Synthesis, characterization and electrical properties of Pb(₈₋x)Na₂Ndx(VO₄)₆O(x/₂) solid solutions
Substitution of neodymium for lead in the apatite structure in accordance to scheme 2Pb²⁺ +□ o→ 2Nd³⁺ + O²⁻ has been investigated by X-ray powder diffraction, scanning electron microscopy, IR spectroscopy and the measurement of electrical conductivity. It was established that single phase solid solu...
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| Zitieren: | Synthesis, characterization and electrical properties of Pb(₈₋x)Na₂Ndx(VO₄)₆O(x/₂) solid solutions / E.I. Getman, T.M. Savankova, A.V. Ignatov, K.G. Didorenko, A.Y. Talykova, L.I. Ardanova // Functional Materials. — 2014. — Т. 21, № 3. — С. 247-253. — Бібліогр.: 28 назв. — англ. |
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Getman, E.I. Savankova, T.M. Ignatov, A.V. Didorenko, K.G. Talykova, A.Y. Ardanova, L.I. 2017-06-12T07:51:00Z 2017-06-12T07:51:00Z 2014 Synthesis, characterization and electrical properties of Pb(₈₋x)Na₂Ndx(VO₄)₆O(x/₂) solid solutions / E.I. Getman, T.M. Savankova, A.V. Ignatov, K.G. Didorenko, A.Y. Talykova, L.I. Ardanova // Functional Materials. — 2014. — Т. 21, № 3. — С. 247-253. — Бібліогр.: 28 назв. — англ. 1027-5495 DOI: dx.doi.org/10.15407/fm21.03.247 https://nasplib.isofts.kiev.ua/handle/123456789/120455 Substitution of neodymium for lead in the apatite structure in accordance to scheme 2Pb²⁺ +□ o→ 2Nd³⁺ + O²⁻ has been investigated by X-ray powder diffraction, scanning electron microscopy, IR spectroscopy and the measurement of electrical conductivity. It was established that single phase solid solutions Pb(₈₋x)Na₂Ndx(VO₄)₆O(x/₂) are formed in the range of x = 0-0.25. The crystal structure features of some samples have been refined by the Rietveld method. It was shown that ions Nd³⁺ preferably occupy M(1) site. Influence of the composition x on the electrical conductivity and activation energy has been investigated. en НТК «Інститут монокристалів» НАН України Functional Materials Characterization and properties Synthesis, characterization and electrical properties of Pb(₈₋x)Na₂Ndx(VO₄)₆O(x/₂) solid solutions Article published earlier |
| institution |
Digital Library of Periodicals of National Academy of Sciences of Ukraine |
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DSpace DC |
| title |
Synthesis, characterization and electrical properties of Pb(₈₋x)Na₂Ndx(VO₄)₆O(x/₂) solid solutions |
| spellingShingle |
Synthesis, characterization and electrical properties of Pb(₈₋x)Na₂Ndx(VO₄)₆O(x/₂) solid solutions Getman, E.I. Savankova, T.M. Ignatov, A.V. Didorenko, K.G. Talykova, A.Y. Ardanova, L.I. Characterization and properties |
| title_short |
Synthesis, characterization and electrical properties of Pb(₈₋x)Na₂Ndx(VO₄)₆O(x/₂) solid solutions |
| title_full |
Synthesis, characterization and electrical properties of Pb(₈₋x)Na₂Ndx(VO₄)₆O(x/₂) solid solutions |
| title_fullStr |
Synthesis, characterization and electrical properties of Pb(₈₋x)Na₂Ndx(VO₄)₆O(x/₂) solid solutions |
| title_full_unstemmed |
Synthesis, characterization and electrical properties of Pb(₈₋x)Na₂Ndx(VO₄)₆O(x/₂) solid solutions |
| title_sort |
synthesis, characterization and electrical properties of pb(₈₋x)na₂ndx(vo₄)₆o(x/₂) solid solutions |
| author |
Getman, E.I. Savankova, T.M. Ignatov, A.V. Didorenko, K.G. Talykova, A.Y. Ardanova, L.I. |
| author_facet |
Getman, E.I. Savankova, T.M. Ignatov, A.V. Didorenko, K.G. Talykova, A.Y. Ardanova, L.I. |
| topic |
Characterization and properties |
| topic_facet |
Characterization and properties |
| publishDate |
2014 |
| language |
English |
| container_title |
Functional Materials |
| publisher |
НТК «Інститут монокристалів» НАН України |
| format |
Article |
| description |
Substitution of neodymium for lead in the apatite structure in accordance to scheme 2Pb²⁺ +□ o→ 2Nd³⁺ + O²⁻ has been investigated by X-ray powder diffraction, scanning electron microscopy, IR spectroscopy and the measurement of electrical conductivity. It was established that single phase solid solutions Pb(₈₋x)Na₂Ndx(VO₄)₆O(x/₂) are formed in the range of x = 0-0.25. The crystal structure features of some samples have been refined by the Rietveld method. It was shown that ions Nd³⁺ preferably occupy M(1) site. Influence of the composition x on the electrical conductivity and activation energy has been investigated.
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| issn |
1027-5495 |
| url |
https://nasplib.isofts.kiev.ua/handle/123456789/120455 |
| citation_txt |
Synthesis, characterization and electrical properties of Pb(₈₋x)Na₂Ndx(VO₄)₆O(x/₂) solid solutions / E.I. Getman, T.M. Savankova, A.V. Ignatov, K.G. Didorenko, A.Y. Talykova, L.I. Ardanova // Functional Materials. — 2014. — Т. 21, № 3. — С. 247-253. — Бібліогр.: 28 назв. — англ. |
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