Photoinduced absorption and anomalous dichroism in NaCa₂Mn₂V₃O₁₂ garnet as an evidence for the formation of oxygen holes dynamics
It is shown that long-lived photoinduced dichroism in garnets is caused by photoproduced charges with anisotropic structure, keeping long memory of the pumping light polarization, while photoinduced absorption is due to all photoproduced charges irrespective of their intrinsic structure. The char...
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| Опубліковано в: : | Физика низких температур |
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| Дата: | 2005 |
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| Мова: | English |
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Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України
2005
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| Назва журналу: | Digital Library of Periodicals of National Academy of Sciences of Ukraine |
| Цитувати: | Photoinduced absorption and anomalous dichroism in NaCa₂Mn₂V₃O₁₂ garnet as an evidence for the formation of oxygen holes dynamics / V.V. Eremenko, S.L. Gnatchenko, I.S. Kachur, V.G. Piryatinskaya, A.M. Ratner, V.V. Shapiro, M.B. Kosmyna, B.P. Nazarenko, V.M. Puzikov // Физика низких температур. — 2005. — Т. 31, № 11. — С. 1293-1301. — Бібліогр.: 17 назв. — англ. |
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Digital Library of Periodicals of National Academy of Sciences of Ukraine| id |
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Eremenko, V.V. Gnatchenko, S.L. Kachur, I.S. Piryatinskaya, V.G. Ratner, A.M. Shapiro, V.V. Kosmyna, M.B. Nazarenko, B.P. Puzikov, V.M. 2017-06-15T15:40:33Z 2017-06-15T15:40:33Z 2005 Photoinduced absorption and anomalous dichroism in NaCa₂Mn₂V₃O₁₂ garnet as an evidence for the formation of oxygen holes dynamics / V.V. Eremenko, S.L. Gnatchenko, I.S. Kachur, V.G. Piryatinskaya, A.M. Ratner, V.V. Shapiro, M.B. Kosmyna, B.P. Nazarenko, V.M. Puzikov // Физика низких температур. — 2005. — Т. 31, № 11. — С. 1293-1301. — Бібліогр.: 17 назв. — англ. 0132-6414 PASC: 78.40.-q https://nasplib.isofts.kiev.ua/handle/123456789/121729 It is shown that long-lived photoinduced dichroism in garnets is caused by photoproduced charges with anisotropic structure, keeping long memory of the pumping light polarization, while photoinduced absorption is due to all photoproduced charges irrespective of their intrinsic structure. The charges with anisotropic structure are identified as two-center oxygen holes. The formation of an oxygen hole is preceded by the excitation of a charge-transfer state with electron partially transferred to a cation C (V⁵⁺ for NaCa₂Mn₂V₃O₁₂ garnet) from an adjacent oxygen anion. To turn this excited state into a free hole state requires some time τhole during which the hole axis can be reoriented resulting in a diminution of dichroism. The time τhole shortens with increasing ionization potential of the cation C (very high for V⁵⁺). Such a mechanism explains qualitatively a set of unusual experimental facts, in particular, a very strong dichroism observed just in the NaCa₂Mn₂V₃O₁₂ garnet, where photoinduced changes of all optical properties disappear after switching off of the irradiation significantly faster than those in other garnets examined. en Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України Физика низких температур Квантовые эффекты в полупpоводниках и диэлектриках Photoinduced absorption and anomalous dichroism in NaCa₂Mn₂V₃O₁₂ garnet as an evidence for the formation of oxygen holes dynamics Article published earlier |
| institution |
Digital Library of Periodicals of National Academy of Sciences of Ukraine |
| collection |
DSpace DC |
