Structure of quench condensed nH₂–N₂ binary alloys: isotope effect

Structure of quench condensed nH₂–N₂ alloys was investigated by powder x-ray diffraction over a wide range of temperatures, compositions, and rates of deposition. The structure of the deposits is shown to depend on the condensation regime. Under mild regime, no solid nitrogen reflections from hydr...

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Published in:Физика низких температур
Date:2007
Main Authors: Galtsov, N.N., Prokhvatilov, A.I., Strzhemechny, M.A.
Format: Article
Language:English
Published: Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України 2007
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Online Access:https://nasplib.isofts.kiev.ua/handle/123456789/121784
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Journal Title:Digital Library of Periodicals of National Academy of Sciences of Ukraine
Cite this:Structure of quench condensed nH₂–N₂ binary alloys: isotope effect / N.N. Galtsov, A.I. Prokhvatilov, M.A. Strzhemechny // Физика низких температур. — 2007. — Т. 33, № 6-7. — С. 668-672. — Бібліогр.: 19 назв. — англ.

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Digital Library of Periodicals of National Academy of Sciences of Ukraine
id nasplib_isofts_kiev_ua-123456789-121784
record_format dspace
spelling Galtsov, N.N.
Prokhvatilov, A.I.
Strzhemechny, M.A.
2017-06-16T07:48:55Z
2017-06-16T07:48:55Z
2007
Structure of quench condensed nH₂–N₂ binary alloys: isotope effect / N.N. Galtsov, A.I. Prokhvatilov, M.A. Strzhemechny // Физика низких температур. — 2007. — Т. 33, № 6-7. — С. 668-672. — Бібліогр.: 19 назв. — англ.
0132-6414
PACS: 78.55.Kz; 31.50.+w
https://nasplib.isofts.kiev.ua/handle/123456789/121784
Structure of quench condensed nH₂–N₂ alloys was investigated by powder x-ray diffraction over a wide range of temperatures, compositions, and rates of deposition. The structure of the deposits is shown to depend on the condensation regime. Under mild regime, no solid nitrogen reflections from hydrogen-rich deposits were observed. When the temperature is increased to the hydrogen triple point, nitrogen lines appear at substantially larger angles compared to pure N₂, which suggests presence of dissolved hydrogen. The quantum nature of this hydrogen is suppressed in the nitrogen matrix. The samples grown in mild regime exhibit the highest apparent solubility (up to 25%) of hydrogen in solid N₂. When H₂ is substituted by D₂, the isotope effect consists in a wider range of mono-phase states based on the nitrogen cubic lattice, which can accommodate up to 70% of deuterium, if grown under mild regime.
en
Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України
Физика низких температур
Quantum Crystals
Structure of quench condensed nH₂–N₂ binary alloys: isotope effect
Article
published earlier
institution Digital Library of Periodicals of National Academy of Sciences of Ukraine
collection DSpace DC
title Structure of quench condensed nH₂–N₂ binary alloys: isotope effect
spellingShingle Structure of quench condensed nH₂–N₂ binary alloys: isotope effect
Galtsov, N.N.
Prokhvatilov, A.I.
Strzhemechny, M.A.
Quantum Crystals
title_short Structure of quench condensed nH₂–N₂ binary alloys: isotope effect
title_full Structure of quench condensed nH₂–N₂ binary alloys: isotope effect
title_fullStr Structure of quench condensed nH₂–N₂ binary alloys: isotope effect
title_full_unstemmed Structure of quench condensed nH₂–N₂ binary alloys: isotope effect
title_sort structure of quench condensed nh₂–n₂ binary alloys: isotope effect
author Galtsov, N.N.
Prokhvatilov, A.I.
Strzhemechny, M.A.
author_facet Galtsov, N.N.
Prokhvatilov, A.I.
Strzhemechny, M.A.
topic Quantum Crystals
topic_facet Quantum Crystals
publishDate 2007
language English
container_title Физика низких температур
publisher Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України
format Article
description Structure of quench condensed nH₂–N₂ alloys was investigated by powder x-ray diffraction over a wide range of temperatures, compositions, and rates of deposition. The structure of the deposits is shown to depend on the condensation regime. Under mild regime, no solid nitrogen reflections from hydrogen-rich deposits were observed. When the temperature is increased to the hydrogen triple point, nitrogen lines appear at substantially larger angles compared to pure N₂, which suggests presence of dissolved hydrogen. The quantum nature of this hydrogen is suppressed in the nitrogen matrix. The samples grown in mild regime exhibit the highest apparent solubility (up to 25%) of hydrogen in solid N₂. When H₂ is substituted by D₂, the isotope effect consists in a wider range of mono-phase states based on the nitrogen cubic lattice, which can accommodate up to 70% of deuterium, if grown under mild regime.
issn 0132-6414
url https://nasplib.isofts.kiev.ua/handle/123456789/121784
citation_txt Structure of quench condensed nH₂–N₂ binary alloys: isotope effect / N.N. Galtsov, A.I. Prokhvatilov, M.A. Strzhemechny // Физика низких температур. — 2007. — Т. 33, № 6-7. — С. 668-672. — Бібліогр.: 19 назв. — англ.
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first_indexed 2025-11-27T16:51:44Z
last_indexed 2025-11-27T16:51:44Z
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