Correlated band structure of electron-doped cuprate materials

We present a numerical study of the doping dependence of the spectral function of the n-type
 cuprates. Using a variational cluster-perturbation theory approach based upon the self-energyfunctional
 theory, the spectral function of the electron-doped two-dimensional Hubbard model is&...

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Published in:Физика низких температур
Date:2006
Main Authors: Dahnken, C., Potthoff, M., Arrigoni, E., Hanke, W.
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Language:English
Published: Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України 2006
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Online Access:https://nasplib.isofts.kiev.ua/handle/123456789/120195
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Cite this:Correlated band structure of electron-doped cuprate
 materials / C. Dahnken, M. Potthoff, E. Arrigoni, W. Hanke // Физика низких температур. — 2006. — Т. 32, № 4-5. — С. 602– 608. — Бібліогр.: 33 назв. — англ.

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Digital Library of Periodicals of National Academy of Sciences of Ukraine
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author Dahnken, C.
Potthoff, M.
Arrigoni, E.
Hanke, W.
author_facet Dahnken, C.
Potthoff, M.
Arrigoni, E.
Hanke, W.
citation_txt Correlated band structure of electron-doped cuprate
 materials / C. Dahnken, M. Potthoff, E. Arrigoni, W. Hanke // Физика низких температур. — 2006. — Т. 32, № 4-5. — С. 602– 608. — Бібліогр.: 33 назв. — англ.
collection DSpace DC
container_title Физика низких температур
description We present a numerical study of the doping dependence of the spectral function of the n-type
 cuprates. Using a variational cluster-perturbation theory approach based upon the self-energyfunctional
 theory, the spectral function of the electron-doped two-dimensional Hubbard model is
 calculated. The model includes the next-nearest neighbor electronic hopping amplitude t' and a
 fixed on-site interaction U - 8t at half-filling and doping levels ranging from x - 0.077 to x - 0.20 .
 Our results support the fact that a comprehensive description of the single-particle spectrum of
 electron-doped cuprates requires a proper treatment of strong electronic correlations. In contrast
 to previous weak-coupling approaches, we obtain a consistent description of the ARPES
 experiments without the need to (artificially) introduce a doping-dependent on-site interaction U.
first_indexed 2025-12-07T18:35:31Z
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fulltext Fizika Nizkikh Temperatur, 2006, v. 32, Nos. 4/5, p. 602– 608 Correlated band structure of electron-doped cuprate materials C. Dahnken1, M. Potthoff1, E. Arrigoni2, and W. Hanke1,3 1Institute for Theoretical Physics and Astrophysics, University of W�rzburg, am Hubland, W�rzburg 97074, Germany E-mail: arriqoni@itp.tu-graz.ac.at 2Institute for Theoretical Physics and Computational Physics, Graz University of Technology, Graz, A-8010, Austria 3Kavli Institute for Theoretical Physics, University of California, Santa Barbara, California 93106-4030, USA E-mail: hanke@physik.uni-wuerzburg.de Received August 25, 2005 We present a numerical study of the doping dependence of the spectral function of the n-type cuprates. Using a variational cluster-perturbation theory approach based upon the self-energy- functional theory, the spectral function of the electron-doped two-dimensional Hubbard model is calculated. The model includes the next-nearest neighbor electronic hopping amplitude t� and a fixed on-site interaction U t� 8 at half-filling and doping levels ranging from x � 0077. to x � 020. . Our results support the fact that a comprehensive description of the single-particle spectrum of electron-doped cuprates requires a proper treatment of strong electronic correlations. In contrast to previous weak-coupling approaches, we obtain a consistent description of the ARPES experiments without the need to (artificially) introduce a doping-dependent on-site interactionU. PACS: 74.25.Jb, 74.72.