Photovoltaic and optical properties of a polymer - PbS nanocomposite

Photovoltaic and optical properties of a polymer-PbS nanoparticles in polyvinyl alcohol (PVA) films and the effect of annealing in air at various temperatures on these properties are studied in this work. In the range of 1.0 to 3.7 eV, absorption spectra of PbS nanocomposite films are correctly fitt...

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Published in:Semiconductor Physics Quantum Electronics & Optoelectronics
Date:2005
Main Authors: Lutsyk, P., Dzura, L., Kutsenko, A., Vertsimakha, Ya., Sworakowski, J.
Format: Article
Language:English
Published: Інститут фізики напівпровідників імені В.Є. Лашкарьова НАН України 2005
Online Access:https://nasplib.isofts.kiev.ua/handle/123456789/120969
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Journal Title:Digital Library of Periodicals of National Academy of Sciences of Ukraine
Cite this:Photovoltaic and optical properties of a polymer - PbS nanocomposite / P. Lutsyk, L. Dzura, A. Kutsenko, Ya. Vertsimakha, J. Sworakowski // Semiconductor Physics Quantum Electronics & Optoelectronics. — 2005. — Т. 8, № 3. — С. 54-59. — Бібліогр.: 11 назв. — англ.

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Digital Library of Periodicals of National Academy of Sciences of Ukraine
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author Lutsyk, P.
Dzura, L.
Kutsenko, A.
Vertsimakha, Ya.
Sworakowski, J.
author_facet Lutsyk, P.
Dzura, L.
Kutsenko, A.
Vertsimakha, Ya.
Sworakowski, J.
citation_txt Photovoltaic and optical properties of a polymer - PbS nanocomposite / P. Lutsyk, L. Dzura, A. Kutsenko, Ya. Vertsimakha, J. Sworakowski // Semiconductor Physics Quantum Electronics & Optoelectronics. — 2005. — Т. 8, № 3. — С. 54-59. — Бібліогр.: 11 назв. — англ.
collection DSpace DC
container_title Semiconductor Physics Quantum Electronics & Optoelectronics
description Photovoltaic and optical properties of a polymer-PbS nanoparticles in polyvinyl alcohol (PVA) films and the effect of annealing in air at various temperatures on these properties are studied in this work. In the range of 1.0 to 3.7 eV, absorption spectra of PbS nanocomposite films are correctly fitted by five Gaussian bands peaking at 1.5, 1.84, 2.41, 3.06, and 3.58 eV. A characteristic feature of the films is the presence of green and blue luminescence with intensity maxima at 2.25 and 3.02 eV, respectively. The luminescence intensity strongly depends on the excitation energy and the annealing temperature in air. The highest intensity of the green luminescence is observed under the excitation with 2.35 eV radiation, whereas the intensity of the blue luminescence peaks under 3.46 eV excitation. After annealing at 370 K, the intensity of the green luminescence decreases a few times whereas the intensity of the blue emission increases. The photovoltaic sensitivity of the PbS nanocomposite films depends on the annealing conditions, attaining the maximum after annealing in air at approximately glass transition temperature of PVA (370 K). The spectral range of the photosensitivity of PbS nanocomposite films is wider than that of CdSe- and CuInS₂-polymer nanocomposite films.
first_indexed 2025-12-07T13:15:03Z
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institution Digital Library of Periodicals of National Academy of Sciences of Ukraine
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language English
last_indexed 2025-12-07T13:15:03Z
publishDate 2005
publisher Інститут фізики напівпровідників імені В.Є. Лашкарьова НАН України
record_format dspace
spelling Lutsyk, P.
Dzura, L.
Kutsenko, A.
Vertsimakha, Ya.
Sworakowski, J.
2017-06-13T11:31:00Z
2017-06-13T11:31:00Z
2005
Photovoltaic and optical properties of a polymer - PbS nanocomposite / P. Lutsyk, L. Dzura, A. Kutsenko, Ya. Vertsimakha, J. Sworakowski // Semiconductor Physics Quantum Electronics & Optoelectronics. — 2005. — Т. 8, № 3. — С. 54-59. — Бібліогр.: 11 назв. — англ.
1560-8034
PACS: 73.50. Pz, 78.20. –e, 78.67. Bf.
https://nasplib.isofts.kiev.ua/handle/123456789/120969
Photovoltaic and optical properties of a polymer-PbS nanoparticles in polyvinyl alcohol (PVA) films and the effect of annealing in air at various temperatures on these properties are studied in this work. In the range of 1.0 to 3.7 eV, absorption spectra of PbS nanocomposite films are correctly fitted by five Gaussian bands peaking at 1.5, 1.84, 2.41, 3.06, and 3.58 eV. A characteristic feature of the films is the presence of green and blue luminescence with intensity maxima at 2.25 and 3.02 eV, respectively. The luminescence intensity strongly depends on the excitation energy and the annealing temperature in air. The highest intensity of the green luminescence is observed under the excitation with 2.35 eV radiation, whereas the intensity of the blue luminescence peaks under 3.46 eV excitation. After annealing at 370 K, the intensity of the green luminescence decreases a few times whereas the intensity of the blue emission increases. The photovoltaic sensitivity of the PbS nanocomposite films depends on the annealing conditions, attaining the maximum after annealing in air at approximately glass transition temperature of PVA (370 K). The spectral range of the photosensitivity of PbS nanocomposite films is wider than that of CdSe- and CuInS₂-polymer nanocomposite films.
en
Інститут фізики напівпровідників імені В.Є. Лашкарьова НАН України
Semiconductor Physics Quantum Electronics & Optoelectronics
Photovoltaic and optical properties of a polymer - PbS nanocomposite
Article
published earlier
spellingShingle Photovoltaic and optical properties of a polymer - PbS nanocomposite
Lutsyk, P.
Dzura, L.
Kutsenko, A.
Vertsimakha, Ya.
Sworakowski, J.
title Photovoltaic and optical properties of a polymer - PbS nanocomposite
title_full Photovoltaic and optical properties of a polymer - PbS nanocomposite
title_fullStr Photovoltaic and optical properties of a polymer - PbS nanocomposite
title_full_unstemmed Photovoltaic and optical properties of a polymer - PbS nanocomposite
title_short Photovoltaic and optical properties of a polymer - PbS nanocomposite
title_sort photovoltaic and optical properties of a polymer - pbs nanocomposite
url https://nasplib.isofts.kiev.ua/handle/123456789/120969
work_keys_str_mv AT lutsykp photovoltaicandopticalpropertiesofapolymerpbsnanocomposite
AT dzural photovoltaicandopticalpropertiesofapolymerpbsnanocomposite
AT kutsenkoa photovoltaicandopticalpropertiesofapolymerpbsnanocomposite
AT vertsimakhaya photovoltaicandopticalpropertiesofapolymerpbsnanocomposite
AT sworakowskij photovoltaicandopticalpropertiesofapolymerpbsnanocomposite