Electronic structure and atomic structure peculiarities of isomorphic modified zinc diphosphates
Effects of partial substitution of Zn by Mn on the electronic and atomic structure of diphosphates Zn₂₋xMnxP₂O₇⋅5H₂O (x = 0.0, 0.7) have been studied out by X-ray photoelectron spectroscopy, IR spectroscopy, NMR and thermogravimetric analysis. Analysis of the infrared absorption spectra was carried...
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| Опубліковано в: : | Functional Materials |
|---|---|
| Дата: | 2014 |
| Автори: | , , |
| Формат: | Стаття |
| Мова: | Англійська |
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НТК «Інститут монокристалів» НАН України
2014
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| Онлайн доступ: | https://nasplib.isofts.kiev.ua/handle/123456789/120372 |
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| Назва журналу: | Digital Library of Periodicals of National Academy of Sciences of Ukraine |
| Цитувати: | Electronic structure and atomic structure peculiarities of isomorphic modified zinc diphosphates / S.S. Smolyak, V.L. Karbivskyy, V.H. Kasiyanenko // Functional Materials. — 2014. — Т. 21, № 1. — С. 80-85. — Бібліогр.: 13 назв. — англ. |
Репозитарії
Digital Library of Periodicals of National Academy of Sciences of Ukraine| _version_ | 1862546732731072512 |
|---|---|
| author | Smolyak, S.S. Karbivskyy, V.L. Kasiyanenko, V.H. |
| author_facet | Smolyak, S.S. Karbivskyy, V.L. Kasiyanenko, V.H. |
| citation_txt | Electronic structure and atomic structure peculiarities of isomorphic modified zinc diphosphates / S.S. Smolyak, V.L. Karbivskyy, V.H. Kasiyanenko // Functional Materials. — 2014. — Т. 21, № 1. — С. 80-85. — Бібліогр.: 13 назв. — англ. |
| collection | DSpace DC |
| container_title | Functional Materials |
| description | Effects of partial substitution of Zn by Mn on the electronic and atomic structure of diphosphates Zn₂₋xMnxP₂O₇⋅5H₂O (x = 0.0, 0.7) have been studied out by X-ray photoelectron spectroscopy, IR spectroscopy, NMR and thermogravimetric analysis. Analysis of the infrared absorption spectra was carried out for functional groups of Zn₂P₂O₇⋅5H₂O and Zn₁.₃Mn₀.₇P₂O₇5H₂O compounds. Through correlation between the symmetric and asymmetric stretching vibrations of P-O-P bridge and P-O-P angle an increase of P-O-P bridge angle was established for Zn₁.₃Mn₀.₇P₂O₇5H₂O. Substitution of zinc by manganese has little impact on the overall balance of chemical bond in the compound, which is manifested in minor changes of the core electrons binding energies.
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| first_indexed | 2025-11-25T12:23:10Z |
| format | Article |
| fulltext | |
| id | nasplib_isofts_kiev_ua-123456789-120372 |
| institution | Digital Library of Periodicals of National Academy of Sciences of Ukraine |
| issn | 1027-5495 |
| language | English |
| last_indexed | 2025-11-25T12:23:10Z |
| publishDate | 2014 |
| publisher | НТК «Інститут монокристалів» НАН України |
| record_format | dspace |
| spelling | Smolyak, S.S. Karbivskyy, V.L. Kasiyanenko, V.H. 2017-06-12T06:32:30Z 2017-06-12T06:32:30Z 2014 Electronic structure and atomic structure peculiarities of isomorphic modified zinc diphosphates / S.S. Smolyak, V.L. Karbivskyy, V.H. Kasiyanenko // Functional Materials. — 2014. — Т. 21, № 1. — С. 80-85. — Бібліогр.: 13 назв. — англ. 1027-5495 https://nasplib.isofts.kiev.ua/handle/123456789/120372 DOI: dx.doi.org/10.15407/fm21.01.080 Effects of partial substitution of Zn by Mn on the electronic and atomic structure of diphosphates Zn₂₋xMnxP₂O₇⋅5H₂O (x = 0.0, 0.7) have been studied out by X-ray photoelectron spectroscopy, IR spectroscopy, NMR and thermogravimetric analysis. Analysis of the infrared absorption spectra was carried out for functional groups of Zn₂P₂O₇⋅5H₂O and Zn₁.₃Mn₀.₇P₂O₇5H₂O compounds. Through correlation between the symmetric and asymmetric stretching vibrations of P-O-P bridge and P-O-P angle an increase of P-O-P bridge angle was established for Zn₁.₃Mn₀.₇P₂O₇5H₂O. Substitution of zinc by manganese has little impact on the overall balance of chemical bond in the compound, which is manifested in minor changes of the core electrons binding energies. en НТК «Інститут монокристалів» НАН України Functional Materials Modeling and simulation Electronic structure and atomic structure peculiarities of isomorphic modified zinc diphosphates Article published earlier |
| spellingShingle | Electronic structure and atomic structure peculiarities of isomorphic modified zinc diphosphates Smolyak, S.S. Karbivskyy, V.L. Kasiyanenko, V.H. Modeling and simulation |
| title | Electronic structure and atomic structure peculiarities of isomorphic modified zinc diphosphates |
| title_full | Electronic structure and atomic structure peculiarities of isomorphic modified zinc diphosphates |
| title_fullStr | Electronic structure and atomic structure peculiarities of isomorphic modified zinc diphosphates |
| title_full_unstemmed | Electronic structure and atomic structure peculiarities of isomorphic modified zinc diphosphates |
| title_short | Electronic structure and atomic structure peculiarities of isomorphic modified zinc diphosphates |
| title_sort | electronic structure and atomic structure peculiarities of isomorphic modified zinc diphosphates |
| topic | Modeling and simulation |
| topic_facet | Modeling and simulation |
| url | https://nasplib.isofts.kiev.ua/handle/123456789/120372 |
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