—h Keywords: High-Tc superconductivity, cuprate materials, electron correlations. Introduction Angular resolved photoemission spectroscopy (ARPES) has greatly contributed to our current un- derstanding of materials with strong electron corre- lations, in particular high-temperature supercon- ductors (HTSC). Up to a few years ago, ARPES investigations have been concentrated on hole-doped HTSC materials. Since ARPES probes the part of the spectral function that is occupied by electrons, only the region below the insulating gap can be investi- gated in hole-doped cuprates. Although the observa- tion of the unoccupied parts of the spectral function is in principle possible via inverse photoemission, the process is highly involved and does not yield the same resolution as direct photoemission. An opportunity for a more comprehensive study of the doping dependence of the spectral function is offered by electron-doped cuprates. In these materials, not only the excitations below the Fermi level in the lower Hubbard band, but also those below the Fermi level in the upper Hubbard band can be studied and thus a large part of the important low-energy excitations is covered. For this reason, the investigation of such n-type cuprates by ARPES provides a large amount of new information on the quasiparticle dynamics of HTSC cuprates. Recently, an ARPES study of the doping dependence of the electron-doped cuprate Nd2�xCexCuOCl4� � (NCCO) has been carried out by the Stanford group [1,2]. In these measurements, the low-energy excitations of Nd2CuOCl 4� � (NCO) were shown to essentially coincide with the ones of typical undoped parent compounds of hole-doped materials such as Sr2CuO2Cl2 and Ca2CuO2Cl2, thus demonstrating the universality of the electronic structure of the (single layer) undoped cuprates. Upon electron do- ping, a remarkable Fermi surface (FS) evolution was found: In the heavily underdoped region the low- energy spectral weight is limited to an area close © C. Dahnken, M. Potthoff, E. Arrigoni, and W. Hanke, 2006 around k � ( , )� 0 . This has been interpreted as the formation of electron pockets. With increasing doping level, these pockets are connected by FS patches and finally form a large local density approximation (LDA)-like FS closed around k � ( , )� � . The spectral function and FS data presented in [2] gave rise to several theoretical interpretations, which also include the idea of a collapse of the Mott gap due to strong suppression of the local Coulomb repulsion upon doping [3]. This conclusion was based upon mean-field calculations which employ a fitting of the on-site repulsion Ueff of the Hubbard model as a function of doping, to the value of the antiferromag- netic order parameter obtained from experiments at each doping level. In the present paper, using both standard cluster- perturbation theory (CPT) [4–6] and, in particular, also a variationally improved version (V-CPT) [7–10], which is based on the self-energy functional theory [11], we calculate the spectral function of the two-dimensional one-band Hubbard model. This mo- del is taken with next-nearest neighbor hopping amplitude t t� � �0 35. and fixed on-site interaction U t� 8 at half filling and doping levels ranging from x � 0 077. to x � 0 20. . Our numerical results show that the salient features of the recent ARPES experiments for electron-doped cuprates can be reproduced with one-and-the-same Hubbard model without the neces- sity to resort to any change of the U-values as a function of doping as used in previous theoretical studies. Our challenge here is to reproduce the global (i.e. n- and p-doped) phase diagram by one universal choice of the model parameters, starting from a pic- ture of a doped Mott–Hubbard insulator. Model As a generic model for the HTSC compounds we use the one-band Hubbard model [12] H b1 , i.e. H t c c U n nb i j i j i i i1 � � � � � � � �� �( ) , † � � h.c. . (1) Here, ci� † (ci�) creates (annihilates) an electron on site i with spin �, � �� denotes nearest neighbors and U is the on-site part of the Coulomb repulsion. Al- though the t U� Hubbard model at low temperature develops a quasiparticle band of the appropriate width [13,14], the dispersion shows a near degene- racy between the k � ( , )� 0 and the k � ( , )� �/ /2 2 points. From ARPES experiments, however, we know that the quasiparticle peak at k � ( , )� 0 is shifted to higher binding energies. Actually, the dispersion of the quasiparticle peak shows two parabola with low- est binding energy at k � ( , )� /2 0 and k � ( , )� � /2 . It is, thus, indispensable to add at least one addi- tional term [15,16], which is taken here to be the hopping between next-nearest neighbors (�� ��� ), i.e. � � � �� �� �t c c i j i j( ) , † � � h.c . (2) Even longer-range hopping (t ) elements have been proposed to achieve consistency with experiment [17]. However, for the purpose of a