Thermal properties of solid solution of manganese (II) -cobalt (II) diphosphate
The composition, temperature ranges of formation and thermal stability of heat treatment products of solid solution with the general formula (Mn₁-xCox)₂P₂O₇•5H₂O (0 leq; x≤0.41) in the range of 298-1273 K were determined. The cation nature effect on them was concretized. The end product of the heat...
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| Published in: | Functional Materials |
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| Date: | 2016 |
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| Format: | Article |
| Language: | English |
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НТК «Інститут монокристалів» НАН України
2016
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| Online Access: | https://nasplib.isofts.kiev.ua/handle/123456789/121494 |
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| Journal Title: | Digital Library of Periodicals of National Academy of Sciences of Ukraine |
| Cite this: | Thermal properties of solid solution of manganese (II) -cobalt (II) diphosphate / N.M. Antraptseva, N.V. Solod // Functional Materials. — 2016. — Т. 23, № 4. — С. 657-664. — Бібліогр.: 14 назв. — англ. |
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Digital Library of Periodicals of National Academy of Sciences of Ukraine| _version_ | 1862643802076872704 |
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| author | Antraptseva, N.M. Solod, N.V. |
| author_facet | Antraptseva, N.M. Solod, N.V. |
| citation_txt | Thermal properties of solid solution of manganese (II) -cobalt (II) diphosphate / N.M. Antraptseva, N.V. Solod // Functional Materials. — 2016. — Т. 23, № 4. — С. 657-664. — Бібліогр.: 14 назв. — англ. |
| collection | DSpace DC |
| container_title | Functional Materials |
| description | The composition, temperature ranges of formation and thermal stability of heat treatment products of solid solution with the general formula (Mn₁-xCox)₂P₂O₇•5H₂O (0 leq; x≤0.41) in the range of 298-1273 K were determined. The cation nature effect on them was concretized. The end product of the heat treatment - solid solution of anhydrous diphosphates with composition β-(Mn₁-xCox)₂P₂O₇, 0 &leq& x≤ 0.41 (space group C 2/m, Z = 2) - was identified. It was shown, that its formation is realized in two directions. The first of them is realized by 69-66 % due to dehydration of initial crystallohydrate (Mn₁-xCox)₂P₂O₇•5H₂O. According to the second direction, 31-34 % β-(Mn₁-xCox)₂P₂O₇ is formed through solid phase reaction of the intermediate dehydration products. The sequence of thermal and structural transformations, which accompany the heat treatment of the diphosphates (Mn₁-xCox)₂P₂O₇•5H₂O (0 ≤x≤0.41), was proposed.
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| first_indexed | 2025-12-01T08:39:31Z |
| format | Article |
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| id | nasplib_isofts_kiev_ua-123456789-121494 |
| institution | Digital Library of Periodicals of National Academy of Sciences of Ukraine |
| issn | 1027-5495 |
| language | English |
| last_indexed | 2025-12-01T08:39:31Z |
| publishDate | 2016 |
| publisher | НТК «Інститут монокристалів» НАН України |
| record_format | dspace |
| spelling | Antraptseva, N.M. Solod, N.V. 2017-06-14T14:11:42Z 2017-06-14T14:11:42Z 2016 Thermal properties of solid solution of manganese (II) -cobalt (II) diphosphate / N.M. Antraptseva, N.V. Solod // Functional Materials. — 2016. — Т. 23, № 4. — С. 657-664. — Бібліогр.: 14 назв. — англ. 1027-5495 DOI: doi.org/10.15407/fm23.04.657 https://nasplib.isofts.kiev.ua/handle/123456789/121494 The composition, temperature ranges of formation and thermal stability of heat treatment products of solid solution with the general formula (Mn₁-xCox)₂P₂O₇•5H₂O (0 leq; x≤0.41) in the range of 298-1273 K were determined. The cation nature effect on them was concretized. The end product of the heat treatment - solid solution of anhydrous diphosphates with composition β-(Mn₁-xCox)₂P₂O₇, 0 &leq& x≤ 0.41 (space group C 2/m, Z = 2) - was identified. It was shown, that its formation is realized in two directions. The first of them is realized by 69-66 % due to dehydration of initial crystallohydrate (Mn₁-xCox)₂P₂O₇•5H₂O. According to the second direction, 31-34 % β-(Mn₁-xCox)₂P₂O₇ is formed through solid phase reaction of the intermediate dehydration products. The sequence of thermal and structural transformations, which accompany the heat treatment of the diphosphates (Mn₁-xCox)₂P₂O₇•5H₂O (0 ≤x≤0.41), was proposed. en НТК «Інститут монокристалів» НАН України Functional Materials Technology Thermal properties of solid solution of manganese (II) -cobalt (II) diphosphate Article published earlier |
| spellingShingle | Thermal properties of solid solution of manganese (II) -cobalt (II) diphosphate Antraptseva, N.M. Solod, N.V. Technology |
| title | Thermal properties of solid solution of manganese (II) -cobalt (II) diphosphate |
| title_full | Thermal properties of solid solution of manganese (II) -cobalt (II) diphosphate |
| title_fullStr | Thermal properties of solid solution of manganese (II) -cobalt (II) diphosphate |
| title_full_unstemmed | Thermal properties of solid solution of manganese (II) -cobalt (II) diphosphate |
| title_short | Thermal properties of solid solution of manganese (II) -cobalt (II) diphosphate |
| title_sort | thermal properties of solid solution of manganese (ii) -cobalt (ii) diphosphate |
| topic | Technology |
| topic_facet | Technology |
| url | https://nasplib.isofts.kiev.ua/handle/123456789/121494 |
| work_keys_str_mv | AT antraptsevanm thermalpropertiesofsolidsolutionofmanganeseiicobaltiidiphosphate AT solodnv thermalpropertiesofsolidsolutionofmanganeseiicobaltiidiphosphate |