-1044. — Бібліогр.: 50 назв. — англ.

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Digital Library of Periodicals of National Academy of Sciences of Ukraine
id nasplib_isofts_kiev_ua-123456789-119653
record_format dspace
spelling Antsygina, T.N.
Chishko, K.A.
2017-06-07T18:59:00Z
2017-06-07T18:59:00Z
2014
Helium atom in an external electric field: Exact diagonalization / T.N. Antsygina, K.A. Chishko // Физика низких температур. — 2014. — Т. 40, № 9. — С. 1035-1044. — Бібліогр.: 50 назв. — англ.
0132-6414
PACS 31.15.ac
https://nasplib.isofts.kiev.ua/handle/123456789/119653
An exact diagonalization method is applied to solve the quantum-mechanical problem of spinless helium atom in an external electric field of arbitrary magnitude. The basis set for two-electron problem is built from different pair combinations ψnalama(αra)ψnblbmb(αrb) of orthonormalized single-particle hydrogen-like wave functions ψnml(r) belonging to any possibly bound states of the individual a- and b-electrons in the Coulomb central field renormalized by the scale parameter α > 0. Within the selected basis the matrix elements of the total Hamiltonian allows an exact analytical representation in the form of finite numerical sums. The diagonalization procedure is performed by Jacobi algorithm for N×N square Hermitian matrix built on the basis of dimension N = 25. The systematics and the numerical values of the low-lying energy levels at zero field are in good agreement with known experimental data. The field dependences of low-lying levels (Stark effect) and polarizability in the ground state of helium atom are presented. It is shown that even extremely high external fields lead only to shifting or splitting of existing low levels, without disturbance of their systematics. Typically, no new lowenergy excitation can be created under external electric field of moderate intensity. Radical reconstruction in spectrum of individual helium atoms can be expected in condensed helium phases where each atom is deeply affected by interaction fields from neighbors. This result should be taken into account at interpretation of electrodynamic experiments on superfluid helium.
en
Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України
Физика низких температур
Квантовые жидкости и квантовые кpисталлы
Helium atom in an external electric field: Exact diagonalization
Article
published earlier
institution Digital Library of Periodicals of National Academy of Sciences of Ukraine
collection DSpace DC
title Helium atom in an external electric field: Exact diagonalization
spellingShingle Helium atom in an external electric field: Exact diagonalization
Antsygina, T.N.
Chishko, K.A.
Квантовые жидкости и квантовые кpисталлы
title_short Helium atom in an external electric field: Exact diagonalization
title_full Helium atom in an external electric field: Exact diagonalization
title_fullStr Helium atom in an external electric field: Exact diagonalization
title_full_unstemmed Helium atom in an external electric field: Exact diagonalization
title_sort helium atom in an external electric field: exact diagonalization
author Antsygina, T.N.
Chishko, K.A.
author_facet Antsygina, T.N.
Chishko, K.A.
topic Квантовые жидкости и квантовые кpисталлы
topic_facet Квантовые жидкости и квантовые кpисталлы
publishDate 2014
language English
container_title Физика низких температур
publisher Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України
format Article
description An exact diagonalization method is applied to solve the quantum-mechanical problem of spinless helium atom in an external electric field of arbitrary magnitude. The basis set for two-electron problem is built from different pair combinations ψnalama(αra)ψnblbmb(αrb) of orthonormalized single-particle hydrogen-like wave functions ψnml(r) belonging to any possibly bound states of the individual a- and b-electrons in the Coulomb central field renormalized by the scale parameter α > 0. Within the selected basis the matrix elements of the total Hamiltonian allows an exact analytical representation in the form of finite numerical sums. The diagonalization procedure is performed by Jacobi algorithm for N×N square Hermitian matrix built on the basis of dimension N = 25. The systematics and the numerical values of the low-lying energy levels at zero field are in good agreement with known experimental data. The field dependences of low-lying levels (Stark effect) and polarizability in the ground state of helium atom are presented. It is shown that even extremely high external fields lead only to shifting or splitting of existing low levels, without disturbance of their systematics. Typically, no new lowenergy excitation can be created under external electric field of moderate intensity. Radical reconstruction in spectrum of individual helium atoms can be expected in condensed helium phases where each atom is deeply affected by interaction fields from neighbors. This result should be taken into account at interpretation of electrodynamic experiments on superfluid helium.
issn 0132-6414
url https://nasplib.isofts.kiev.ua/handle/123456789/119653
citation_txt Helium atom in an external electric field: Exact diagonalization / T.N. Antsygina, K.A. Chishko // Физика низких температур. — 2014. — Т. 40, № 9. — С. 1035-1044. — Бібліогр.: 50 назв. — англ.
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AT chishkoka heliumatominanexternalelectricfieldexactdiagonalization
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