Luminescent temperature sensor based on [Ru(bpy)₃]²⁺ incorporated into chitosan

A novel luminescent temperature sensor using ruthenium(II)-tris(2,2´-bipyridil) ([Ru(bpy)₃]²⁺) incorporated into chitosan polymer matrix was developed. The sensor exhibits completely reversible and stable luminescent response (λ exc = 455 nm, λ em = 605 nm), strong temperature sensitivity (–2.0 %/°C...

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Бібліографічні деталі
Опубліковано в: :Functional Materials
Дата:2013
Автори: Tsvirko, M., Tkaczyk, S., Kozak, M., Kalota, B.
Формат: Стаття
Мова:Англійська
Опубліковано: НТК «Інститут монокристалів» НАН України 2013
Теми:
Онлайн доступ:https://nasplib.isofts.kiev.ua/handle/123456789/119962
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Назва журналу:Digital Library of Periodicals of National Academy of Sciences of Ukraine
Цитувати:Luminescent temperature sensor based on [Ru(bpy)₃]²⁺ incorporated into chitosan / M. Tsvirko, S. Tkaczyk, M. Kozak, B. Kalota // Functional Materials. — 2013. — Т. 20, № 1. — С. 127-132. — Бібліогр.: 36 назв. — англ.

Репозитарії

Digital Library of Periodicals of National Academy of Sciences of Ukraine
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author Tsvirko, M.
Tkaczyk, S.
Kozak, M.
Kalota, B.
author_facet Tsvirko, M.
Tkaczyk, S.
Kozak, M.
Kalota, B.
citation_txt Luminescent temperature sensor based on [Ru(bpy)₃]²⁺ incorporated into chitosan / M. Tsvirko, S. Tkaczyk, M. Kozak, B. Kalota // Functional Materials. — 2013. — Т. 20, № 1. — С. 127-132. — Бібліогр.: 36 назв. — англ.
collection DSpace DC
container_title Functional Materials
description A novel luminescent temperature sensor using ruthenium(II)-tris(2,2´-bipyridil) ([Ru(bpy)₃]²⁺) incorporated into chitosan polymer matrix was developed. The sensor exhibits completely reversible and stable luminescent response (λ exc = 455 nm, λ em = 605 nm), strong temperature sensitivity (–2.0 %/°C), significant luminescence intensity decrease (~10×) in the range of 25–75°C, and stable construction. Ruthenium(II) complex oxygen sensitivity was avoided by use of matrix (chitosan) with low oxygen permeability coefficient. In the absence of oxygen the sensor shows a little higher accuracy and stability of luminescence response than under oxygen conditions. Moreover, this sensor, due to biocompatibility of the used ingredients and the emission in the red VIS-region, which is transparent for tissues, is promising for use in biological applications.
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last_indexed 2025-11-25T12:22:55Z
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publisher НТК «Інститут монокристалів» НАН України
record_format dspace
spelling Tsvirko, M.
Tkaczyk, S.
Kozak, M.
Kalota, B.
2017-06-10T13:30:44Z
2017-06-10T13:30:44Z
2013
Luminescent temperature sensor based on [Ru(bpy)₃]²⁺ incorporated into chitosan / M. Tsvirko, S. Tkaczyk, M. Kozak, B. Kalota // Functional Materials. — 2013. — Т. 20, № 1. — С. 127-132. — Бібліогр.: 36 назв. — англ.
1027-5495
DOI: dx.doi.org/10.15407/fm20.01.127
https://nasplib.isofts.kiev.ua/handle/123456789/119962
A novel luminescent temperature sensor using ruthenium(II)-tris(2,2´-bipyridil) ([Ru(bpy)₃]²⁺) incorporated into chitosan polymer matrix was developed. The sensor exhibits completely reversible and stable luminescent response (λ exc = 455 nm, λ em = 605 nm), strong temperature sensitivity (–2.0 %/°C), significant luminescence intensity decrease (~10×) in the range of 25–75°C, and stable construction. Ruthenium(II) complex oxygen sensitivity was avoided by use of matrix (chitosan) with low oxygen permeability coefficient. In the absence of oxygen the sensor shows a little higher accuracy and stability of luminescence response than under oxygen conditions. Moreover, this sensor, due to biocompatibility of the used ingredients and the emission in the red VIS-region, which is transparent for tissues, is promising for use in biological applications.
en
НТК «Інститут монокристалів» НАН України
Functional Materials
Devices and instruments
Luminescent temperature sensor based on [Ru(bpy)₃]²⁺ incorporated into chitosan
Article
published earlier
spellingShingle Luminescent temperature sensor based on [Ru(bpy)₃]²⁺ incorporated into chitosan
Tsvirko, M.
Tkaczyk, S.
Kozak, M.
Kalota, B.
Devices and instruments
title Luminescent temperature sensor based on [Ru(bpy)₃]²⁺ incorporated into chitosan
title_full Luminescent temperature sensor based on [Ru(bpy)₃]²⁺ incorporated into chitosan
title_fullStr Luminescent temperature sensor based on [Ru(bpy)₃]²⁺ incorporated into chitosan
title_full_unstemmed Luminescent temperature sensor based on [Ru(bpy)₃]²⁺ incorporated into chitosan
title_short Luminescent temperature sensor based on [Ru(bpy)₃]²⁺ incorporated into chitosan
title_sort luminescent temperature sensor based on [ru(bpy)₃]²⁺ incorporated into chitosan
topic Devices and instruments
topic_facet Devices and instruments
url https://nasplib.isofts.kiev.ua/handle/123456789/119962
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AT tkaczyks luminescenttemperaturesensorbasedonrubpy32incorporatedintochitosan
AT kozakm luminescenttemperaturesensorbasedonrubpy32incorporatedintochitosan
AT kalotab luminescenttemperaturesensorbasedonrubpy32incorporatedintochitosan