The polymerization of acetylene on supported metal clusters

• Published in: Физика низких температур
• Date: 2006
• Main Authors: Gilb, S., Arenz, M., Heiz, U.
• Format: Article
• Language: English
• Published: Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України 2006
• Subjects: Clusters
• Online Access: https://nasplib.isofts.kiev.ua/handle/123456789/120894
• Journal Title: Digital Library of Periodicals of National Academy of Sciences of Ukraine
• Cite this: The polymerization of acetylene on supported metal clusters / S. Gilb, M. Arenz, U. Heiz // Физика низких температур. — 2006. — Т. 32, № 11. — С. 1441–1448. — Бібліогр.: 31 назв. — англ.

The polymerization of acetylene was studied by thermal programmed reaction on model catalysts consisting of size-selected Ag, Rh, and Pd atoms and Pdn (1 ≤ n ≤ 30) clusters on well-characterized MgO(111) thin films. In a single-pass heating cycle experiment, benzene, butadiene, and butane were ca...