How the phosphorus chains impact on the vibrational properties of diphosphides ZnP₂ and CdP₂ at low temperatures

The temperature dependence of the vibrational modes in the diphosphides ZnP₂ and CdP₂ has been studied by employing IR reflectance spectroscopy within the 4…300 K temperature range in the polarized radiation. It has been demonstrated that decreasing the bond distance in the phosphorus chain at low t...

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Published in:Semiconductor Physics Quantum Electronics & Optoelectronics
Date:2016
Main Author: Shportko, K.V.
Format: Article
Language:English
Published: Інститут фізики напівпровідників імені В.Є. Лашкарьова НАН України 2016
Online Access:https://nasplib.isofts.kiev.ua/handle/123456789/121678
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Journal Title:Digital Library of Periodicals of National Academy of Sciences of Ukraine
Cite this:How the phosphorus chains impact on the vibrational properties of diphosphides ZnP₂ and CdP₂ at low temperatures / K.V. Shportko // Semiconductor Physics Quantum Electronics & Optoelectronics. — 2016. — Т. 19, № 4. — С. 377-383. — Бібліогр.: 16 назв. — англ.

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Digital Library of Periodicals of National Academy of Sciences of Ukraine
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Summary:The temperature dependence of the vibrational modes in the diphosphides ZnP₂ and CdP₂ has been studied by employing IR reflectance spectroscopy within the 4…300 K temperature range in the polarized radiation. It has been demonstrated that decreasing the bond distance in the phosphorus chain at low temperatures causes an additional amount of anharmonicity of the corresponding modes, which is manifested in more pronounced temperature dependences of their frequencies and damping coefficients.
ISSN:1560-8034