PEPC sensitization with polymethine dyes: 1. Squarylium dyes of indole row as efficient sensitizers for red region of optical spectrum
Phase hologram recording is based on photoconductivity which appears in polymer molecular semiconductor film being exposed to light [1]. Photocurrent threshold depends on energy gap between valence and conduction bands of a photoconductor (PC). Energy gap of PCs based on poly-N-epoxypropylcarbazole...
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| Veröffentlicht in: | Semiconductor Physics Quantum Electronics & Optoelectronics |
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| Datum: | 2000 |
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Інститут фізики напівпровідників імені В.Є. Лашкарьова НАН України
2000
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| Zitieren: | PEPC sensitization with polymethine dyes: 1. Squarylium dyes of indole row as efficient sensitizers for red region of optical spectrum / M.Yu. Bazhenov, P.I. Golod, V.V. Grabovskyya, V.V. Kurdyukov, A.I. Tolmachev, A.Ya. Ilchenko, N.I. Sokolov, G.Zahaykevich // Semiconductor Physics Quantum Electronics & Optoelectronics. — 2000. — Т. 3, № 3. — С. 423-425. — Бібліогр.: 14 назв. — англ. |
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Bazhenov, M.Yu. Golod, P.I. Grabovskyy, V.V. Kurdyukov, V.V. Tolmachev, A.I. Ilchenko, A.Ya. Sokolov, N.I. Zahaykevich, G. 2017-06-13T15:30:43Z 2017-06-13T15:30:43Z 2000 PEPC sensitization with polymethine dyes: 1. Squarylium dyes of indole row as efficient sensitizers for red region of optical spectrum / M.Yu. Bazhenov, P.I. Golod, V.V. Grabovskyya, V.V. Kurdyukov, A.I. Tolmachev, A.Ya. Ilchenko, N.I. Sokolov, G.Zahaykevich // Semiconductor Physics Quantum Electronics & Optoelectronics. — 2000. — Т. 3, № 3. — С. 423-425. — Бібліогр.: 14 назв. — англ. 1560-8034 PACS: 42.70.Ln https://nasplib.isofts.kiev.ua/handle/123456789/121129 Phase hologram recording is based on photoconductivity which appears in polymer molecular semiconductor film being exposed to light [1]. Photocurrent threshold depends on energy gap between valence and conduction bands of a photoconductor (PC). Energy gap of PCs based on poly-N-epoxypropylcarbazole (PEPC) which are widely used for hologram recording is rather large. That is why recording on pure PEPC film may be only in UV range of optical spectra. Thus, sensitization of PEPC with different dyes to make it sensitive to visible range is usually used for practice. Nowadays structural PEPC sensitization with fluorene electron acceptors is widely used for holographic recording material synthesis [2]. There are few publications about organic dye sensitization of PEPC due to low efficiency of first dyes used. Main obstacle to practical use of dyes like rhodamine 6G, malachite green and other 3-phenilmethans, is low diffraction efficiency (η) of hologram due to large charges thermo-relaxation in single-layer PEPC films. We have investigated some polymethine dyes like squarylium with indole residues for PEPC sensitization in red range of visible spectrum. These dyes are under intense interest due to its promising usefulness for xerography and optical recording. Particularity of such dyes is its intra-ionoide, actually bipolar, structure. en Інститут фізики напівпровідників імені В.Є. Лашкарьова НАН України Semiconductor Physics Quantum Electronics & Optoelectronics PEPC sensitization with polymethine dyes: 1. Squarylium dyes of indole row as efficient sensitizers for red region of optical spectrum Article published earlier |
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Digital Library of Periodicals of National Academy of Sciences of Ukraine |
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| title |
PEPC sensitization with polymethine dyes: 1. Squarylium dyes of indole row as efficient sensitizers for red region of optical spectrum |
| spellingShingle |
PEPC sensitization with polymethine dyes: 1. Squarylium dyes of indole row as efficient sensitizers for red region of optical spectrum Bazhenov, M.Yu. Golod, P.I. Grabovskyy, V.V. Kurdyukov, V.V. Tolmachev, A.I. Ilchenko, A.Ya. Sokolov, N.I. Zahaykevich, G. |
| title_short |
PEPC sensitization with polymethine dyes: 1. Squarylium dyes of indole row as efficient sensitizers for red region of optical spectrum |
| title_full |
PEPC sensitization with polymethine dyes: 1. Squarylium dyes of indole row as efficient sensitizers for red region of optical spectrum |
| title_fullStr |
PEPC sensitization with polymethine dyes: 1. Squarylium dyes of indole row as efficient sensitizers for red region of optical spectrum |
| title_full_unstemmed |
PEPC sensitization with polymethine dyes: 1. Squarylium dyes of indole row as efficient sensitizers for red region of optical spectrum |
| title_sort |
pepc sensitization with polymethine dyes: 1. squarylium dyes of indole row as efficient sensitizers for red region of optical spectrum |
| author |
Bazhenov, M.Yu. Golod, P.I. Grabovskyy, V.V. Kurdyukov, V.V. Tolmachev, A.I. Ilchenko, A.Ya. Sokolov, N.I. Zahaykevich, G. |
| author_facet |
Bazhenov, M.Yu. Golod, P.I. Grabovskyy, V.V. Kurdyukov, V.V. Tolmachev, A.I. Ilchenko, A.Ya. Sokolov, N.I. Zahaykevich, G. |
| publishDate |
2000 |
| language |
English |
| container_title |
Semiconductor Physics Quantum Electronics & Optoelectronics |
| publisher |
Інститут фізики напівпровідників імені В.Є. Лашкарьова НАН України |
| format |
Article |
| description |
Phase hologram recording is based on photoconductivity which appears in polymer molecular semiconductor film being exposed to light [1]. Photocurrent threshold depends on energy gap between valence and conduction bands of a photoconductor (PC). Energy gap of PCs based on poly-N-epoxypropylcarbazole (PEPC) which are widely used for hologram recording is rather large. That is why recording on pure PEPC film may be only in UV range of optical spectra. Thus, sensitization of PEPC with different dyes to make it sensitive to visible range is usually used for practice. Nowadays structural PEPC sensitization with fluorene electron acceptors is widely used for holographic recording material synthesis [2]. There are few publications about organic dye sensitization of PEPC due to low efficiency of first dyes used. Main obstacle to practical use of dyes like rhodamine 6G, malachite green and other 3-phenilmethans, is low diffraction efficiency (η) of hologram due to large charges thermo-relaxation in single-layer PEPC films. We have investigated some polymethine dyes like squarylium with indole residues for PEPC sensitization in red range of visible spectrum. These dyes are under intense interest due to its promising usefulness for xerography and optical recording. Particularity of such dyes is its intra-ionoide, actually bipolar, structure.
|
| issn |
1560-8034 |
| url |
https://nasplib.isofts.kiev.ua/handle/123456789/121129 |
| citation_txt |
PEPC sensitization with polymethine dyes: 1. Squarylium dyes of indole row as efficient sensitizers for red region of optical spectrum / M.Yu. Bazhenov, P.I. Golod, V.V. Grabovskyya, V.V. Kurdyukov, A.I. Tolmachev, A.Ya. Ilchenko, N.I. Sokolov, G.Zahaykevich // Semiconductor Physics Quantum Electronics & Optoelectronics. — 2000. — Т. 3, № 3. — С. 423-425. — Бібліогр.: 14 назв. — англ. |
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| first_indexed |
2025-11-27T16:51:31Z |
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2025-11-27T16:51:31Z |
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