Influence of the presence of a fluxing agent and its composition on the spectral characteristics of ZnS(Cu) obtained by self-propagating high-temperature synthesis
Investigated in this work were the photoluminescence spectra and luminescence excitation spectra of powered ZnS:Cu, obtained using the method of selfpropagating high-temperature synthesis (SHS) with addition of NaCl and MgCl₂ as a fluxing agent into the charge and without them. It was shown that inc...
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| Veröffentlicht in: | Semiconductor Physics Quantum Electronics & Optoelectronics |
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| Datum: | 2016 |
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Інститут фізики напівпровідників імені В.Є. Лашкарьова НАН України
2016
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| Zitieren: | Influence of the presence of a fluxing agent and its composition on the spectral characteristics of ZnS(Cu) obtained by self-propagating high-temperature synthesis / Yu.Yu. Bacherikov, O.B. Okhrimenko, A.G. Zhuk, R.V. Kurichka, A.V. Gilchuk // Semiconductor Physics Quantum Electronics & Optoelectronics. — 2016. — Т. 19, № 3. — С. 303-306. — Бібліогр.: 20 назв. — англ. |
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Bacherikov, Yu.Yu. Okhrimenko, O.B. Zhuk, A.G. Kurichka, R.V. Gilchuk, A.V. 2017-06-14T18:37:17Z 2017-06-14T18:37:17Z 2016 Influence of the presence of a fluxing agent and its composition on the spectral characteristics of ZnS(Cu) obtained by self-propagating high-temperature synthesis / Yu.Yu. Bacherikov, O.B. Okhrimenko, A.G. Zhuk, R.V. Kurichka, A.V. Gilchuk // Semiconductor Physics Quantum Electronics & Optoelectronics. — 2016. — Т. 19, № 3. — С. 303-306. — Бібліогр.: 20 назв. — англ. 1560-8034 DOI: 10.15407/spqeo19.03.303 PACS 78.55.Et https://nasplib.isofts.kiev.ua/handle/123456789/121604 Investigated in this work were the photoluminescence spectra and luminescence excitation spectra of powered ZnS:Cu, obtained using the method of selfpropagating high-temperature synthesis (SHS) with addition of NaCl and MgCl₂ as a fluxing agent into the charge and without them. It was shown that increasing the amount of fraction with the particle sizes ≤5 nm in powdered ZnS:Cu-SHS, where fluxing agents are present in the charge, is caused by the decrease in temperature inside the reactor in the course of the synthesis reaction. Besides, related increasing the intensity of the PL blue band with λmax ~ 450…465 nm in powdered ZnS:Cu-SHS/MgCl₂, which is associated with redistribution of the copper impurity in the bulk of microcrystals, probably, occurring as a result of increasing the partial pressure of Cl during synthesis. en Інститут фізики напівпровідників імені В.Є. Лашкарьова НАН України Semiconductor Physics Quantum Electronics & Optoelectronics Influence of the presence of a fluxing agent and its composition on the spectral characteristics of ZnS(Cu) obtained by self-propagating high-temperature synthesis Article published earlier |
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Digital Library of Periodicals of National Academy of Sciences of Ukraine |
| collection |
DSpace DC |
| title |
Influence of the presence of a fluxing agent and its composition on the spectral characteristics of ZnS(Cu) obtained by self-propagating high-temperature synthesis |
| spellingShingle |
Influence of the presence of a fluxing agent and its composition on the spectral characteristics of ZnS(Cu) obtained by self-propagating high-temperature synthesis Bacherikov, Yu.Yu. Okhrimenko, O.B. Zhuk, A.G. Kurichka, R.V. Gilchuk, A.V. |
| title_short |
Influence of the presence of a fluxing agent and its composition on the spectral characteristics of ZnS(Cu) obtained by self-propagating high-temperature synthesis |
| title_full |
Influence of the presence of a fluxing agent and its composition on the spectral characteristics of ZnS(Cu) obtained by self-propagating high-temperature synthesis |
| title_fullStr |
Influence of the presence of a fluxing agent and its composition on the spectral characteristics of ZnS(Cu) obtained by self-propagating high-temperature synthesis |
| title_full_unstemmed |
Influence of the presence of a fluxing agent and its composition on the spectral characteristics of ZnS(Cu) obtained by self-propagating high-temperature synthesis |
| title_sort |
influence of the presence of a fluxing agent and its composition on the spectral characteristics of zns(cu) obtained by self-propagating high-temperature synthesis |
| author |
Bacherikov, Yu.Yu. Okhrimenko, O.B. Zhuk, A.G. Kurichka, R.V. Gilchuk, A.V. |
| author_facet |
Bacherikov, Yu.Yu. Okhrimenko, O.B. Zhuk, A.G. Kurichka, R.V. Gilchuk, A.V. |
| publishDate |
2016 |
| language |
English |
| container_title |
Semiconductor Physics Quantum Electronics & Optoelectronics |
| publisher |
Інститут фізики напівпровідників імені В.Є. Лашкарьова НАН України |
| format |
Article |
| description |
Investigated in this work were the photoluminescence spectra and luminescence excitation spectra of powered ZnS:Cu, obtained using the method of selfpropagating high-temperature synthesis (SHS) with addition of NaCl and MgCl₂ as a fluxing agent into the charge and without them. It was shown that increasing the amount of fraction with the particle sizes ≤5 nm in powdered ZnS:Cu-SHS, where fluxing agents are present in the charge, is caused by the decrease in temperature inside the reactor in the course of the synthesis reaction. Besides, related increasing the intensity of the PL blue band with λmax ~ 450…465 nm in powdered ZnS:Cu-SHS/MgCl₂, which is associated with redistribution of the copper impurity in the bulk of microcrystals, probably, occurring as a result of increasing the partial pressure of Cl during synthesis.
|
| issn |
1560-8034 |
| url |
https://nasplib.isofts.kiev.ua/handle/123456789/121604 |
| citation_txt |
Influence of the presence of a fluxing agent and its composition on the spectral characteristics of ZnS(Cu) obtained by self-propagating high-temperature synthesis / Yu.Yu. Bacherikov, O.B. Okhrimenko, A.G. Zhuk, R.V. Kurichka, A.V. Gilchuk // Semiconductor Physics Quantum Electronics & Optoelectronics. — 2016. — Т. 19, № 3. — С. 303-306. — Бібліогр.: 20 назв. — англ. |
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2025-12-07T15:29:04Z |
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2025-12-07T15:29:04Z |
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