SrTiO₃:Eu³⁺ phosphors prepared by sol-gel synthesis: Structural characterization, magnetic properties and luminescence spectroscopy study
We report the results of the comprehensive study of the structural, magnetic and optical properties of SrTiO₃ perovskite doped with Eu³⁺ ions. Polycrystalline powders were obtained by sol-gel process including high-temperature annealing at 1300 °C. The structural analysis showed that material is com...
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| Published in: | Semiconductor Physics Quantum Electronics & Optoelectronics |
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| Date: | 2016 |
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| Format: | Article |
| Language: | English |
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Інститут фізики напівпровідників імені В.Є. Лашкарьова НАН України
2016
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| Online Access: | https://nasplib.isofts.kiev.ua/handle/123456789/121654 |
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| Journal Title: | Digital Library of Periodicals of National Academy of Sciences of Ukraine |
| Cite this: | SrTiO₃:Eu³⁺ phosphors prepared by sol-gel synthesis: Structural characterization, magnetic properties and luminescence spectroscopy study / A.S. Pusenkova, О.N. Marchylo, L.V. Zavyalova, I.S. Golovina, S.V. Svechnikov, B.А. Snopok // Semiconductor Physics Quantum Electronics & Optoelectronics. — 2016. — Т. 19, № 4. — С. 343-351. — Бібліогр.: 45 назв. — англ. |
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Digital Library of Periodicals of National Academy of Sciences of Ukraine| _version_ | 1862699299029123072 |
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| author | Pusenkova, A.S. Marchylo, О.N. Zavyalova, L.V. Golovina, I.S. Svechnikov, S.V. Snopok, B.А. |
| author_facet | Pusenkova, A.S. Marchylo, О.N. Zavyalova, L.V. Golovina, I.S. Svechnikov, S.V. Snopok, B.А. |
| citation_txt | SrTiO₃:Eu³⁺ phosphors prepared by sol-gel synthesis: Structural characterization, magnetic properties and luminescence spectroscopy study / A.S. Pusenkova, О.N. Marchylo, L.V. Zavyalova, I.S. Golovina, S.V. Svechnikov, B.А. Snopok // Semiconductor Physics Quantum Electronics & Optoelectronics. — 2016. — Т. 19, № 4. — С. 343-351. — Бібліогр.: 45 назв. — англ. |
| collection | DSpace DC |
| container_title | Semiconductor Physics Quantum Electronics & Optoelectronics |
| description | We report the results of the comprehensive study of the structural, magnetic and optical properties of SrTiO₃ perovskite doped with Eu³⁺ ions. Polycrystalline powders were obtained by sol-gel process including high-temperature annealing at 1300 °C. The structural analysis showed that material is composed of several phases with dominant SrТiO₃ and onsiderable quantity of titanium dioxide (rutile, 10…20%). Both the amount of Eu and ratio of Eu:Sr in the final product are considerably smaller as compared to the original solutions for synthesis. The elemental analysis reveals europium only in the phase of EuSrTi₂O₇ compound for equimolar ratio of Eu and Sr during the synthesis. The EPR analysis reports deficiency of Eu²⁺ in the samples under investigations. SrTiO₃:Eu³⁺ powders demonstrate weak photoluminescence, which intensity grows up with increasing the concentration of Eu and reaches its maximum at c.a. 8 mol.% of Eu in the original solutions. Addition of Al increases the intensity of photoluminescence (c.a. 2.2 for 10 mol.%). Emission spectra are typical for Eu³⁺ occupied sites with high symmetric environment (dominant ⁵D₀→⁷F₁ transition) with relatively low distortion (both ⁵D₀→⁷F₂ and ⁵D₀→⁷F₄ as well present, but with a lower intensity) of coordination polyhedron. Low solid-solubility limit of Eu³⁺ in perovskite matrix (less than 1 mol.%), peculiarities of optical spectra, effect of Al, production/annealing temperature dependence etc. have suggested that structural effects are dominating in functional, in particular, optical properties of SrTiO₃:Eu³⁺ phosphors.
