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Structural rearrangement and change of cerium valence in cerium dioxide (CeO₂) nanocrystals

For CeO₂ nanocrystals a large number of cerium ions undergo Ce⁴⁺→ Ce³⁺ transition leading to formation of oxygen-deficient CeO₂₋x phase in the subsurface layer of nanocrystal. Such structural rearrangement leads to density gradient in ceria nanocrystals changing thereby the elastic constants of mate...

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Bibliographic Details
Published in:	Functional Materials
Date:	2016
Main Authors:	Boyko, Yu.I., Seminko, V.V., Maksimchuk, P.O., Malyukin, Yu.V.
Format:	Article
Language:	English
Published:	НТК «Інститут монокристалів» НАН України 2016
Subjects:	Characterization and properties
Online Access:	https://nasplib.isofts.kiev.ua/handle/123456789/120610
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Journal Title:	Digital Library of Periodicals of National Academy of Sciences of Ukraine
Cite this:	Structural rearrangement and change of cerium valence in cerium dioxide (CeO₂) nanocrystals / Yu.I. Boyko, V.V. Seminko, P.O. Maksimchuk, Yu.V. Malyukin // Functional Materials. — 2016. — Т. 23, № 2. — С. 202-205. — Бібліогр.: 17 назв. — англ.

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