A treatment of the exclusion volume term in the inhomogeneous Poisson-Boltzmann theory for an ion-dipole mixture

• Published in: Condensed Matter Physics
• Date: 2001
• Main Authors: Outhwaite, C.W., Lamperski, S.
• Format: Article
• Language: English
• Published: Інститут фізики конденсованих систем НАН України 2001
• Online Access: https://nasplib.isofts.kiev.ua/handle/123456789/120536
• Journal Title: Digital Library of Periodicals of National Academy of Sciences of Ukraine
• Cite this: A treatment of the exclusion volume term in the inhomogeneous Poisson-Boltzmann theory for an ion-dipole mixture / C.W. Outhwaite, S. Lamperski // Condensed Matter Physics. — 2001. — Т. 4, № 4(28). — С. 739-748. — Бібліогр.: 28 назв. — англ.

The exclusion volume approximation in the Poisson-Boltzmann theory is analysed at the mean field level for an ion-dipole mixture against a plane, uniformly charged hard wall. An earlier treatment is extended to take account of the deviation of the exclusion volume term from the uncharged wall –...