qualitative analysis, it is sufficient to lift the degeneracy between k � ( , )� 0 and k � ( , )� �/ /2 2 and, thus, create the indirect gap as observed in experiments. Numerical technique Despite the considerable simplification arising from the use of an effective single-band model, the calculation of the spectral function of the Hubbard model still remains a difficult task. The calculation of this quantity by exact diagonalization is only possible for a small lattice of up to 4 4 sites, provided periodic boundary conditions are used. Larger lattice sizes can only be calculated by stochastic methods, such as the quantum Monte Carlo (QMC) technique [18] or the density matrix renormalization group algorithm (DMRG) [19]. While these techniques certainly represent powerful approaches to strongly- correlated electron systems, they are known to show disadvantages when applied to the present problem. In case of QMC, doping and low temperatures lead to the well-known sign problem, i.e. the computation time increases exponentially with T and system size [14,20]. DMRG, in contrast, is a ground state tech- nique successfully applied for 1D and ladder systems, but displays convergence problems when applied to two-dimensional systems. Recently, a strong-coupling perturbation theory has been developed for which the infinite lattice is subdivided into sufficiently small clusters that can be treated exactly, followed by an infinite-lattice ex- pansion in powers of the hopping between the clusters [4–6]. The expansion in the intercluster hopping can be formally carried out up to arbitrary order following the diagrammatic method of Refs. 21–23. The lowest order of this strong-coupling expansion in the inter- cluster hopping has been termed «cluster perturbation theory» (CPT). The CPT Green’s function is given by G G G TG G TG TG G T � � � � � �0 0 0 0 0 0 0 1 1 � [ ]– , (3) where G is the Green’s function of the infinite system, G0 the cluster Green’s function and T the inter-cluster hopping. All quantities are matrices with Correlated band structure of electron-doped cuprate materials Fizika Nizkikh Temperatur, 2006, v. 32, Nos. 4/5 603 indices referring to the particular cluster and to the sites within that cluster. CPT can be considered as a systematic approach with respect to the cluster size, i.e. it becomes exact in the limit Nc � �, where Nc is the number of sites within a cluster. In addition, CPT provides approximate results for an infinitely large system: One of the advantages of this method is that the CPT Green’s function is defined for any wave vector k in the Brillouin zone, contrary to common «direct» cluster methods, like QMC or exact diagonalization (ED), for which only a few momenta are available. CPT results for static quantities as well as for the single-particle spectral function have been shown to agree very well with different exact analytical and numerical results [5,6]. On the other hand, there is also a serious disadvantage of CPT at this level: Namely, the method does not contain any self-con- sistent procedure which implies that symmetry-broken phases cannot be studied. We have recently proposed a variational approach (V-CPT) to this problem, which is based on the self-energy-functional approach (SFA). This method is explained in detail elsewhere [7,8,11]. We use V-CPT to calculate the Green’s function of the half-filled Hubbard model with long- range antiferromagnetic order while plain CPT is used for the doped system. The extension to a doped system with d-wave superconductivity was presented in Refs. 10. Results and discussion We consider the above single-band Hubbard model with nearest- t and next-nearest-neighbor t� hopping at zero temperature. Useful parameterizations of the t t U� �� Hubbard model can be taken from the lite- rature [16,24]. We choose t t� � �0 35. andU t� 8 here, which yields a sufficiently accurate ratio for the Mott gap � 4t and for the width of the quasiparticle band W t� 1 , and fits the experimental dispersion of the quasiparticle band. For a reasonable approximation to the full many-body problem, CPT and V-CPT cal- culations for relatively large clusters are required. In this work, we have calculated the spectral function for half filling and for doped systems with x � 0 07. to 0 2. . To achieve the smallest doping level, clusters con- sisting of 13 sites have been used. Figure 1 displays the spectral function A( , )k � of the half-filled (x � 0 0. , panel A) and overdoped t t U� �� Hubbard model (x � 0 2. , panel B). The plots show A( , )k � along the momenta � � � �( , )0 0 X � � � � �( , ) ( , ) ( , )� � �0 0 0M � through the Bril- 604 Fizika Nizkikh Temperatur, 2006, v. 32, Nos. 4/5 C. Dahnken, M. Potthoff, E. Arrigoni, and W. Hanke 6 6 4 4 2 2 0 0 –0.1 –0.2 –0.3 –0.4 0 –2 –2 –4 –4 –6 –6 –8 –8 �� � � � � E, eV �� � � � �t t Fig. 1. Spectral function of the t t U� � � Hubbard model with t t� � �035. and U t� 8 . Panel A: half-filling. Panel B: over- doped system with x � 02. . Panel C: Detailed dispersion of the quasiparticle band of panel A for t � 05. eV. Symbols repre- sent the experimentally determined dispersion for Sr2CuO2Cl2 (squares [25], circles [26], diamonds [27]). Both spectra where obtained by a CPT calculation using a 10-site cluster. louin zone. The half-filled system in panel A gives rise to a narrow quasiparticle band, roughly between � � �3t and � � �2t. A more detailed plot is given in panel C. One notices the characteristic parabolic dispersion close to k � ( , )� /2 0 , k � ( , )� � /2 and k � ( , )� �/ /2 2 . Assuming t � 0 5. eV, this dispersion is practically identical to the ARPES data [2,25,26,28]. The indirect single particle gap between k � ( , )� 0 and k � ( , )� �/ /2 2 is about 4t, which is the maximum value still compatible with experiments. At about � � �3t a feature with maximal spectral weight close to k � ( , )0 0 can be observed. The same spectral feature was already observed in early QMC simulations of the single-band t U� Hubbard mo- del [29], exact diagonalizations of the t – J model [30] and approximate perturbative methods such as the self-consistent Born approximation (SCBA). Its spectral weight was mostly perceived as coherent, i.e. corresponding to the «coherent» motion of a «spin- bag» like quasiparticle. This is also supported by more recent QMC simulations [13], V-CPT calculations [8] of the t U� Hubbard model, and analytical consi- derations [31]. We now discuss the spectral function for the over- doped (x � 0 2. ) system, which is plotted in panel B. Here, one finds a metallic quasiparticle band with a flat dispersion just below the Fermi level at k � ( , )� 0 . The band crosses the Fermi level close to k � ( , )� �/ /2 2 and k � ( , )� � /2 and therefore creates a large Fermi surface closed around k � ( , )� � in the Brillouin zone. The quasiparticle band shows almost the same dispersion as the tight-binding (U � 0) model with the same parameterization. Deep below the Fermi level, between � � �6t and � � �10t, we can see the traces of the lower Hubbard band observed at half filling, i.e. the area between � � �4t and � � �6t in panel A. In Fig. 2 we plot a detail of the spectral function of the Hubbard model in a more restricted region around the Fermi level for three doping values, namely x � 0 077. (panel A), x � 0 091. (panel B), and x � 0 200. (panel C). For x � 0 077. , the Fermi level enters into the upper Hubbard band with only slight modi- fications of the spectral weight. Most important, the arc around k � ( , )� 0 in the upper Hubbard band of the half-filled system is virtually unchanged and now forms an electron pocket around k � ( , )� 0 , as can be seen in panel A. However, for this underdoped system, the Fermi level has not yet reached the bottom of the parabolic band around k � ( , )� �/ /2 2 . The effect of doping is not limited to a rigid shift of the band structure with respect to the half-filled situation. As a matter of fact, some new spectral weight is created between � � �1t and � � �0 5. t at k � ( , )0 0 and bet- ween� � �0 5. t and� � 0t at k � ( , )� �/ /2 2 . At higher doping, for x � 0 091. (panel B), this new spectral weight becomes more pronounced and starts producing the branches at k � �( , ) ( , )0 0 0� and k � �( , ) ( , )0 0 2 2� �/ / below the Fermi level, which are clearly observed in the overdoped system in pa- nel C. The results described above provide a deeper in- sight into the doping process of the t t U� �� Hubbard model, provided one assumes that the parameters of the model do not change as a function of doping. Correlated band structure of electron-doped cuprate materials Fizika Nizkikh Temperatur, 2006, v. 32, Nos. 4/5 605 –2 –2 –2 –1.5 –1.5 –1.5 –1.0 –1.0 –1.0 – 0.5 – 0.5 – 0.5 0 0 0 0.5 0.5 0.5 1.0 1.0 1.0 �� � ��� �� � ��� �� � ��� t t t �� �� �� �� �� �� � �� � �� � �� � � � � � � �� �� �� �� �� �� A B C Fig. 2. Details of the spectral function of the t t U� �� Hubbard model with t t� � �035. and U t� 8 restricted to a narrower