EPR spectra of deuterated methyl radicals trapped in low temperature matrices
EPR spectra of CHD₂, and CD₃ radicals have been investigated in low-temperature matrices of H₂, D₂, and Ne at temperatures 1.6–4.2 K. A method of condensation from the gas phase on a cold substrate has been used. With decreasing sample temperature, a transformation of the shape of the CD₃ spectru...
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| Datum: | 2005 |
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| Format: | Artikel |
| Sprache: | English |
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Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України
2005
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| Zitieren: | EPR spectra of deuterated methyl radicals trapped in low temperature matrices / Yu.A. Dmitriev // Физика низких температур. — 2005. — Т. 31, № 5. — С. 558-564. — Бібліогр.: 13 назв. — англ. |
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Dmitriev, Yu.A. 2017-06-14T11:50:21Z 2017-06-14T11:50:21Z 2005 EPR spectra of deuterated methyl radicals trapped in low temperature matrices / Yu.A. Dmitriev // Физика низких температур. — 2005. — Т. 31, № 5. — С. 558-564. — Бібліогр.: 13 назв. — англ. 0132-6414 PACS: 32.30.–r, 76.30.–v https://nasplib.isofts.kiev.ua/handle/123456789/121463 EPR spectra of CHD₂, and CD₃ radicals have been investigated in low-temperature matrices of H₂, D₂, and Ne at temperatures 1.6–4.2 K. A method of condensation from the gas phase on a cold substrate has been used. With decreasing sample temperature, a transformation of the shape of the CD₃ spectrum in H₂, D₂, and Ne matrices and CHD₂ spectrum in H₂ and Ne was observed. This transformation was reversible in the above temperature range. The temperature effects are explained as reflecting a change in the populations of the lowest rotational states of the radicals. Based on the present data and known results for deuterated methyl radicals in Ar obtained in photolytic experiments, we compare the temperature behavior of the EPR spectra for the radicals trapped in various matrices. As a result an existence of a hindering barrier for the radical rotation is suggested. en Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України Физика низких температур Физические свойства криокристаллов EPR spectra of deuterated methyl radicals trapped in low temperature matrices Article published earlier |
| institution |
Digital Library of Periodicals of National Academy of Sciences of Ukraine |
| collection |
DSpace DC |
| title |
EPR spectra of deuterated methyl radicals trapped in low temperature matrices |
| spellingShingle |
EPR spectra of deuterated methyl radicals trapped in low temperature matrices Dmitriev, Yu.A. Физические свойства криокристаллов |
| title_short |
EPR spectra of deuterated methyl radicals trapped in low temperature matrices |
| title_full |
EPR spectra of deuterated methyl radicals trapped in low temperature matrices |
| title_fullStr |
EPR spectra of deuterated methyl radicals trapped in low temperature matrices |
| title_full_unstemmed |
EPR spectra of deuterated methyl radicals trapped in low temperature matrices |
| title_sort |
epr spectra of deuterated methyl radicals trapped in low temperature matrices |
| author |
Dmitriev, Yu.A. |
| author_facet |
Dmitriev, Yu.A. |
| topic |
Физические свойства криокристаллов |
| topic_facet |
Физические свойства криокристаллов |
| publishDate |
2005 |
| language |
English |
| container_title |
Физика низких температур |
| publisher |
Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України |
| format |
Article |
| description |
EPR spectra of CHD₂, and CD₃ radicals have been investigated in low-temperature matrices of
H₂, D₂, and Ne at temperatures 1.6–4.2 K. A method of condensation from the gas phase on a cold
substrate has been used. With decreasing sample temperature, a transformation of the shape of the
CD₃ spectrum in H₂, D₂, and Ne matrices and CHD₂ spectrum in H₂ and Ne was observed. This
transformation was reversible in the above temperature range. The temperature effects are explained
as reflecting a change in the populations of the lowest rotational states of the radicals.
Based on the present data and known results for deuterated methyl radicals in Ar obtained in
photolytic experiments, we compare the temperature behavior of the EPR spectra for the radicals
trapped in various matrices. As a result an existence of a hindering barrier for the radical rotation
is suggested.
|
| issn |
0132-6414 |
| url |
https://nasplib.isofts.kiev.ua/handle/123456789/121463 |
| citation_txt |
EPR spectra of deuterated methyl radicals trapped in low temperature matrices / Yu.A. Dmitriev // Физика низких температур. — 2005. — Т. 31, № 5. — С. 558-564. — Бібліогр.: 13 назв. — англ. |
| work_keys_str_mv |
AT dmitrievyua eprspectraofdeuteratedmethylradicalstrappedinlowtemperaturematrices |
| first_indexed |
2025-11-27T18:36:39Z |
| last_indexed |
2025-11-27T18:36:39Z |
| _version_ |
1850852650296279040 |