Theory of rare gas alloys: heat capacity

Low-temperature heat capacity of cryocrystals, which contain impurity clusters has been investigated theoretically and experimentally. Such defects might essentially enrich low-frequency part of the phonon spectrum by introducing both localized and delocalized vibrations. The effect of both types...

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Published in:Физика низких температур
Date:2007
Main Authors: Bagatskii, M.I., Feodosyev, S.B., Gospodarev, I.A., Kotlyar, O.V., Manzhelii, E.V., Nedzvetskiy, A.V., Syrkin, E.S.
Format: Article
Language:English
Published: Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України 2007
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Online Access:https://nasplib.isofts.kiev.ua/handle/123456789/121776
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Journal Title:Digital Library of Periodicals of National Academy of Sciences of Ukraine
Cite this:Theory of rare gas alloys: heat capacity / M.I. Bagatskii, S.B. Feodosyev, I.A. Gospodarev, O.V. Kotlyar, E.V. Manzhelii, A.V. Nedzvetskiy, E.S. Syrkin // Физика низких температур. — 2007. — Т. 33, № 6-7. — С. 741-746. — Бібліогр.: 33 назв. — англ.

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Digital Library of Periodicals of National Academy of Sciences of Ukraine
id nasplib_isofts_kiev_ua-123456789-121776
record_format dspace
spelling Bagatskii, M.I.
Feodosyev, S.B.
Gospodarev, I.A.
Kotlyar, O.V.
Manzhelii, E.V.
Nedzvetskiy, A.V.
Syrkin, E.S.
2017-06-16T07:21:52Z
2017-06-16T07:21:52Z
2007
Theory of rare gas alloys: heat capacity / M.I. Bagatskii, S.B. Feodosyev, I.A. Gospodarev, O.V. Kotlyar, E.V. Manzhelii, A.V. Nedzvetskiy, E.S. Syrkin // Физика низких температур. — 2007. — Т. 33, № 6-7. — С. 741-746. — Бібліогр.: 33 назв. — англ.
0132-6414
PACS: 63.20.–e; 63.20.Mt; 63.50.+x; 63.70.+h
https://nasplib.isofts.kiev.ua/handle/123456789/121776
Low-temperature heat capacity of cryocrystals, which contain impurity clusters has been investigated theoretically and experimentally. Such defects might essentially enrich low-frequency part of the phonon spectrum by introducing both localized and delocalized vibrations. The effect of both types of the vibrations on the temperature dependence of the heat capacity is analyzed. Heat capacity of the disordered solid solution Kr–Ar (Ar concentration is ~25%) is studied as an example of the effect of the light weakly connected impurities on the low-temperature thermodynamic characteristics of the system. The mass defect of such an impurity induces «phonon pumping» from the low-frequency part of the spectrum into the high-frequency part and decreasing the low-temperature heat capacity, while the weakened interaction between the impurity and the host atoms combined with even weaker interaction between the impurities leads to the formation of the low-temperature maximum on the heat capacity temperature dependence. The analysis performed shows that at rather high Ar concentrations, the nonmonotonous temperature dependence of the relative change in the heat capacity of solid Kr₁₋pArp solutions is determined by excitation of delocalized high-dispersion low-frequency phonons.
en
Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України
Физика низких температур
Classical Cryocrystals
Theory of rare gas alloys: heat capacity
Article
published earlier
institution Digital Library of Periodicals of National Academy of Sciences of Ukraine
collection DSpace DC
title Theory of rare gas alloys: heat capacity
spellingShingle Theory of rare gas alloys: heat capacity
Bagatskii, M.I.
Feodosyev, S.B.
Gospodarev, I.A.
Kotlyar, O.V.
Manzhelii, E.V.
Nedzvetskiy, A.V.
Syrkin, E.S.
Classical Cryocrystals
title_short Theory of rare gas alloys: heat capacity
title_full Theory of rare gas alloys: heat capacity
title_fullStr Theory of rare gas alloys: heat capacity
title_full_unstemmed Theory of rare gas alloys: heat capacity
title_sort theory of rare gas alloys: heat capacity
author Bagatskii, M.I.
Feodosyev, S.B.
Gospodarev, I.A.
Kotlyar, O.V.
Manzhelii, E.V.
Nedzvetskiy, A.V.
Syrkin, E.S.
author_facet Bagatskii, M.I.
Feodosyev, S.B.
Gospodarev, I.A.
Kotlyar, O.V.
Manzhelii, E.V.
Nedzvetskiy, A.V.
Syrkin, E.S.
topic Classical Cryocrystals
topic_facet Classical Cryocrystals
publishDate 2007
language English
container_title Физика низких температур
publisher Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України
format Article
description Low-temperature heat capacity of cryocrystals, which contain impurity clusters has been investigated theoretically and experimentally. Such defects might essentially enrich low-frequency part of the phonon spectrum by introducing both localized and delocalized vibrations. The effect of both types of the vibrations on the temperature dependence of the heat capacity is analyzed. Heat capacity of the disordered solid solution Kr–Ar (Ar concentration is ~25%) is studied as an example of the effect of the light weakly connected impurities on the low-temperature thermodynamic characteristics of the system. The mass defect of such an impurity induces «phonon pumping» from the low-frequency part of the spectrum into the high-frequency part and decreasing the low-temperature heat capacity, while the weakened interaction between the impurity and the host atoms combined with even weaker interaction between the impurities leads to the formation of the low-temperature maximum on the heat capacity temperature dependence. The analysis performed shows that at rather high Ar concentrations, the nonmonotonous temperature dependence of the relative change in the heat capacity of solid Kr₁₋pArp solutions is determined by excitation of delocalized high-dispersion low-frequency phonons.
issn 0132-6414
url https://nasplib.isofts.kiev.ua/handle/123456789/121776
citation_txt Theory of rare gas alloys: heat capacity / M.I. Bagatskii, S.B. Feodosyev, I.A. Gospodarev, O.V. Kotlyar, E.V. Manzhelii, A.V. Nedzvetskiy, E.S. Syrkin // Физика низких температур. — 2007. — Т. 33, № 6-7. — С. 741-746. — Бібліогр.: 33 назв. — англ.
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