Vertical spin transport in semiconductor heterostructures

The Landauer—B ttiker formalism combined with the tight-binding transfer matrix method is employed to model vertical coherent spin transport within magnetization modulated semiconductor heterostructures based on GaAs. This formalism provides excellent physical description of recent experiments co...

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Автори: Sankowski, P., Kacman, P., Majewski, J.A., Dietl, T.
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Опубліковано: Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України 2007
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Цитувати:Vertical spin transport in semiconductor heterostructures / P. Sankowski, P. Kacman, J.A. Majewski, T. Dietl // Физика низких температур. — 2007. — Т. 33, № 2-3. — С. 256-262. — Бібліогр.: 34 назв. — англ.

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Digital Library of Periodicals of National Academy of Sciences of Ukraine
id nasplib_isofts_kiev_ua-123456789-127727
record_format dspace
spelling Sankowski, P.
Kacman, P.
Majewski, J.A.
Dietl, T.
2017-12-27T10:47:28Z
2017-12-27T10:47:28Z
2007
Vertical spin transport in semiconductor heterostructures / P. Sankowski, P. Kacman, J.A. Majewski, T. Dietl // Физика низких температур. — 2007. — Т. 33, № 2-3. — С. 256-262. — Бібліогр.: 34 назв. — англ.
0132-6414
PACS: 75.50.Pp, 72.25.Hg, 73.40.Gk
https://nasplib.isofts.kiev.ua/handle/123456789/127727
The Landauer—B ttiker formalism combined with the tight-binding transfer matrix method is employed to model vertical coherent spin transport within magnetization modulated semiconductor heterostructures based on GaAs. This formalism provides excellent physical description of recent experiments concerning the high tunneling magnetoresistance (TMR) in (Ga,Mn)As-based trilayers and highly polarized spin injection in p-(Ga,Mn)As/n-GaAs Zener diode. For both the TMR and the Zener spin current polarization, the calculated values compare well with those observed in the experiments and the formalism reproduces the strong decrease of the observed effects with external bias. We ascribe this decrease to the band structure effects. The role played in the spin dependent tunneling by carrier concentration and magnetic ion content is also studied.
This work was partly supported by the EC project NANOSPIN (FP6-2002-IST-015728). Calculations were carried out using the resources and software at Interdisciplinary Center of Mathematical and Computer Modelling (ICM) in Warsaw.
en
Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України
Физика низких температур
Структура и свойства полупроводников с переходными элементами
Vertical spin transport in semiconductor heterostructures
Article
published earlier
institution Digital Library of Periodicals of National Academy of Sciences of Ukraine
collection DSpace DC
title Vertical spin transport in semiconductor heterostructures
spellingShingle Vertical spin transport in semiconductor heterostructures
Sankowski, P.
Kacman, P.
Majewski, J.A.
Dietl, T.
Структура и свойства полупроводников с переходными элементами
title_short Vertical spin transport in semiconductor heterostructures
title_full Vertical spin transport in semiconductor heterostructures
title_fullStr Vertical spin transport in semiconductor heterostructures
title_full_unstemmed Vertical spin transport in semiconductor heterostructures
title_sort vertical spin transport in semiconductor heterostructures
author Sankowski, P.
Kacman, P.
Majewski, J.A.
Dietl, T.
author_facet Sankowski, P.
Kacman, P.
Majewski, J.A.
Dietl, T.
topic Структура и свойства полупроводников с переходными элементами
topic_facet Структура и свойства полупроводников с переходными элементами
publishDate 2007
language English
container_title Физика низких температур
publisher Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України
format Article
description The Landauer—B ttiker formalism combined with the tight-binding transfer matrix method is employed to model vertical coherent spin transport within magnetization modulated semiconductor heterostructures based on GaAs. This formalism provides excellent physical description of recent experiments concerning the high tunneling magnetoresistance (TMR) in (Ga,Mn)As-based trilayers and highly polarized spin injection in p-(Ga,Mn)As/n-GaAs Zener diode. For both the TMR and the Zener spin current polarization, the calculated values compare well with those observed in the experiments and the formalism reproduces the strong decrease of the observed effects with external bias. We ascribe this decrease to the band structure effects. The role played in the spin dependent tunneling by carrier concentration and magnetic ion content is also studied.
issn 0132-6414
url https://nasplib.isofts.kiev.ua/handle/123456789/127727
citation_txt Vertical spin transport in semiconductor heterostructures / P. Sankowski, P. Kacman, J.A. Majewski, T. Dietl // Физика низких температур. — 2007. — Т. 33, № 2-3. — С. 256-262. — Бібліогр.: 34 назв. — англ.
