Structural behaviour of continuous solid solution SmCo₁₋xFexO₃

Phase and structural behaviour in the SmCoO₃-SmFeO₃ pseudobinary system has been investigated at the ambient conditions in a whole concentration range by means of X-ray powder diffraction technique applied laboratory and synchrotron radiation sources. Series of mixed samarium cobaltites-ferrites SmC...

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Опубліковано в: :Functional Materials
Дата:2014
Автори: Kharko, O.V., Vasylechko, L.O., Ubizskii, S.B., Pashuk, A., Prots, Yu.
Формат: Стаття
Мова:Англійська
Опубліковано: НТК «Інститут монокристалів» НАН України 2014
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Онлайн доступ:https://nasplib.isofts.kiev.ua/handle/123456789/120436
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Назва журналу:Digital Library of Periodicals of National Academy of Sciences of Ukraine
Цитувати:Structural behaviour of continuous solid solution SmCo₁₋xFexO₃ / O.V. Kharko, L.O. Vasylechko, S.B. Ubizskii, A. Pashuk, Yu. Prots // Functional Materials. — 2014. — Т. 21, № 2. — С. 226-232. — Бібліогр.: 36 назв. — англ.

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Digital Library of Periodicals of National Academy of Sciences of Ukraine
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author Kharko, O.V.
Vasylechko, L.O.
Ubizskii, S.B.
Pashuk, A.
Prots, Yu.
author_facet Kharko, O.V.
Vasylechko, L.O.
Ubizskii, S.B.
Pashuk, A.
Prots, Yu.
citation_txt Structural behaviour of continuous solid solution SmCo₁₋xFexO₃ / O.V. Kharko, L.O. Vasylechko, S.B. Ubizskii, A. Pashuk, Yu. Prots // Functional Materials. — 2014. — Т. 21, № 2. — С. 226-232. — Бібліогр.: 36 назв. — англ.
collection DSpace DC
container_title Functional Materials
description Phase and structural behaviour in the SmCoO₃-SmFeO₃ pseudobinary system has been investigated at the ambient conditions in a whole concentration range by means of X-ray powder diffraction technique applied laboratory and synchrotron radiation sources. Series of mixed samarium cobaltites-ferrites SmCo₁₋xFexO₃ was obtained by the solid state reaction in air at 1573 K. Formation of a continuous solid solution SmCo₁₋xFexO₃ with orthorhombic perovskite structure (GdFeO₃ type, space group Pbnm) has been revealed. Crystal structure parameters of the mixed samarium cobaltites-ferrites, as well as nominally pure SmCoO₃ and SmFeO₃ have been established by full profile Rietveld refinement. Based on the analysis of structural parameters, an influence of the cation substitution on the deformation of the orthorhombic perovskite structure in the SmCo₁₋xFexO₃ series has been established.
first_indexed 2025-12-07T19:54:29Z
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last_indexed 2025-12-07T19:54:29Z
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publisher НТК «Інститут монокристалів» НАН України
record_format dspace
spelling Kharko, O.V.
Vasylechko, L.O.
Ubizskii, S.B.
Pashuk, A.
Prots, Yu.
2017-06-12T07:38:50Z
2017-06-12T07:38:50Z
2014
Structural behaviour of continuous solid solution SmCo₁₋xFexO₃ / O.V. Kharko, L.O. Vasylechko, S.B. Ubizskii, A. Pashuk, Yu. Prots // Functional Materials. — 2014. — Т. 21, № 2. — С. 226-232. — Бібліогр.: 36 назв. — англ.
1027-5495
DOI: dx.doi.org/10.15407/fm21.02.226
https://nasplib.isofts.kiev.ua/handle/123456789/120436
Phase and structural behaviour in the SmCoO₃-SmFeO₃ pseudobinary system has been investigated at the ambient conditions in a whole concentration range by means of X-ray powder diffraction technique applied laboratory and synchrotron radiation sources. Series of mixed samarium cobaltites-ferrites SmCo₁₋xFexO₃ was obtained by the solid state reaction in air at 1573 K. Formation of a continuous solid solution SmCo₁₋xFexO₃ with orthorhombic perovskite structure (GdFeO₃ type, space group Pbnm) has been revealed. Crystal structure parameters of the mixed samarium cobaltites-ferrites, as well as nominally pure SmCoO₃ and SmFeO₃ have been established by full profile Rietveld refinement. Based on the analysis of structural parameters, an influence of the cation substitution on the deformation of the orthorhombic perovskite structure in the SmCo₁₋xFexO₃ series has been established.
en
НТК «Інститут монокристалів» НАН України
Functional Materials
Technology
Structural behaviour of continuous solid solution SmCo₁₋xFexO₃
Article
published earlier
spellingShingle Structural behaviour of continuous solid solution SmCo₁₋xFexO₃
Kharko, O.V.
Vasylechko, L.O.
Ubizskii, S.B.
Pashuk, A.
Prots, Yu.
Technology
title Structural behaviour of continuous solid solution SmCo₁₋xFexO₃
title_full Structural behaviour of continuous solid solution SmCo₁₋xFexO₃
title_fullStr Structural behaviour of continuous solid solution SmCo₁₋xFexO₃
title_full_unstemmed Structural behaviour of continuous solid solution SmCo₁₋xFexO₃
title_short Structural behaviour of continuous solid solution SmCo₁₋xFexO₃
title_sort structural behaviour of continuous solid solution smco₁₋xfexo₃
topic Technology
topic_facet Technology
url https://nasplib.isofts.kiev.ua/handle/123456789/120436
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AT vasylechkolo structuralbehaviourofcontinuoussolidsolutionsmco1xfexo3
AT ubizskiisb structuralbehaviourofcontinuoussolidsolutionsmco1xfexo3
AT pashuka structuralbehaviourofcontinuoussolidsolutionsmco1xfexo3
AT protsyu structuralbehaviourofcontinuoussolidsolutionsmco1xfexo3