region around the Fermi level. Panel A: x = 0.077, obtained from a 13 site cluster. Panel B: x = 0.091, ob- tained from a 11 site cluster. Panel C: x = 0.200, obtained from a 10 site cluster. Although this assumption is widely believed to be appropriate for the doping range considered here, there have been suggestions that the on-site repulsion U is constant over a broader doping range. The possibility of a doping-dependent on-site repulsion was considered recently on the basis of a spin-density wave (SDW) mean field calculation of the t t t U� �� � Hubbard model to describe the experimental data of the electron-doped system NCCO [2,3]. In contrast to the usual SDW calculation, where one self-consis- tently determines the single particle gap mf under the assumption that U is a fixed parameter, the authors of Ref. 3 consider U as a doping-dependent parameter fixed by the condition that at each doping value mf corresponds to the experimentally-deter- mined pseudogap. In their calculation, which we herewith refer to as KMLB, the value of Ueff drops sharply upon doping from U teff � 6 at half filling to U teff � 3 at x � 015. . The success of this idea is sup- ported by the fact that the spectral function obtained from this procedure shows excellent agreement with the doping evolution of the experimentally observed Fermi surface. The whole scenario, however, is based upon the assumption that a varying Ueff is indis- pensable for the reproduction of the experimental results. For this reason, it is important to verify, whether a doping-dependentU is necessary in order to correctly reproduce the spectral features as a function of dop- ing, in particular the doping dependence of the Fermi surface. This is conveniently represented experimen- tally by plotting an intensity plot of the spectral weight at the Fermi energy � � 0. The upper row of Fig. 3 (panels A through C) shows the ARPES data taken from [2], whereas the lower row (panels D through F) plots the results obtained by in the CPT calculation [32]. Although we only used a minimal set of standard parameters and did not change the parameterization (in particular U) as a function of doping, the CPT Fermi surface of the fully correlated Hubbard model qualitatively reproduces the experimental result. In particular, we observe electron pockets around k � ( , )� 0 in the underdoped region, a FS patch at k � ( , )� �/ /2 2 for about x � 010. and a large FS centered around k � ( , )� � in the overdoped case. All these features are consistent with the experimental results found in [2] as well as in the Hartree—Fock calculation of Ref. 3. As a matter of fact, Fig. 2 shows that the closing of the gap at higher doping, which is obtained «by hand» upon decreasing U within the KMLB, comes about naturally within our numerical treatment of the Hubbard model, in which electron correlations are treated more accurately. Figure 4 directly compares the CPT and KMLB quasiparticle dispersion at half filling and x � 010. (CPT: x � 0 091. ). Notice that for the KMLB results only the dispersion is indicated (solid line). In order to have comparable energy scales, we reported the energies from [3] in unit of t � 1. At half filling (Panel A) both methods show almost identical dispersions for the lowest-energy excitations, since both methods have been fitted to the expe- rimental results. However, as a SDW-type mean field 606 Fizika Nizkikh Temperatur, 2006, v. 32, Nos. 4/5 C. Dahnken, M. Potthoff, E. Arrigoni, and W. Hanke A D B E C F Fig. 3 Spectral weight at the Fermi energy, whose maximum is an indication of the Fermi-surface contour for different doping levels. The plots A through C are obtained from ARPES experiments (taken from [2]), while D through F correspond to our CPT results, whose spectral functions are plotted in Fig. 2. method, the KMLB results cannot describe the full lower Hubbard band and is exclusively fitted to the low-energy excitations. Hence, the lower part of the spectrum between � � �3t to � � �4t cannot be re- produced within this technique. Both techniques describe the closing of the gap as a function of doping. Although the CPT dispersion is much weaker and shows a much smaller gap at k � ( , )� �/ /2 2 , the qualitative development as a function of doping is very similar. As discussed above, there is additional information provided by CPT in contrast to KMLB, concerning the high-binding ener- gy part of the spectrum. In particular, a remainder of the parabolic dispersion at k � ( , )� �/ /2 2 is found at � � �5t. This feature does not appear in the mean field calculation, but can be clearly identified in the ex- perimental data [2]. Conclusion In conclusion, we have shown that the evolution of the Fermi surface of the electron-doped cuprates is well described within the framework of the one-band Hubbard model with nearest- and next-nearest-neigh- bor hoppings. In particular, we have provided indi- cations that a doping-dependent Hubbard repulsionU is not necessary in order to describe the doping dependence of the ARPES spectrum. The authors would like to acknowledge support by the DFG-Forschergruppe: Doping-dependence of phase transitions and ordering phenomena in cuprate superconductors (FOR 538), and by the Bavarian KONWHIR project CUHE. This research was sup- ported in part by the National Science Foundation under Grant No. PHY99-0794. One of us (WH) would like to acknowledge the warm hospitality of the Kavli Institute for Theoretical Physics in Santa Bar- bara, where part of this work was concluded. 1. N.P. Armitage, D.H. Lu, C. Kim, A. Damascelli, K.M. Shen, F. Ronning, D.L. Feng, P. Bogdanov, Z.X. Shen, Y. Onose, Y. Taguchi, Y. Tokura, P.K. Mang, N. Kaneko, and M. Greven, Phys. Rev. Lett. 87, 147003 (2001). 2. N.P. Armitage, F. Ronning, D.H. Lu, C. Kim, A. Da- mascelli, K.M. Shen, D.L. Feng, H. Eisaki, Z.-X. Shen, P.K. Mang, N. 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institution Digital Library of Periodicals of National Academy of Sciences of Ukraine
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spelling Dahnken, C.
Potthoff, M.
Arrigoni, E.
Hanke, W.
2017-06-11T12:14:54Z
2017-06-11T12:14:54Z
2006
Correlated band structure of electron-doped cuprate
 materials / C. Dahnken, M. Potthoff, E. Arrigoni, W. Hanke // Физика низких температур. — 2006. — Т. 32, № 4-5. — С. 602– 608. — Бібліогр.: 33 назв. — англ.
0132-6414
PACS: 74.25.Jb, 74.72.—h
https://nasplib.isofts.kiev.ua/handle/123456789/120195
We present a numerical study of the doping dependence of the spectral function of the n-type
 cuprates. Using a variational cluster-perturbation theory approach based upon the self-energyfunctional
 theory, the spectral function of the electron-doped two-dimensional Hubbard model is
 calculated. The model includes the next-nearest neighbor electronic hopping amplitude t' and a
 fixed on-site interaction U - 8t at half-filling and doping levels ranging from x - 0.077 to x - 0.20 .
 Our results support the fact that a comprehensive description of the single-particle spectrum of
 electron-doped cuprates requires a proper treatment of strong electronic correlations. In contrast
 to previous weak-coupling approaches, we obtain a consistent description of the ARPES
 experiments without the need to (artificially) introduce a doping-dependent on-site interaction U.
The authors would like to acknowledge support
 by the DFG-Forschergruppe: Doping-dependence of
 phase transitions and ordering phenomena in cuprate superconductors (FOR 538), and by the Bavarian
 KONWHIR project CUHE. This research was supported
 in part by the National Science Foundation
 under Grant No. PHY99-0794. One of us (WH)
 would like to acknowledge the warm hospitality of the
 Kavli Institute for Theoretical Physics in Santa Barbara,
 where part of this work was concluded.
en
Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України
Физика низких температур
Strong Correlations
Correlated band structure of electron-doped cuprate materials
Article
published earlier
spellingShingle Correlated band structure of electron-doped cuprate materials
Dahnken, C.
Potthoff, M.
Arrigoni, E.
Hanke, W.
Strong Correlations
title Correlated band structure of electron-doped cuprate materials
title_full Correlated band structure of electron-doped cuprate materials
title_fullStr Correlated band structure of electron-doped cuprate materials
title_full_unstemmed Correlated band structure of electron-doped cuprate materials
title_short Correlated band structure of electron-doped cuprate materials
title_sort correlated band structure of electron-doped cuprate materials
topic Strong Correlations
topic_facet Strong Correlations
url https://nasplib.isofts.kiev.ua/handle/123456789/120195
work_keys_str_mv AT dahnkenc correlatedbandstructureofelectrondopedcupratematerials
AT potthoffm correlatedbandstructureofelectrondopedcupratematerials
AT arrigonie correlatedbandstructureofelectrondopedcupratematerials
AT hankew correlatedbandstructureofelectrondopedcupratematerials