work_keys_str_mv AT sankowskip verticalspintransportinsemiconductorheterostructures
AT kacmanp verticalspintransportinsemiconductorheterostructures
AT majewskija verticalspintransportinsemiconductorheterostructures
AT dietlt verticalspintransportinsemiconductorheterostructures
first_indexed 2025-11-27T07:12:25Z
last_indexed 2025-11-27T07:12:25Z
_version_ 1850803074290941952
fulltext Fizika Nizkikh Temperatur, 2007, v. 33, Nos. 2/3, p. 256–262 Vertical spin transport in semiconductor heterostructures P. Sankowski1, P. Kacman1, J.A. Majewski2, and T. Dietl1,2,3 1 Institute of Physics, Polish Academy of Sciences, 32/46 al. Lotnikow, Warszawa 02668, Poland 2 Institute of Theoretical Physics, Warsaw University, 69 ul. Hoza, Warszawa 00681, Poland E-mail: jacek.majewski@fuw.edu.pl 3 ERATO Semiconductor Spintronics Project Received September 22, 2006 The Landauer—B�ttiker formalism combined with the tight-binding transfer matrix method is employed to model vertical coherent spin transport within magnetization modulated semiconduc- tor heterostructures based on GaAs. This formalism provides excellent physical description of re- cent experiments concerning the high tunneling magnetoresistance (TMR) in (Ga,Mn)As-based trilayers and highly polarized spin injection in p-(Ga,Mn)As/n-GaAs Zener diode. For both the TMR and the Zener spin current polarization, the calculated values compare well with those ob- served in the experiments and the formalism reproduces the strong decrease of the observed effects with external bias. We ascribe this decrease to the band structure effects. The role played in the spin dependent tunneling by carrier concentration and magnetic ion content is also studied. PACS: 75.50.Pp Magnetic semiconductors; 72.25.Hg Electrical injection of spin polarized carriers; 73.40.Gk Tunneling. Keywords: ferromagnetic semiconductors, spin transport, tunneling magnetoresistance. 1. Introduction With the recent discovery of ferromagnetic semi- conductors [1] compatible with III–V epitaxy [2] the field of spintronics has expanded from all-metal [3,4] and hybrid metal—semiconductor [5] structures to in- clude all-semiconductor ferromagnetic devices [6]. Such devices have revealed intriguing properties, such as control of their Curie temperature with an applied voltage [7]. This is a consequence of the carrier- mediated nature of the ferromagnetism in these mate- rials, which allows manipulation of the magnetic properties through control of the electronic subsystem (i.e., through doping, gating, etc.) [8]. (Ga,Mn)As is believed to be one of the most promi- sing materials for semiconductor spintronics. First of all, it has almost the same lattice constant as GaAs and AlAs, and with the (Ga,Mn)As/III–V hetero- structures one can form high-quality all-semiconduc- tor spintronic devices, such as magnetic tunnel junc- tions. In addition, (Ga,Mn)As, based devices might be easily integrated within other III–V-based devices. Moreover, in recent years the optimization of the con- ditions of MBE growth and post-growth annealing of (Ga,Mn)As has resulted in a still rapid increase of the Curie temperature in this compound, which now reaches 173 K [9]. Spin-dependent phenomena in modulated magnetic semiconductors attract a lot of interest due to the pos- sible applications in spintronic devices. One of the fundamental prerequisites for construction of func- tional spintronic devices, such as spin transistors [10], is efficient spin injection from ferromagnetic regions into the paramagnetic ones. On the other hand, the tunneling magnetoresistance (TMR) effect, discov- ered by J�lliere in a Co/Ge/Fe structure [11], has al- ready found many applications in magnetic field sensors and magnetic random access memories, for example. Both these phenomena have been also recently observed in (Ga,Mn)As-based structures. It has been demonstrated that highly spin-polarized electron current (about 80%) can indeed be obtained from p-(Ga,Mn)As/n-GaAs Zener diode [12]. Also a high (of about 75%) TMR effect in (Ga,Mn)As/AlAs/(Ga,Mn)As trilayers was presen- © P. Sankowski, P. Kacman, J.A. Majewski, and T. Dietl, 2007 ted first by Tanaka and Higo [13]. Recent experi- ments exhibit TMR even as high as 250% [14–16]. The further developement of spintronic devices re- quires deep understanding of vertical spin transport and a modeling tool that facilitates the design of new devices. Since the ferromagnetic coupling in (Ga,Mn)As is mediated by the holes [1,8], a meaning- ful theory has to take into account the entire complex- ity of the valence band, including the spin—orbit in- teraction. Furthermore, the intermixing of valence bands caused by spin—orbit coupling shortens the spin diffusion length and makes it comparable to the phase coherence length. This renders the models based on the classical spin-diffusion equation, which de- scribe satisfactorily the spin transport phenomena in metallic MTJs, nonapplicable directly to the struc- tures containing layers of hole-controlled diluted fer- romagnetic semiconductors. Recently, we have developed a computational scheme for vertical