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| first_indexed | 2025-12-07T16:36:03Z |
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| id | nasplib_isofts_kiev_ua-123456789-121654 |
| institution | Digital Library of Periodicals of National Academy of Sciences of Ukraine |
| issn | 1560-8034 |
| language | English |
| last_indexed | 2025-12-07T16:36:03Z |
| publishDate | 2016 |
| publisher | Інститут фізики напівпровідників імені В.Є. Лашкарьова НАН України |
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| spelling | Pusenkova, A.S. Marchylo, О.N. Zavyalova, L.V. Golovina, I.S. Svechnikov, S.V. Snopok, B.А. 2017-06-15T08:16:11Z 2017-06-15T08:16:11Z 2016 SrTiO₃:Eu³⁺ phosphors prepared by sol-gel synthesis: Structural characterization, magnetic properties and luminescence spectroscopy study / A.S. Pusenkova, О.N. Marchylo, L.V. Zavyalova, I.S. Golovina, S.V. Svechnikov, B.А. Snopok // Semiconductor Physics Quantum Electronics & Optoelectronics. — 2016. — Т. 19, № 4. — С. 343-351. — Бібліогр.: 45 назв. — англ. 1560-8034 DOI: 10.15407/spqeo19.04.343 PACS 61.05.cp, 61.72.Hh, 78.55.Hx https://nasplib.isofts.kiev.ua/handle/123456789/121654 We report the results of the comprehensive study of the structural, magnetic and optical properties of SrTiO₃ perovskite doped with Eu³⁺ ions. Polycrystalline powders were obtained by sol-gel process including high-temperature annealing at 1300 °C. The structural analysis showed that material is composed of several phases with dominant SrТiO₃ and onsiderable quantity of titanium dioxide (rutile, 10…20%). Both the amount of Eu and ratio of Eu:Sr in the final product are considerably smaller as compared to the original solutions for synthesis. The elemental analysis reveals europium only in the phase of EuSrTi₂O₇ compound for equimolar ratio of Eu and Sr during the synthesis. The EPR analysis reports deficiency of Eu²⁺ in the samples under investigations. SrTiO₃:Eu³⁺ powders demonstrate weak photoluminescence, which intensity grows up with increasing the concentration of Eu and reaches its maximum at c.a. 8 mol.% of Eu in the original solutions. Addition of Al increases the intensity of photoluminescence (c.a. 2.2 for 10 mol.%). Emission spectra are typical for Eu³⁺ occupied sites with high symmetric environment (dominant ⁵D₀→⁷F₁ transition) with relatively low distortion (both ⁵D₀→⁷F₂ and ⁵D₀→⁷F₄ as well present, but with a lower intensity) of coordination polyhedron. Low solid-solubility limit of Eu³⁺ in perovskite matrix (less than 1 mol.%), peculiarities of optical spectra, effect of Al, production/annealing temperature dependence etc. have suggested that structural effects are dominating in functional, in particular, optical properties of SrTiO₃:Eu³⁺ phosphors. Assistance of Dr. Sc. Miroslav V. Karpets with X-ray measurements is highly appreciated. Authors acknowledge multiple discussions with Dr. Anna N. Morozovska. en Інститут фізики напівпровідників імені В.Є. Лашкарьова НАН України Semiconductor Physics Quantum Electronics & Optoelectronics SrTiO₃:Eu³⁺ phosphors prepared by sol-gel synthesis: Structural characterization, magnetic properties and luminescence spectroscopy study Article published earlier |
| spellingShingle | SrTiO₃:Eu³⁺ phosphors prepared by sol-gel synthesis: Structural characterization, magnetic properties and luminescence spectroscopy study Pusenkova, A.S. Marchylo, О.N. Zavyalova, L.V. Golovina, I.S. Svechnikov, S.V. Snopok, B.А. |
| title | SrTiO₃:Eu³⁺ phosphors prepared by sol-gel synthesis: Structural characterization, magnetic properties and luminescence spectroscopy study |
| title_full | SrTiO₃:Eu³⁺ phosphors prepared by sol-gel synthesis: Structural characterization, magnetic properties and luminescence spectroscopy study |
| title_fullStr | SrTiO₃:Eu³⁺ phosphors prepared by sol-gel synthesis: Structural characterization, magnetic properties and luminescence spectroscopy study |
| title_full_unstemmed | SrTiO₃:Eu³⁺ phosphors prepared by sol-gel synthesis: Structural characterization, magnetic properties and luminescence spectroscopy study |
| title_short | SrTiO₃:Eu³⁺ phosphors prepared by sol-gel synthesis: Structural characterization, magnetic properties and luminescence spectroscopy study |
| title_sort | srtio₃:eu³⁺ phosphors prepared by sol-gel synthesis: structural characterization, magnetic properties and luminescence spectroscopy study |
| url | https://nasplib.isofts.kiev.ua/handle/123456789/121654 |
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