Electron spin resonance study on Mo-SiO₂ and Mo-TiO₂ with adsorbed benzene

The study is devoted to ESR-investigation of the primary processes upon chemisorption of benzene molecules onto the molybdenum supported on dispersed SiO₂ and TiO₂ samples. It has been confirmed that benzene chemisorption onto the Mo⁶⁺ species results in one-electron transfer in the ground state and...

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Veröffentlicht in:Поверхность
Datum:2002
Hauptverfasser: Ignatovych, M., Teslenko, V., Eremenko, A., Ogenko, V., Chuiko, A.
Format: Artikel
Sprache:Englisch
Veröffentlicht: Інститут хімії поверхні ім. О.О. Чуйка НАН України 2002
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Online Zugang:https://nasplib.isofts.kiev.ua/handle/123456789/126358
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Zitieren:Electron spin resonance study on Mo-SiO₂ and Mo-TiO₂ with adsorbed benzene / M. Ignatovych, V. Teslenko, A. Eremenko, V. Ogenko, A. Chuiko // Поверхность. — 2002. — Вип. 7-8. — С. 115-124. — Бібліогр.: 20 назв. — англ.

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Digital Library of Periodicals of National Academy of Sciences of Ukraine
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author Ignatovych, M.
Teslenko, V.
Eremenko, A.
Ogenko, V.
Chuiko, A.
author_facet Ignatovych, M.
Teslenko, V.
Eremenko, A.
Ogenko, V.
Chuiko, A.
citation_txt Electron spin resonance study on Mo-SiO₂ and Mo-TiO₂ with adsorbed benzene / M. Ignatovych, V. Teslenko, A. Eremenko, V. Ogenko, A. Chuiko // Поверхность. — 2002. — Вип. 7-8. — С. 115-124. — Бібліогр.: 20 назв. — англ.
collection DSpace DC
container_title Поверхность
description The study is devoted to ESR-investigation of the primary processes upon chemisorption of benzene molecules onto the molybdenum supported on dispersed SiO₂ and TiO₂ samples. It has been confirmed that benzene chemisorption onto the Mo⁶⁺ species results in one-electron transfer in the ground state and paramagnetic species formation, namely reduced molybdenum species (Mo⁵⁺ species) and radicals of benzene. Computer treatment of ESR experimental data revealed that there are several types of Mo⁵⁺ species and benzene radicals, the assignment of which is proposed.
first_indexed 2025-12-07T20:23:01Z
format Article
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institution Digital Library of Periodicals of National Academy of Sciences of Ukraine
issn XXXX-0106
language English
last_indexed 2025-12-07T20:23:01Z
publishDate 2002
publisher Інститут хімії поверхні ім. О.О. Чуйка НАН України
record_format dspace
spelling Ignatovych, M.
Teslenko, V.
Eremenko, A.
Ogenko, V.
Chuiko, A.
2017-11-20T18:40:40Z
2017-11-20T18:40:40Z
2002
Electron spin resonance study on Mo-SiO₂ and Mo-TiO₂ with adsorbed benzene / M. Ignatovych, V. Teslenko, A. Eremenko, V. Ogenko, A. Chuiko // Поверхность. — 2002. — Вип. 7-8. — С. 115-124. — Бібліогр.: 20 назв. — англ.
XXXX-0106
https://nasplib.isofts.kiev.ua/handle/123456789/126358
The study is devoted to ESR-investigation of the primary processes upon chemisorption of benzene molecules onto the molybdenum supported on dispersed SiO₂ and TiO₂ samples. It has been confirmed that benzene chemisorption onto the Mo⁶⁺ species results in one-electron transfer in the ground state and paramagnetic species formation, namely reduced molybdenum species (Mo⁵⁺ species) and radicals of benzene. Computer treatment of ESR experimental data revealed that there are several types of Mo⁵⁺ species and benzene radicals, the assignment of which is proposed.
en
Інститут хімії поверхні ім. О.О. Чуйка НАН України
Поверхность
Surface chemistry of silica and related sorbents
Electron spin resonance study on Mo-SiO₂ and Mo-TiO₂ with adsorbed benzene
Article
published earlier
spellingShingle Electron spin resonance study on Mo-SiO₂ and Mo-TiO₂ with adsorbed benzene
Ignatovych, M.
Teslenko, V.
Eremenko, A.
Ogenko, V.
Chuiko, A.
Surface chemistry of silica and related sorbents
title Electron spin resonance study on Mo-SiO₂ and Mo-TiO₂ with adsorbed benzene
title_full Electron spin resonance study on Mo-SiO₂ and Mo-TiO₂ with adsorbed benzene
title_fullStr Electron spin resonance study on Mo-SiO₂ and Mo-TiO₂ with adsorbed benzene
title_full_unstemmed Electron spin resonance study on Mo-SiO₂ and Mo-TiO₂ with adsorbed benzene
title_short Electron spin resonance study on Mo-SiO₂ and Mo-TiO₂ with adsorbed benzene
title_sort electron spin resonance study on mo-sio₂ and mo-tio₂ with adsorbed benzene
topic Surface chemistry of silica and related sorbents
topic_facet Surface chemistry of silica and related sorbents
url https://nasplib.isofts.kiev.ua/handle/123456789/126358
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AT teslenkov electronspinresonancestudyonmosio2andmotio2withadsorbedbenzene
AT eremenkoa electronspinresonancestudyonmosio2andmotio2withadsorbedbenzene
AT ogenkov electronspinresonancestudyonmosio2andmotio2withadsorbedbenzene
AT chuikoa electronspinresonancestudyonmosio2andmotio2withadsorbedbenzene