Influence of CeO₂ nanocrystals size on the vacancies formation processes determined by spectroscopic techniques

• Published in: Functional Materials
• Date: 2014
• Main Authors: Maksimchuk, P.O., Seminko, V.V., Bespalova, I.I., Masalov, A.A.
• Format: Article
• Language: English
• Published: НТК «Інститут монокристалів» НАН України 2014
• Subjects: Characterization and properties
• Online Access: https://nasplib.isofts.kiev.ua/handle/123456789/120460
• Journal Title: Digital Library of Periodicals of National Academy of Sciences of Ukraine
• Cite this: Influence of CeO₂ nanocrystals size on the vacancies formation processes determined by spectroscopic techniques / P.O. Maksimchuk, V.V. Seminko, I.I. Bespalova, A.A. Masalov // Functional Materials. — 2014. — Т. 21, № 3. — С. 254-259. — Бібліогр.: 13 назв. — англ.

In the paper influence of the size on the processes of oxygen vacancies formation in CeO₂ nanocrystals has been investigated. Changes in concentration of oxygen vacancies were determined by two independent indicators: intensity of 5d → 4f luminescence of Ce³⁺ ions and ratio between ⁵D₀ → ⁷F₁ and ⁵D₀...