Neon in carbon nanopores: wetting, growth mechanisms and cluster structures

Low-temperature high-energy (50 keV) electron diffraction study of size-dependent structures and
 growth mechanisms of neon samples in multiporous «amorphous» carbon films is presented. Electron
 diffractograms were analyzed on the basis of the assumption that there exists the cluste...

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Published in:Физика низких температур
Date:2007
Main Author: Krainyukova, N.V.
Format: Article
Language:English
Published: Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України 2007
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Online Access:https://nasplib.isofts.kiev.ua/handle/123456789/121777
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Journal Title:Digital Library of Periodicals of National Academy of Sciences of Ukraine
Cite this:Neon in carbon nanopores: wetting, growth mechanisms
 and cluster structures / N.V. Krainyukova // Физика низких температур. — 2007. — Т. 33, № 6-7. — С. 747-751. — Бібліогр.: 25 назв. — англ.

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Digital Library of Periodicals of National Academy of Sciences of Ukraine
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author Krainyukova, N.V.
author_facet Krainyukova, N.V.
citation_txt Neon in carbon nanopores: wetting, growth mechanisms
 and cluster structures / N.V. Krainyukova // Физика низких температур. — 2007. — Т. 33, № 6-7. — С. 747-751. — Бібліогр.: 25 назв. — англ.
collection DSpace DC
container_title Физика низких температур
description Low-temperature high-energy (50 keV) electron diffraction study of size-dependent structures and
 growth mechanisms of neon samples in multiporous «amorphous» carbon films is presented. Electron
 diffractograms were analyzed on the basis of the assumption that there exists the cluster size distribution in
 deposits formed in substrate and multi-shell structures such as icosahedra, decahedra, fcc and hcp were
 probed for different sizes up to approximately 3·10⁴ atoms. The analysis was based on the comparison of
 precise experimental and calculated diffracted intensities with the help of the R (reliability) — factor
 minimization procedure. Highly reproducible discrete distribution functions of sizes and structures were
 found. The time-dependent evolution of diffractograms at earlier stages of growth was revealed. Initially
 distinct diffraction peaks gradually «disappeared» although the total electron beam absorption evidenced
 that deposited neon was preserved in the porous substrate. We ascribed this effect to diffusion-like gas penetration
 from larger to smaller pores which resulted in a highly dispersed or even disordered substance. Evidently,
 clusters initially grown during deposition were later soaked by a sponge-like substrate due to capillary
 forces.
first_indexed 2025-12-02T04:17:28Z
format Article
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id nasplib_isofts_kiev_ua-123456789-121777
institution Digital Library of Periodicals of National Academy of Sciences of Ukraine
issn 0132-6414
language English
last_indexed 2025-12-02T04:17:28Z
publishDate 2007
publisher Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України
record_format dspace
spelling Krainyukova, N.V.
2017-06-16T07:23:51Z
2017-06-16T07:23:51Z
2007
Neon in carbon nanopores: wetting, growth mechanisms
 and cluster structures / N.V. Krainyukova // Физика низких температур. — 2007. — Т. 33, № 6-7. — С. 747-751. — Бібліогр.: 25 назв. — англ.
0132-6414
PACS: 61.14.–x; 61.46.–w; 67.70.+n; 81.05.Rm; 81.05.Uw
https://nasplib.isofts.kiev.ua/handle/123456789/121777
Low-temperature high-energy (50 keV) electron diffraction study of size-dependent structures and
 growth mechanisms of neon samples in multiporous «amorphous» carbon films is presented. Electron
 diffractograms were analyzed on the basis of the assumption that there exists the cluster size distribution in
 deposits formed in substrate and multi-shell structures such as icosahedra, decahedra, fcc and hcp were
 probed for different sizes up to approximately 3·10⁴ atoms. The analysis was based on the comparison of
 precise experimental and calculated diffracted intensities with the help of the R (reliability) — factor
 minimization procedure. Highly reproducible discrete distribution functions of sizes and structures were
 found. The time-dependent evolution of diffractograms at earlier stages of growth was revealed. Initially
 distinct diffraction peaks gradually «disappeared» although the total electron beam absorption evidenced
 that deposited neon was preserved in the porous substrate. We ascribed this effect to diffusion-like gas penetration
 from larger to smaller pores which resulted in a highly dispersed or even disordered substance. Evidently,
 clusters initially grown during deposition were later soaked by a sponge-like substrate due to capillary
 forces.
The author is grateful to V.G. Manzhelii, M.A. Strzhemechny,
 V.V. Khmelenko, V.A. Apkarian, J.-P. Galaup,
 and V. Kiryukhin for fruitful discussion of the problem,
 she is also greatly indebted to B.W. van de Waal for numerous
 valuable comments and also for the software provided
 for cluster modelling.
en
Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України
Физика низких температур
Classical Cryocrystals
Neon in carbon nanopores: wetting, growth mechanisms and cluster structures
Article
published earlier
spellingShingle Neon in carbon nanopores: wetting, growth mechanisms and cluster structures
Krainyukova, N.V.
Classical Cryocrystals
title Neon in carbon nanopores: wetting, growth mechanisms and cluster structures
title_full Neon in carbon nanopores: wetting, growth mechanisms and cluster structures
title_fullStr Neon in carbon nanopores: wetting, growth mechanisms and cluster structures
title_full_unstemmed Neon in carbon nanopores: wetting, growth mechanisms and cluster structures
title_short Neon in carbon nanopores: wetting, growth mechanisms and cluster structures
title_sort neon in carbon nanopores: wetting, growth mechanisms and cluster structures
topic Classical Cryocrystals
topic_facet Classical Cryocrystals
url https://nasplib.isofts.kiev.ua/handle/123456789/121777
work_keys_str_mv AT krainyukovanv neonincarbonnanoporeswettinggrowthmechanismsandclusterstructures