Synthesis, characterization and electrical properties of Pb(₈₋x)Na₂Ndx(VO₄)₆O(x/₂) solid solutions

Substitution of neodymium for lead in the apatite structure in accordance to scheme 2Pb²⁺ +□ o→ 2Nd³⁺ + O²⁻ has been investigated by X-ray powder diffraction, scanning electron microscopy, IR spectroscopy and the measurement of electrical conductivity. It was established that single phase solid solu...

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Veröffentlicht in:Functional Materials
Datum:2014
Hauptverfasser: Getman, E.I., Savankova, T.M., Ignatov, A.V., Didorenko, K.G., Talykova, A.Y., Ardanova, L.I.
Format: Artikel
Sprache:English
Veröffentlicht: НТК «Інститут монокристалів» НАН України 2014
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Online Zugang:https://nasplib.isofts.kiev.ua/handle/123456789/120455
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Назва журналу:Digital Library of Periodicals of National Academy of Sciences of Ukraine
Zitieren:Synthesis, characterization and electrical properties of Pb(₈₋x)Na₂Ndx(VO₄)₆O(x/₂) solid solutions / E.I. Getman, T.M. Savankova, A.V. Ignatov, K.G. Didorenko, A.Y. Talykova, L.I. Ardanova // Functional Materials. — 2014. — Т. 21, № 3. — С. 247-253. — Бібліогр.: 28 назв. — англ.

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Digital Library of Periodicals of National Academy of Sciences of Ukraine
id nasplib_isofts_kiev_ua-123456789-120455
record_format dspace
spelling Getman, E.I.
Savankova, T.M.
Ignatov, A.V.
Didorenko, K.G.
Talykova, A.Y.
Ardanova, L.I.
2017-06-12T07:51:00Z
2017-06-12T07:51:00Z
2014
Synthesis, characterization and electrical properties of Pb(₈₋x)Na₂Ndx(VO₄)₆O(x/₂) solid solutions / E.I. Getman, T.M. Savankova, A.V. Ignatov, K.G. Didorenko, A.Y. Talykova, L.I. Ardanova // Functional Materials. — 2014. — Т. 21, № 3. — С. 247-253. — Бібліогр.: 28 назв. — англ.
1027-5495
DOI: dx.doi.org/10.15407/fm21.03.247
https://nasplib.isofts.kiev.ua/handle/123456789/120455
Substitution of neodymium for lead in the apatite structure in accordance to scheme 2Pb²⁺ +□ o→ 2Nd³⁺ + O²⁻ has been investigated by X-ray powder diffraction, scanning electron microscopy, IR spectroscopy and the measurement of electrical conductivity. It was established that single phase solid solutions Pb(₈₋x)Na₂Ndx(VO₄)₆O(x/₂) are formed in the range of x = 0-0.25. The crystal structure features of some samples have been refined by the Rietveld method. It was shown that ions Nd³⁺ preferably occupy M(1) site. Influence of the composition x on the electrical conductivity and activation energy has been investigated.
en
НТК «Інститут монокристалів» НАН України
Functional Materials
Characterization and properties
Synthesis, characterization and electrical properties of Pb(₈₋x)Na₂Ndx(VO₄)₆O(x/₂) solid solutions
Article
published earlier
institution Digital Library of Periodicals of National Academy of Sciences of Ukraine
collection DSpace DC
title Synthesis, characterization and electrical properties of Pb(₈₋x)Na₂Ndx(VO₄)₆O(x/₂) solid solutions
spellingShingle Synthesis, characterization and electrical properties of Pb(₈₋x)Na₂Ndx(VO₄)₆O(x/₂) solid solutions
Getman, E.I.
Savankova, T.M.
Ignatov, A.V.
Didorenko, K.G.
Talykova, A.Y.
Ardanova, L.I.
Characterization and properties
title_short Synthesis, characterization and electrical properties of Pb(₈₋x)Na₂Ndx(VO₄)₆O(x/₂) solid solutions
title_full Synthesis, characterization and electrical properties of Pb(₈₋x)Na₂Ndx(VO₄)₆O(x/₂) solid solutions
title_fullStr Synthesis, characterization and electrical properties of Pb(₈₋x)Na₂Ndx(VO₄)₆O(x/₂) solid solutions
title_full_unstemmed Synthesis, characterization and electrical properties of Pb(₈₋x)Na₂Ndx(VO₄)₆O(x/₂) solid solutions
title_sort synthesis, characterization and electrical properties of pb(₈₋x)na₂ndx(vo₄)₆o(x/₂) solid solutions
author Getman, E.I.
Savankova, T.M.
Ignatov, A.V.
Didorenko, K.G.
Talykova, A.Y.
Ardanova, L.I.
author_facet Getman, E.I.
Savankova, T.M.
Ignatov, A.V.
Didorenko, K.G.
Talykova, A.Y.
Ardanova, L.I.
topic Characterization and properties
topic_facet Characterization and properties
publishDate 2014
language English
container_title Functional Materials
publisher НТК «Інститут монокристалів» НАН України
format Article
description Substitution of neodymium for lead in the apatite structure in accordance to scheme 2Pb²⁺ +□ o→ 2Nd³⁺ + O²⁻ has been investigated by X-ray powder diffraction, scanning electron microscopy, IR spectroscopy and the measurement of electrical conductivity. It was established that single phase solid solutions Pb(₈₋x)Na₂Ndx(VO₄)₆O(x/₂) are formed in the range of x = 0-0.25. The crystal structure features of some samples have been refined by the Rietveld method. It was shown that ions Nd³⁺ preferably occupy M(1) site. Influence of the composition x on the electrical conductivity and activation energy has been investigated.
issn 1027-5495
url https://nasplib.isofts.kiev.ua/handle/123456789/120455
citation_txt Synthesis, characterization and electrical properties of Pb(₈₋x)Na₂Ndx(VO₄)₆O(x/₂) solid solutions / E.I. Getman, T.M. Savankova, A.V. Ignatov, K.G. Didorenko, A.Y. Talykova, L.I. Ardanova // Functional Materials. — 2014. — Т. 21, № 3. — С. 247-253. — Бібліогр.: 28 назв. — англ.
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