Thermal properties of solid solution of manganese (II) -cobalt (II) diphosphate
The composition, temperature ranges of formation and thermal stability of heat treatment products of solid solution with the general formula (Mn₁-xCox)₂P₂O₇•5H₂O (0 leq; x≤0.41) in the range of 298-1273 K were determined. The cation nature effect on them was concretized. The end product of the heat...
Gespeichert in:
| Veröffentlicht in: | Functional Materials |
|---|---|
| Datum: | 2016 |
| Hauptverfasser: | , |
| Format: | Artikel |
| Sprache: | English |
| Veröffentlicht: |
НТК «Інститут монокристалів» НАН України
2016
|
| Schlagworte: | |
| Online Zugang: | https://nasplib.isofts.kiev.ua/handle/123456789/121494 |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| Назва журналу: | Digital Library of Periodicals of National Academy of Sciences of Ukraine |
| Zitieren: | Thermal properties of solid solution of manganese (II) -cobalt (II) diphosphate / N.M. Antraptseva, N.V. Solod // Functional Materials. — 2016. — Т. 23, № 4. — С. 657-664. — Бібліогр.: 14 назв. — англ. |
Institution
Digital Library of Periodicals of National Academy of Sciences of Ukraine| id |
nasplib_isofts_kiev_ua-123456789-121494 |
|---|---|
| record_format |
dspace |
| spelling |
Antraptseva, N.M. Solod, N.V. 2017-06-14T14:11:42Z 2017-06-14T14:11:42Z 2016 Thermal properties of solid solution of manganese (II) -cobalt (II) diphosphate / N.M. Antraptseva, N.V. Solod // Functional Materials. — 2016. — Т. 23, № 4. — С. 657-664. — Бібліогр.: 14 назв. — англ. 1027-5495 DOI: doi.org/10.15407/fm23.04.657 https://nasplib.isofts.kiev.ua/handle/123456789/121494 The composition, temperature ranges of formation and thermal stability of heat treatment products of solid solution with the general formula (Mn₁-xCox)₂P₂O₇•5H₂O (0 leq; x≤0.41) in the range of 298-1273 K were determined. The cation nature effect on them was concretized. The end product of the heat treatment - solid solution of anhydrous diphosphates with composition β-(Mn₁-xCox)₂P₂O₇, 0 &leq& x≤ 0.41 (space group C 2/m, Z = 2) - was identified. It was shown, that its formation is realized in two directions. The first of them is realized by 69-66 % due to dehydration of initial crystallohydrate (Mn₁-xCox)₂P₂O₇•5H₂O. According to the second direction, 31-34 % β-(Mn₁-xCox)₂P₂O₇ is formed through solid phase reaction of the intermediate dehydration products. The sequence of thermal and structural transformations, which accompany the heat treatment of the diphosphates (Mn₁-xCox)₂P₂O₇•5H₂O (0 ≤x≤0.41), was proposed. en НТК «Інститут монокристалів» НАН України Functional Materials Technology Thermal properties of solid solution of manganese (II) -cobalt (II) diphosphate Article published earlier |
| institution |
Digital Library of Periodicals of National Academy of Sciences of Ukraine |
| collection |
DSpace DC |
| title |
Thermal properties of solid solution of manganese (II) -cobalt (II) diphosphate |
| spellingShingle |
Thermal properties of solid solution of manganese (II) -cobalt (II) diphosphate Antraptseva, N.M. Solod, N.V. Technology |
| title_short |
Thermal properties of solid solution of manganese (II) -cobalt (II) diphosphate |
| title_full |
Thermal properties of solid solution of manganese (II) -cobalt (II) diphosphate |
| title_fullStr |
Thermal properties of solid solution of manganese (II) -cobalt (II) diphosphate |
| title_full_unstemmed |
Thermal properties of solid solution of manganese (II) -cobalt (II) diphosphate |
| title_sort |
thermal properties of solid solution of manganese (ii) -cobalt (ii) diphosphate |
| author |
Antraptseva, N.M. Solod, N.V. |
| author_facet |
Antraptseva, N.M. Solod, N.V. |
| topic |
Technology |
| topic_facet |
Technology |
| publishDate |
2016 |
| language |
English |
| container_title |
Functional Materials |
| publisher |
НТК «Інститут монокристалів» НАН України |
| format |
Article |
| description |
The composition, temperature ranges of formation and thermal stability of heat treatment products of solid solution with the general formula (Mn₁-xCox)₂P₂O₇•5H₂O (0 leq; x≤0.41) in the range of 298-1273 K were determined. The cation nature effect on them was concretized. The end product of the heat treatment - solid solution of anhydrous diphosphates with composition β-(Mn₁-xCox)₂P₂O₇, 0 &leq& x≤ 0.41 (space group C 2/m, Z = 2) - was identified. It was shown, that its formation is realized in two directions. The first of them is realized by 69-66 % due to dehydration of initial crystallohydrate (Mn₁-xCox)₂P₂O₇•5H₂O. According to the second direction, 31-34 % β-(Mn₁-xCox)₂P₂O₇ is formed through solid phase reaction of the intermediate dehydration products. The sequence of thermal and structural transformations, which accompany the heat treatment of the diphosphates (Mn₁-xCox)₂P₂O₇•5H₂O (0 ≤x≤0.41), was proposed.
|
| issn |
1027-5495 |
| url |
https://nasplib.isofts.kiev.ua/handle/123456789/121494 |
| citation_txt |
Thermal properties of solid solution of manganese (II) -cobalt (II) diphosphate / N.M. Antraptseva, N.V. Solod // Functional Materials. — 2016. — Т. 23, № 4. — С. 657-664. — Бібліогр.: 14 назв. — англ. |
| work_keys_str_mv |
AT antraptsevanm thermalpropertiesofsolidsolutionofmanganeseiicobaltiidiphosphate AT solodnv thermalpropertiesofsolidsolutionofmanganeseiicobaltiidiphosphate |
| first_indexed |
2025-12-01T08:39:31Z |
| last_indexed |
2025-12-01T08:39:31Z |
| _version_ |
1850859727824617473 |