Study on lithium dihydrogen phosphate crystal growth conditions in nonstoichiometric solutions

Based on analysis of lithium dihydrogen phosphate (LDP) solubility dependence on solution stoichiometry alteration, solvent evaporation rate impact on solution supersaturation change is evaluated. It is revealed that at constant crystal growth rate relative solution supersaturation linearly depends...

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Бібліографічні деталі
Дата:2014
Автори: Iurchenko, A.N., Voronov, A.P., Babenko, G.N., Stumbra, M.A., Puzikov, V.M.
Формат: Стаття
Мова:English
Опубліковано: НТК «Інститут монокристалів» НАН України 2014
Назва видання:Functional Materials
Теми:
Онлайн доступ:https://nasplib.isofts.kiev.ua/handle/123456789/120464
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Назва журналу:Digital Library of Periodicals of National Academy of Sciences of Ukraine
Цитувати:Study on lithium dihydrogen phosphate crystal growth conditions in nonstoichiometric solutions / A.N. Iurchenko, A.P. Voronov, G.N. Babenko, M.A. Stumbra, V.M. Puzikov // Functional Materials. — 2014. — Т. 21, № 3. — С. 324-328. — Бібліогр.: 15 назв. — англ.

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Digital Library of Periodicals of National Academy of Sciences of Ukraine
Опис
Резюме:Based on analysis of lithium dihydrogen phosphate (LDP) solubility dependence on solution stoichiometry alteration, solvent evaporation rate impact on solution supersaturation change is evaluated. It is revealed that at constant crystal growth rate relative solution supersaturation linearly depends on water evaporation rate. LDP nonstoichiometric saturated solution (20 % H₃PO₄ excess) stability boundary conditions are determined. Water evaporation rate is 0.5 %/24 h and supersaturation σ is 0.6 %/24 h, respectively. LDP nonstoichiometric solutions density and viscosity are measured.