Effects of matrix composition and Eu³⁺ concentration on luminescence properties of phosphate glass
The effect of Li₂O and ZnO content and Eu³⁺ ion concentration in the glass composition on the decay of luminescence was investigated in phosphate glasses of composition P₂O₅—Li₂O—ZnO . The emission was excited by high-current electron beam of nanosecond duration with an electron energy of 200 eV...
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| Published in: | Functional Materials |
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| Date: | 2013 |
| Main Authors: | , , |
| Format: | Article |
| Language: | English |
| Published: |
НТК «Інститут монокристалів» НАН України
2013
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| Subjects: | |
| Online Access: | https://nasplib.isofts.kiev.ua/handle/123456789/120079 |
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| Journal Title: | Digital Library of Periodicals of National Academy of Sciences of Ukraine |
| Cite this: | Effects of matrix composition and Eu³⁺ concentration on luminescence properties of phosphate glass / E.F. Polisadova, H.A. Othman, V.M. Lisitsyn // Functional Materials. — 2013. — Т. 20, № 3. — С. 290-294. — Бібліогр.: 17 назв. — англ. |
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Digital Library of Periodicals of National Academy of Sciences of Ukraine| Summary: | The effect of Li₂O and ZnO content and Eu³⁺ ion concentration in the glass composition on the decay of luminescence was investigated in phosphate glasses of composition P₂O₅—Li₂O—ZnO . The emission was excited by high-current electron beam of nanosecond duration with an electron energy of 200 eV. It was found that in the range of 0.5—3 wt.% Eu₂O₃ the decay time depends weakly on europium ion concentration. The increase of ZnO (with parallel reduction of Li₂O ) leads to a shortening the decay time of luminescence in the bands at 592 and 614 nm of 2.1 to 1.5 ms. This is due to the symmetry reduction of the Eu³⁺ ion environment. The rise of luminescence signal with duration of some microseconds in the kinetics of the luminescence peak at 614 nm was observed.
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| ISSN: | 1027-5495 |