Raman spectra of Ag- and Cu- photodoped chalcogenide films

Raman spectra of the chalcogenide vitreous layers (As₄₀S₆₀, As₄₀S₄₀Se₂₀, As₄₀Se₆₀ ) non-doped and photodoped by Ag, Cu were measured. The spectra were analyzed in terms of a molecular model. It was ascertained, that for the spectra of photodoped As₄₀S₆₀, As₄₀S₄₀Se₂₀ layers, the shift of the main ban...

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Veröffentlicht in:Semiconductor Physics Quantum Electronics & Optoelectronics
Datum:1999
Hauptverfasser: Stronski, A.V., Vlcek, M., Stetsun, A.I., Sklenar, A., Shepeliavyi, P.E.
Format: Artikel
Sprache:Englisch
Veröffentlicht: Інститут фізики напівпровідників імені В.Є. Лашкарьова НАН України 1999
Online Zugang:https://nasplib.isofts.kiev.ua/handle/123456789/119862
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Zitieren:Raman spectra of Ag- and Cu- photodoped chalcogenide films / A.V. Stronski, M. Vlcek, A.I. Stetsun, A. Sklenar, P.E. Shepeliavyi // Semiconductor Physics Quantum Electronics & Optoelectronics. — 1999. — Т. 2, № 1. — С. 63-68. — Бібліогр.: 37 назв. — англ.

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author Stronski, A.V.
Vlcek, M.
Stetsun, A.I.
Sklenar, A.
Shepeliavyi, P.E.
author_facet Stronski, A.V.
Vlcek, M.
Stetsun, A.I.
Sklenar, A.
Shepeliavyi, P.E.
citation_txt Raman spectra of Ag- and Cu- photodoped chalcogenide films / A.V. Stronski, M. Vlcek, A.I. Stetsun, A. Sklenar, P.E. Shepeliavyi // Semiconductor Physics Quantum Electronics & Optoelectronics. — 1999. — Т. 2, № 1. — С. 63-68. — Бібліогр.: 37 назв. — англ.
collection DSpace DC
container_title Semiconductor Physics Quantum Electronics & Optoelectronics
description Raman spectra of the chalcogenide vitreous layers (As₄₀S₆₀, As₄₀S₄₀Se₂₀, As₄₀Se₆₀ ) non-doped and photodoped by Ag, Cu were measured. The spectra were analyzed in terms of a molecular model. It was ascertained, that for the spectra of photodoped As₄₀S₆₀, As₄₀S₄₀Se₂₀ layers, the shift of the main bands to the high frequency side and the appearance of the additional scattering bands in the low frequency spectral range are characteristic features. For the spectra of photodoped As₄₀S₆₀ layers, such shift and significant increase in scattering were not observed. Variations in the Raman spectra with photodoping by Ag or Cu are consistent with the supposition concerning normal covalent and coordinative bond formation between metal additives and chalcogen atoms.
first_indexed 2025-12-07T20:35:15Z
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institution Digital Library of Periodicals of National Academy of Sciences of Ukraine
issn 1560-8034
language English
last_indexed 2025-12-07T20:35:15Z
publishDate 1999
publisher Інститут фізики напівпровідників імені В.Є. Лашкарьова НАН України
record_format dspace
spelling Stronski, A.V.
Vlcek, M.
Stetsun, A.I.
Sklenar, A.
Shepeliavyi, P.E.
2017-06-10T07:47:02Z
2017-06-10T07:47:02Z
1999
Raman spectra of Ag- and Cu- photodoped chalcogenide films / A.V. Stronski, M. Vlcek, A.I. Stetsun, A. Sklenar, P.E. Shepeliavyi // Semiconductor Physics Quantum Electronics & Optoelectronics. — 1999. — Т. 2, № 1. — С. 63-68. — Бібліогр.: 37 назв. — англ.
1560-8034
PACS 78.30, 78.66, 82.20C
https://nasplib.isofts.kiev.ua/handle/123456789/119862
Raman spectra of the chalcogenide vitreous layers (As₄₀S₆₀, As₄₀S₄₀Se₂₀, As₄₀Se₆₀ ) non-doped and photodoped by Ag, Cu were measured. The spectra were analyzed in terms of a molecular model. It was ascertained, that for the spectra of photodoped As₄₀S₆₀, As₄₀S₄₀Se₂₀ layers, the shift of the main bands to the high frequency side and the appearance of the additional scattering bands in the low frequency spectral range are characteristic features. For the spectra of photodoped As₄₀S₆₀ layers, such shift and significant increase in scattering were not observed. Variations in the Raman spectra with photodoping by Ag or Cu are consistent with the supposition concerning normal covalent and coordinative bond formation between metal additives and chalcogen atoms.
The authors wish to express their gratitude to Prof. I.Z. Indutnyi and Dr. A.A. Kudryavtsev for valuable discussion and critical reading the manuscript.
en
Інститут фізики напівпровідників імені В.Є. Лашкарьова НАН України
Semiconductor Physics Quantum Electronics & Optoelectronics
Raman spectra of Ag- and Cu- photodoped chalcogenide films
Article
published earlier
spellingShingle Raman spectra of Ag- and Cu- photodoped chalcogenide films
Stronski, A.V.
Vlcek, M.
Stetsun, A.I.
Sklenar, A.
Shepeliavyi, P.E.
title Raman spectra of Ag- and Cu- photodoped chalcogenide films
title_full Raman spectra of Ag- and Cu- photodoped chalcogenide films
title_fullStr Raman spectra of Ag- and Cu- photodoped chalcogenide films
title_full_unstemmed Raman spectra of Ag- and Cu- photodoped chalcogenide films
title_short Raman spectra of Ag- and Cu- photodoped chalcogenide films
title_sort raman spectra of ag- and cu- photodoped chalcogenide films
url https://nasplib.isofts.kiev.ua/handle/123456789/119862
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AT stetsunai ramanspectraofagandcuphotodopedchalcogenidefilms
AT sklenara ramanspectraofagandcuphotodopedchalcogenidefilms
AT shepeliavyipe ramanspectraofagandcuphotodopedchalcogenidefilms