| title |
Photoinduced absorption and anomalous dichroism in NaCa₂Mn₂V₃O₁₂ garnet as an evidence for the formation of oxygen holes dynamics |
| spellingShingle |
Photoinduced absorption and anomalous dichroism in NaCa₂Mn₂V₃O₁₂ garnet as an evidence for the formation of oxygen holes dynamics Eremenko, V.V. Gnatchenko, S.L. Kachur, I.S. Piryatinskaya, V.G. Ratner, A.M. Shapiro, V.V. Kosmyna, M.B. Nazarenko, B.P. Puzikov, V.M. Квантовые эффекты в полупpоводниках и диэлектриках |
| title_short |
Photoinduced absorption and anomalous dichroism in NaCa₂Mn₂V₃O₁₂ garnet as an evidence for the formation of oxygen holes dynamics |
| title_full |
Photoinduced absorption and anomalous dichroism in NaCa₂Mn₂V₃O₁₂ garnet as an evidence for the formation of oxygen holes dynamics |
| title_fullStr |
Photoinduced absorption and anomalous dichroism in NaCa₂Mn₂V₃O₁₂ garnet as an evidence for the formation of oxygen holes dynamics |
| title_full_unstemmed |
Photoinduced absorption and anomalous dichroism in NaCa₂Mn₂V₃O₁₂ garnet as an evidence for the formation of oxygen holes dynamics |
| title_sort |
photoinduced absorption and anomalous dichroism in naca₂mn₂v₃o₁₂ garnet as an evidence for the formation of oxygen holes dynamics |
| author |
Eremenko, V.V. Gnatchenko, S.L. Kachur, I.S. Piryatinskaya, V.G. Ratner, A.M. Shapiro, V.V. Kosmyna, M.B. Nazarenko, B.P. Puzikov, V.M. |
| author_facet |
Eremenko, V.V. Gnatchenko, S.L. Kachur, I.S. Piryatinskaya, V.G. Ratner, A.M. Shapiro, V.V. Kosmyna, M.B. Nazarenko, B.P. Puzikov, V.M. |
| topic |
Квантовые эффекты в полупpоводниках и диэлектриках |
| topic_facet |
Квантовые эффекты в полупpоводниках и диэлектриках |
| publishDate |
2005 |
| language |
English |
| container_title |
Физика низких температур |
| publisher |
Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України |
| format |
Article |
| description |
It is shown that long-lived photoinduced dichroism in garnets is caused by photoproduced
charges with anisotropic structure, keeping long memory of the pumping light polarization, while
photoinduced absorption is due to all photoproduced charges irrespective of their intrinsic structure.
The charges with anisotropic structure are identified as two-center oxygen holes. The formation
of an oxygen hole is preceded by the excitation of a charge-transfer state with electron partially
transferred to a cation C (V⁵⁺ for NaCa₂Mn₂V₃O₁₂ garnet) from an adjacent oxygen anion.
To turn this excited state into a free hole state requires some time τhole during which the hole axis
can be reoriented resulting in a diminution of dichroism. The time τhole shortens with increasing
ionization potential of the cation C (very high for V⁵⁺). Such a mechanism explains qualitatively a
set of unusual experimental facts, in particular, a very strong dichroism observed just in the
NaCa₂Mn₂V₃O₁₂ garnet, where photoinduced changes of all optical properties disappear after
switching off of the irradiation significantly faster than those in other garnets examined.
|
| issn |
0132-6414 |
| url |
https://nasplib.isofts.kiev.ua/handle/123456789/121729 |
| citation_txt |
Photoinduced absorption and anomalous dichroism in NaCa₂Mn₂V₃O₁₂ garnet as an evidence for the formation of oxygen holes dynamics / V.V. Eremenko, S.L. Gnatchenko, I.S. Kachur, V.G. Piryatinskaya, A.M. Ratner, V.V. Shapiro, M.B. Kosmyna, B.P. Nazarenko, V.M. Puzikov // Физика низких температур. — 2005. — Т. 31, № 11. — С. 1293-1301. — Бібліогр.: 17 назв. — англ. |
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| first_indexed |
2025-11-27T16:51:40Z |
| last_indexed |
2025-11-27T16:51:40Z |
| _version_ |
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