Theoretical studies of the spin Hamiltonian parameters for the two tetragonal Cu²⁺ centers in the calcined catalysts CuO-ZnO

• Veröffentlicht in: Condensed Matter Physics
• Datum: 2011
• Hauptverfasser: Zhang, H.M., Wu, S.Y., Zhang, Z.H.
• Format: Artikel
• Sprache: Englisch
• Veröffentlicht: Інститут фізики конденсованих систем НАН України 2011
• Online Zugang: https://nasplib.isofts.kiev.ua/handle/123456789/120003
• Назва журналу: Digital Library of Periodicals of National Academy of Sciences of Ukraine
• Zitieren: Theoretical studies of the spin Hamiltonian parameters for the two tetragonal Cu²⁺ centers in the calcined catalysts CuO-ZnO / H.M. Zhang, S.Y. Wu, Z.H. Zhang // Condensed Matter Physics. — 2011. — Т. 14, № 2. — С. 23703:1-6. — Бібліогр.: 25 назв. — англ.

The spin Hamiltonian parameters for the two Cu²⁺ centers A1 and A2 in the calcined catalysts CuO-ZnO are theoretically investigated using the high order perturbation formulas of these parameters for a 3d⁹ ion in tetragonally elongated octahedra. In the above formulas, the tetragonal field parameters...