Study of non-reversible photostructural transformations in As₄₀S₆₀-xSex layers applied for fabrication of holographic protective elements

Thin vacuum-evaporated layers of As₄₀S₆₀-xSex composition are investigated using Raman spectroscopy from the viewpoint of thermo- and photostructural transformations in them. These transformations are considered as changes in their network structure including three types of piramidal units AsS₃/₂, A...

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Veröffentlicht in:Semiconductor Physics Quantum Electronics & Optoelectronics
Datum:2002
Hauptverfasser: Stronski, A.V., Vlcek, M., Kostyukevych, S.A., Tomchuk, V.M., Kostyukevych, E.V., Svechnikov, S.V., Kudryavtsev, A.A., Moskalenko, N.L., Koptyukh, A.A.
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Sprache:Englisch
Veröffentlicht: Інститут фізики напівпровідників імені В.Є. Лашкарьова НАН України 2002
Online Zugang:https://nasplib.isofts.kiev.ua/handle/123456789/121298
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Zitieren:Study of non-reversible photostructural transformations in As₄₀S₆₀-xSex layers applied for fabrication of holographic protective elements / A.V. Stronski, M. Vlcek, S.A. Kostyukevych, V.M. Tomchuk, E.V. Kostyukevych, S.V. Svechnikov, A.A. Kudryavtsev, N.L. Moskalenko, A.A. Koptyukh // Semiconductor Physics Quantum Electronics & Optoelectronics. — 2002. — Т. 5, № 3. — С. 284-287. — Бібліогр.: 17 назв. — англ.

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Digital Library of Periodicals of National Academy of Sciences of Ukraine
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author Stronski, A.V.
Vlcek, M.
Kostyukevych, S.A.
Tomchuk, V.M.
Kostyukevych, E.V.
Svechnikov, S.V.
Kudryavtsev, A.A.
Moskalenko, N.L.
Koptyukh, A.A.
author_facet Stronski, A.V.
Vlcek, M.
Kostyukevych, S.A.
Tomchuk, V.M.
Kostyukevych, E.V.
Svechnikov, S.V.
Kudryavtsev, A.A.
Moskalenko, N.L.
Koptyukh, A.A.
citation_txt Study of non-reversible photostructural transformations in As₄₀S₆₀-xSex layers applied for fabrication of holographic protective elements / A.V. Stronski, M. Vlcek, S.A. Kostyukevych, V.M. Tomchuk, E.V. Kostyukevych, S.V. Svechnikov, A.A. Kudryavtsev, N.L. Moskalenko, A.A. Koptyukh // Semiconductor Physics Quantum Electronics & Optoelectronics. — 2002. — Т. 5, № 3. — С. 284-287. — Бібліогр.: 17 назв. — англ.
collection DSpace DC
container_title Semiconductor Physics Quantum Electronics & Optoelectronics
description Thin vacuum-evaporated layers of As₄₀S₆₀-xSex composition are investigated using Raman spectroscopy from the viewpoint of thermo- and photostructural transformations in them. These transformations are considered as changes in their network structure including three types of piramidal units AsS₃/₂, AsSe₃/₂ and AsS(Se)₃/₂ as well as As₄S(Se)₄ and S(Se)n fragments in its initial state. Annealing or light exposure result in polymerization of the molecular groups and the decreasing number of homopolar bonds, which is thermodynamically favorable. Characteristics of sensivity to photon and electron exposure were investigated. Diffraction efficiency perfomances of a microrelief fabricated using these layers are presented.
first_indexed 2025-12-07T17:25:38Z
format Article
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institution Digital Library of Periodicals of National Academy of Sciences of Ukraine
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language English
last_indexed 2025-12-07T17:25:38Z
publishDate 2002
publisher Інститут фізики напівпровідників імені В.Є. Лашкарьова НАН України
record_format dspace
spelling Stronski, A.V.
Vlcek, M.
Kostyukevych, S.A.
Tomchuk, V.M.
Kostyukevych, E.V.
Svechnikov, S.V.
Kudryavtsev, A.A.
Moskalenko, N.L.
Koptyukh, A.A.
2017-06-13T20:39:28Z
2017-06-13T20:39:28Z
2002
Study of non-reversible photostructural transformations in As₄₀S₆₀-xSex layers applied for fabrication of holographic protective elements / A.V. Stronski, M. Vlcek, S.A. Kostyukevych, V.M. Tomchuk, E.V. Kostyukevych, S.V. Svechnikov, A.A. Kudryavtsev, N.L. Moskalenko, A.A. Koptyukh // Semiconductor Physics Quantum Electronics & Optoelectronics. — 2002. — Т. 5, № 3. — С. 284-287. — Бібліогр.: 17 назв. — англ.
1560-8034
PACS: 42.40.Eq, 78.30.Ly
https://nasplib.isofts.kiev.ua/handle/123456789/121298
Thin vacuum-evaporated layers of As₄₀S₆₀-xSex composition are investigated using Raman spectroscopy from the viewpoint of thermo- and photostructural transformations in them. These transformations are considered as changes in their network structure including three types of piramidal units AsS₃/₂, AsSe₃/₂ and AsS(Se)₃/₂ as well as As₄S(Se)₄ and S(Se)n fragments in its initial state. Annealing or light exposure result in polymerization of the molecular groups and the decreasing number of homopolar bonds, which is thermodynamically favorable. Characteristics of sensivity to photon and electron exposure were investigated. Diffraction efficiency perfomances of a microrelief fabricated using these layers are presented.
The authors thank Ministry of Education and Science of Ukraine for financial support and express his gratitude to colleagues from Institute of Semiconductor Physics (NAS of Ukraine), Specialized Enterprizes "Holography" and "Optronics" for their help in carrying out the holographic experiments.
en
Інститут фізики напівпровідників імені В.Є. Лашкарьова НАН України
Semiconductor Physics Quantum Electronics & Optoelectronics
Study of non-reversible photostructural transformations in As₄₀S₆₀-xSex layers applied for fabrication of holographic protective elements
Article
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spellingShingle Study of non-reversible photostructural transformations in As₄₀S₆₀-xSex layers applied for fabrication of holographic protective elements
Stronski, A.V.
Vlcek, M.
Kostyukevych, S.A.
Tomchuk, V.M.
Kostyukevych, E.V.
Svechnikov, S.V.
Kudryavtsev, A.A.
Moskalenko, N.L.
Koptyukh, A.A.
title Study of non-reversible photostructural transformations in As₄₀S₆₀-xSex layers applied for fabrication of holographic protective elements
title_full Study of non-reversible photostructural transformations in As₄₀S₆₀-xSex layers applied for fabrication of holographic protective elements
title_fullStr Study of non-reversible photostructural transformations in As₄₀S₆₀-xSex layers applied for fabrication of holographic protective elements
title_full_unstemmed Study of non-reversible photostructural transformations in As₄₀S₆₀-xSex layers applied for fabrication of holographic protective elements
title_short Study of non-reversible photostructural transformations in As₄₀S₆₀-xSex layers applied for fabrication of holographic protective elements
title_sort study of non-reversible photostructural transformations in as₄₀s₆₀-xsex layers applied for fabrication of holographic protective elements
url https://nasplib.isofts.kiev.ua/handle/123456789/121298
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