On collective variables method in the microscopic theory of alloys

• Published in: Condensed Matter Physics
• Date: 2000
• Main Author: Gurskii, Z.
• Format: Article
• Language: English
• Published: Інститут фізики конденсованих систем НАН України 2000
• Online Access: https://nasplib.isofts.kiev.ua/handle/123456789/121020
• Journal Title: Digital Library of Periodicals of National Academy of Sciences of Ukraine
• Cite this: On collective variables method in the microscopic theory of alloys / Z. Gurskii // Condensed Matter Physics. — 2000. — Т. 3, № 2(22). — С. 307-334. — Бібліогр.: 61 назв. — англ.

Ab initio approach is developed for thermodynamical investigations of disordered binary alloys. It is based on utilizing the collective variables method. The explicit expression for the free energy and the equation determining the alloy components' chemical potentials are obtained within the ri...