Simplified computations of spin excitations in high-spin carbon nanoclusters and related systems

Spin excitation spectra for possible molecule-based magnetic structures are evaluated semiempirically. A simplest spin-flip model with singly-excited configurations (SF-CIS) is used. While only a small amount of electron correlation is captured by the SF-CIS scheme, it turns out to be practically us...

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Veröffentlicht in:Functional Materials
Datum:2015
1. Verfasser: Luzanov, A.V.
Format: Artikel
Sprache:English
Veröffentlicht: НТК «Інститут монокристалів» НАН України 2015
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Online Zugang:https://nasplib.isofts.kiev.ua/handle/123456789/119707
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Назва журналу:Digital Library of Periodicals of National Academy of Sciences of Ukraine
Zitieren:Simplified computations of spin excitations in high-spin carbon nanoclusters and related systems / A.V. Luzanov // Functional Materials. — 2015. — Т. 22, № 4. — С. 514-523. — Бібліогр.: 61 назв. — англ.

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Digital Library of Periodicals of National Academy of Sciences of Ukraine
id nasplib_isofts_kiev_ua-123456789-119707
record_format dspace
spelling Luzanov, A.V.
2017-06-08T07:23:21Z
2017-06-08T07:23:21Z
2015
Simplified computations of spin excitations in high-spin carbon nanoclusters and related systems / A.V. Luzanov // Functional Materials. — 2015. — Т. 22, № 4. — С. 514-523. — Бібліогр.: 61 назв. — англ.
1027-5495
DOI: dx.doi.org/10.15407/fm22.04.514
https://nasplib.isofts.kiev.ua/handle/123456789/119707
Spin excitation spectra for possible molecule-based magnetic structures are evaluated semiempirically. A simplest spin-flip model with singly-excited configurations (SF-CIS) is used. While only a small amount of electron correlation is captured by the SF-CIS scheme, it turns out to be practically useful tool for computing quasi-magnon spectra in large polyradicals. We study examples of three different structural types (graphene nanoribbon with methylene edges, triangulene and Mataga-type model organic ferromagnet). We demonstrate that these systems show different behavior of the spin excitation spectra and different spin heat capacity temperature dependences. It is also shown that the same SF-CIS technique can be useful for describing high-spin states in nanodiamonds with defects.
en
НТК «Інститут монокристалів» НАН України
Functional Materials
Modeling and simulation
Simplified computations of spin excitations in high-spin carbon nanoclusters and related systems
Article
published earlier
institution Digital Library of Periodicals of National Academy of Sciences of Ukraine
collection DSpace DC
title Simplified computations of spin excitations in high-spin carbon nanoclusters and related systems
spellingShingle Simplified computations of spin excitations in high-spin carbon nanoclusters and related systems
Luzanov, A.V.
Modeling and simulation
title_short Simplified computations of spin excitations in high-spin carbon nanoclusters and related systems
title_full Simplified computations of spin excitations in high-spin carbon nanoclusters and related systems
title_fullStr Simplified computations of spin excitations in high-spin carbon nanoclusters and related systems
title_full_unstemmed Simplified computations of spin excitations in high-spin carbon nanoclusters and related systems
title_sort simplified computations of spin excitations in high-spin carbon nanoclusters and related systems
author Luzanov, A.V.
author_facet Luzanov, A.V.
topic Modeling and simulation
topic_facet Modeling and simulation
publishDate 2015
language English
container_title Functional Materials
publisher НТК «Інститут монокристалів» НАН України
format Article
description Spin excitation spectra for possible molecule-based magnetic structures are evaluated semiempirically. A simplest spin-flip model with singly-excited configurations (SF-CIS) is used. While only a small amount of electron correlation is captured by the SF-CIS scheme, it turns out to be practically useful tool for computing quasi-magnon spectra in large polyradicals. We study examples of three different structural types (graphene nanoribbon with methylene edges, triangulene and Mataga-type model organic ferromagnet). We demonstrate that these systems show different behavior of the spin excitation spectra and different spin heat capacity temperature dependences. It is also shown that the same SF-CIS technique can be useful for describing high-spin states in nanodiamonds with defects.
issn 1027-5495
url https://nasplib.isofts.kiev.ua/handle/123456789/119707
citation_txt Simplified computations of spin excitations in high-spin carbon nanoclusters and related systems / A.V. Luzanov // Functional Materials. — 2015. — Т. 22, № 4. — С. 514-523. — Бібліогр.: 61 назв. — англ.
work_keys_str_mv AT luzanovav simplifiedcomputationsofspinexcitationsinhighspincarbonnanoclustersandrelatedsystems
first_indexed 2025-11-28T09:24:50Z
last_indexed 2025-11-28T09:24:50Z
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