Electron spin resonance study on Mo-SiO₂ and Mo-TiO₂ with adsorbed benzene
The study is devoted to ESR-investigation of the primary processes upon chemisorption of benzene molecules onto the molybdenum supported on dispersed SiO₂ and TiO₂ samples. It has been confirmed that benzene chemisorption onto the Mo⁶⁺ species results in one-electron transfer in the ground state and...
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| Published in: | Поверхность |
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| Date: | 2002 |
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| Format: | Article |
| Language: | English |
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Інститут хімії поверхні ім. О.О. Чуйка НАН України
2002
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| Online Access: | https://nasplib.isofts.kiev.ua/handle/123456789/126358 |
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| Journal Title: | Digital Library of Periodicals of National Academy of Sciences of Ukraine |
| Cite this: | Electron spin resonance study on Mo-SiO₂ and Mo-TiO₂ with adsorbed benzene / M. Ignatovych, V. Teslenko, A. Eremenko, V. Ogenko, A. Chuiko // Поверхность. — 2002. — Вип. 7-8. — С. 115-124. — Бібліогр.: 20 назв. — англ. |
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Ignatovych, M. Teslenko, V. Eremenko, A. Ogenko, V. Chuiko, A. 2017-11-20T18:40:40Z 2017-11-20T18:40:40Z 2002 Electron spin resonance study on Mo-SiO₂ and Mo-TiO₂ with adsorbed benzene / M. Ignatovych, V. Teslenko, A. Eremenko, V. Ogenko, A. Chuiko // Поверхность. — 2002. — Вип. 7-8. — С. 115-124. — Бібліогр.: 20 назв. — англ. XXXX-0106 https://nasplib.isofts.kiev.ua/handle/123456789/126358 The study is devoted to ESR-investigation of the primary processes upon chemisorption of benzene molecules onto the molybdenum supported on dispersed SiO₂ and TiO₂ samples. It has been confirmed that benzene chemisorption onto the Mo⁶⁺ species results in one-electron transfer in the ground state and paramagnetic species formation, namely reduced molybdenum species (Mo⁵⁺ species) and radicals of benzene. Computer treatment of ESR experimental data revealed that there are several types of Mo⁵⁺ species and benzene radicals, the assignment of which is proposed. en Інститут хімії поверхні ім. О.О. Чуйка НАН України Поверхность Surface chemistry of silica and related sorbents Electron spin resonance study on Mo-SiO₂ and Mo-TiO₂ with adsorbed benzene Article published earlier |
| institution |
Digital Library of Periodicals of National Academy of Sciences of Ukraine |
| collection |
DSpace DC |
| title |
Electron spin resonance study on Mo-SiO₂ and Mo-TiO₂ with adsorbed benzene |
| spellingShingle |
Electron spin resonance study on Mo-SiO₂ and Mo-TiO₂ with adsorbed benzene Ignatovych, M. Teslenko, V. Eremenko, A. Ogenko, V. Chuiko, A. Surface chemistry of silica and related sorbents |
| title_short |
Electron spin resonance study on Mo-SiO₂ and Mo-TiO₂ with adsorbed benzene |
| title_full |
Electron spin resonance study on Mo-SiO₂ and Mo-TiO₂ with adsorbed benzene |
| title_fullStr |
Electron spin resonance study on Mo-SiO₂ and Mo-TiO₂ with adsorbed benzene |
| title_full_unstemmed |
Electron spin resonance study on Mo-SiO₂ and Mo-TiO₂ with adsorbed benzene |
| title_sort |
electron spin resonance study on mo-sio₂ and mo-tio₂ with adsorbed benzene |
| author |
Ignatovych, M. Teslenko, V. Eremenko, A. Ogenko, V. Chuiko, A. |
| author_facet |
Ignatovych, M. Teslenko, V. Eremenko, A. Ogenko, V. Chuiko, A. |
| topic |
Surface chemistry of silica and related sorbents |
| topic_facet |
Surface chemistry of silica and related sorbents |
| publishDate |
2002 |
| language |
English |
| container_title |
Поверхность |
| publisher |
Інститут хімії поверхні ім. О.О. Чуйка НАН України |
| format |
Article |
| description |
The study is devoted to ESR-investigation of the primary processes upon chemisorption of benzene molecules onto the molybdenum supported on dispersed SiO₂ and TiO₂ samples. It has been confirmed that benzene chemisorption onto the Mo⁶⁺ species results in one-electron transfer in the ground state and paramagnetic species formation, namely reduced molybdenum species (Mo⁵⁺ species) and radicals of benzene. Computer treatment of ESR experimental data revealed that there are several types of Mo⁵⁺ species and benzene radicals, the assignment of which is proposed.
|
| issn |
XXXX-0106 |
| url |
https://nasplib.isofts.kiev.ua/handle/123456789/126358 |
| citation_txt |
Electron spin resonance study on Mo-SiO₂ and Mo-TiO₂ with adsorbed benzene / M. Ignatovych, V. Teslenko, A. Eremenko, V. Ogenko, A. Chuiko // Поверхность. — 2002. — Вип. 7-8. — С. 115-124. — Бібліогр.: 20 назв. — англ. |
| work_keys_str_mv |
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| first_indexed |
2025-12-07T20:23:01Z |
| last_indexed |
2025-12-07T20:23:01Z |
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