On features of deoxidization of CsI melt with zirconium getter
Interaction of Zr getter with oxygen-containing admixtures being most abundant in molten alkali metal iodides (deoxidization) is studied. Reaction of Zr with oxide ions (in form of the corresponding alkali metal oxide) is characterized by very negative enthalpy and Gibbs energy values that make the...
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| Published in: | Functional Materials |
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| Date: | 2016 |
| Main Authors: | , , , , , , |
| Format: | Article |
| Language: | English |
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НТК «Інститут монокристалів» НАН України
2016
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| Online Access: | https://nasplib.isofts.kiev.ua/handle/123456789/120638 |
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| Journal Title: | Digital Library of Periodicals of National Academy of Sciences of Ukraine |
| Cite this: | On features of deoxidization of CsI melt with zirconium getter / Yu.N. Datsko, T.P Rebrova, V.L. Cherginets, V.A. Naumenko, A.L. Rebrov, P.V. Mateychenko, I.N. Vjunnik // Functional Materials. — 2016. — Т. 23, № 2. — С. 307-312. — Бібліогр.: 7 назв. — англ. |
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Digital Library of Periodicals of National Academy of Sciences of Ukraine| _version_ | 1862718710012182528 |
|---|---|
| author | Datsko, Yu.N. Rebrova, T.P. Cherginets, V.L. Naumenko, V.A. Rebrov, A.L. Mateychenko, P.V. Vjunnik, I.N. |
| author_facet | Datsko, Yu.N. Rebrova, T.P. Cherginets, V.L. Naumenko, V.A. Rebrov, A.L. Mateychenko, P.V. Vjunnik, I.N. |
| citation_txt | On features of deoxidization of CsI melt with zirconium getter / Yu.N. Datsko, T.P Rebrova, V.L. Cherginets, V.A. Naumenko, A.L. Rebrov, P.V. Mateychenko, I.N. Vjunnik // Functional Materials. — 2016. — Т. 23, № 2. — С. 307-312. — Бібліогр.: 7 назв. — англ. |
| collection | DSpace DC |
| container_title | Functional Materials |
| description | Interaction of Zr getter with oxygen-containing admixtures being most abundant in molten alkali metal iodides (deoxidization) is studied. Reaction of Zr with oxide ions (in form of the corresponding alkali metal oxide) is characterized by very negative enthalpy and Gibbs energy values that make the deoxidization process very favorable. Practically the interaction leads to decrease of O²⁻ concentration by a factor of ca. 6. Interaction of Zr with carbonate ions is shown both by the calculations and by experiment Ґй lead to the formation of carbon particles (suspension) in the melts that causes certain limitations of the getter treatment for the purification of practically used growth iodide melts.
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| first_indexed | 2025-12-07T18:16:23Z |
| format | Article |
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| id | nasplib_isofts_kiev_ua-123456789-120638 |
| institution | Digital Library of Periodicals of National Academy of Sciences of Ukraine |
| issn | 1027-5495 |
| language | English |
| last_indexed | 2025-12-07T18:16:23Z |
| publishDate | 2016 |
| publisher | НТК «Інститут монокристалів» НАН України |
| record_format | dspace |
| spelling | Datsko, Yu.N. Rebrova, T.P. Cherginets, V.L. Naumenko, V.A. Rebrov, A.L. Mateychenko, P.V. Vjunnik, I.N. 2017-06-12T14:32:50Z 2017-06-12T14:32:50Z 2016 On features of deoxidization of CsI melt with zirconium getter / Yu.N. Datsko, T.P Rebrova, V.L. Cherginets, V.A. Naumenko, A.L. Rebrov, P.V. Mateychenko, I.N. Vjunnik // Functional Materials. — 2016. — Т. 23, № 2. — С. 307-312. — Бібліогр.: 7 назв. — англ. 1027-5495 https://nasplib.isofts.kiev.ua/handle/123456789/120638 DOI: dx.doi.org/10.15407/fm23.02.307 Interaction of Zr getter with oxygen-containing admixtures being most abundant in molten alkali metal iodides (deoxidization) is studied. Reaction of Zr with oxide ions (in form of the corresponding alkali metal oxide) is characterized by very negative enthalpy and Gibbs energy values that make the deoxidization process very favorable. Practically the interaction leads to decrease of O²⁻ concentration by a factor of ca. 6. Interaction of Zr with carbonate ions is shown both by the calculations and by experiment Ґй lead to the formation of carbon particles (suspension) in the melts that causes certain limitations of the getter treatment for the purification of practically used growth iodide melts. en НТК «Інститут монокристалів» НАН України Functional Materials Technology On features of deoxidization of CsI melt with zirconium getter Article published earlier |
| spellingShingle | On features of deoxidization of CsI melt with zirconium getter Datsko, Yu.N. Rebrova, T.P. Cherginets, V.L. Naumenko, V.A. Rebrov, A.L. Mateychenko, P.V. Vjunnik, I.N. Technology |
| title | On features of deoxidization of CsI melt with zirconium getter |
| title_full | On features of deoxidization of CsI melt with zirconium getter |
| title_fullStr | On features of deoxidization of CsI melt with zirconium getter |
| title_full_unstemmed | On features of deoxidization of CsI melt with zirconium getter |
| title_short | On features of deoxidization of CsI melt with zirconium getter |
| title_sort | on features of deoxidization of csi melt with zirconium getter |
| topic | Technology |
| topic_facet | Technology |
| url | https://nasplib.isofts.kiev.ua/handle/123456789/120638 |
| work_keys_str_mv | AT datskoyun onfeaturesofdeoxidizationofcsimeltwithzirconiumgetter AT rebrovatp onfeaturesofdeoxidizationofcsimeltwithzirconiumgetter AT cherginetsvl onfeaturesofdeoxidizationofcsimeltwithzirconiumgetter AT naumenkova onfeaturesofdeoxidizationofcsimeltwithzirconiumgetter AT rebroval onfeaturesofdeoxidizationofcsimeltwithzirconiumgetter AT mateychenkopv onfeaturesofdeoxidizationofcsimeltwithzirconiumgetter AT vjunnikin onfeaturesofdeoxidizationofcsimeltwithzirconiumgetter |