Low-temperature directed crystallization as a realization of Green Chemistry principles.

It is proposed a hybrid method for determination of water using low temperature directed crystallization. The length of the opaque upper part of obtained ice ingot depends on total salinity of water and serves as an analytical signal. Simultaneously the presence of dominant anions can be visually de...

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Veröffentlicht in:Functional Materials
Datum:2016
1. Verfasser: Eksperiandova, L.P.
Format: Artikel
Sprache:Englisch
Veröffentlicht: НТК «Інститут монокристалів» НАН України 2016
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Online Zugang:https://nasplib.isofts.kiev.ua/handle/123456789/121498
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Назва журналу:Digital Library of Periodicals of National Academy of Sciences of Ukraine
Zitieren:Low-temperature directed crystallization as a realization of Green Chemistry principles. / L.P. Eksperiandova // Functional Materials. — 2016. — Т. 23, № 4. — С. 676-681. — Бібліогр.: 17 назв. — англ.

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Digital Library of Periodicals of National Academy of Sciences of Ukraine
Beschreibung
Zusammenfassung:It is proposed a hybrid method for determination of water using low temperature directed crystallization. The length of the opaque upper part of obtained ice ingot depends on total salinity of water and serves as an analytical signal. Simultaneously the presence of dominant anions can be visually determined by configuration of the opaque part. The concentrate of micro-impurities localized after the crystallization in the upper part can be separated from the ice ingot and left to the following analysis. The method is compared favorably with such standard methods as gravimetry and conductometry used for water salinity determination. The reagentless method complies with the principles of Green Chemistry, since its application does not lead to pollution of the environment.
ISSN:1027-5495