coherent spin transport. This mo- del combines the two-terminal Landauer—B�ttiker formalism with the empirical multi-orbital tight-bind- ing description of the semiconductor band structure. In this way, the quantum character of spin transport over the length scale relevant for the devices in ques- tion is taken into account. Furthermore, the tight-binding approach, in con- trast to kp models employed so-far [17,18], allows for a proper description of effects crucial for spin trans- port in heterostructures such as atomic structure of in- terfaces, effects of Rashba and Dresselhaus terms, as well as tunnel involving k states away from the center of the Brillouin zone. Our model has recently been ap- plied to describe selected features of Zener—Esaki di- odes [19,20] and TMR devices [20] and has also been as well as it was adopted to examine an intrinsic do- main-wall resistance in (Ga,Mn)As [21]. The present paper is organized as follows. In Sec. 2, we present the basics of the formalism employed. In Secs. 3 and 4, we discuss two basic phenomena men- tioned above, namely, the injection of spin polarized valence electrons into the conduction band of GaAs re- alized in the p-(Ga,Mn)As/n-GaAs Zener diode, and TMR effect in (Ga,Mn)As/GaAs/(Ga,Mn)As struc- tures. 2. Theoretical model We consider a prototype heterostructure which is uniform and infinite in the x and y directions, has modulated magnetization along the z ([001]) growth direction, and is connected to two semi-infinite bulk contacts denoted by L and R. In all cases considered, we assume that the bias is applied in such a way that spin-polarized carriers are injected from the ferromag- netic left lead. Our goal is to calculate the electric current in the structure and the degree of current spin polarization outside the left lead. The typical length of the structures studied is comparable to the phase coherence length. Therefore, we restrict ourselves to the vertical coherent transport regime that we treat within Landauer—B�ttiker formalism, where the cur- rent is determined by the transmission probability of the ingoing Bloch state at the left contact into the out- going Bloch state at the right contact. In the presence of spin—orbit coupling, the spin is not a good quan- tum number. The only conserved quantities in tunnel- ing are the energy E and, due to the spatial in-plane symmetry of our structures, the in-plane wave vector k | | . We use semi-empirical tight-binding formalism to calculate electronic states of the system for given k | | and E and further compute transmission coefficients. 2.1. Tight-binding model First, we describe the construction of the tight-binding Hamiltonian matrix for «normal» GaAs and AlAs as well as ferromagnetic (Ga,Mn)As layers of the heterostructure. To describe the band structure of the bulk GaAs and bulk AlAs, we use the nearest neighbor (NN) sp d s3 5 * tight—binding Hamiltonian (resulting in 20 spin-orbitals for each anion or cation), with the spin-orbit coupling included [22]. This model reproduces correctly the effective masses and the band structure of GaAs and AlAs in the whole Brillouin zone. With the tight-binding Hamiltonian introduced above, each double layer (cation + anion) is repre- sented by 40�40 matrix. It should be pointed out that the d orbitals used in our sp d s3 5 * parametrization are not related to the 3d semi-core states and are of no use for description of Mn ions incorporated into GaAs. The presence of Mn ions in (Ga,Mn)As is taken into account by including the (sp—d)-exchange interac- tions within the virtual crystal and mean-field approx- imations. In the spirit of the tight-binding method, the effects of an external interaction are included in the on-site diagonal matrix elements of the tight-bind- ing Hamiltonian. Here, the shifts of on-site energies caused by the (sp—d)-exchange interaction are parameterized in such a way that they reproduce ex- perimentally obtained spin splitting: N0 0 2� � . eV for the conduction band, and N0 12� � � . eV for the va- lence band [23]. The other parameters of the model for the (Ga,Mn)As material and for the NN interactions between GaAs and (Ga,Mn)As are taken to be the same as for GaAs. This is well motivated because the valence-band structure of (Ga,Mn)As with small frac- tion of Mn has been shown to be quite similar to that of GaAs [23]. Consequently, the valence band offset between (Ga,Mn)As and GaAs originates only from Vertical spin transport in semiconductor heterostructures Fizika Nizkikh Temperatur, 2007, v. 33, Nos. 2/3 257 the spin splitting of the bands in (Ga,Mn)As. The Fermi energy in the constituent materials is deter- mined by the assumed carrier concentration and is calculated from the density of states obtained for tight-binding Hamiltonian. Our calculations of the Fermi energy for various hole concentrations are con- sistent with the corresponding results presented in Ref. 8. Having determined the Hamiltonian of the system, we are now in the position to define the current and current spin polarization in the presence of spin—orbit coupling. 2.2. Current and current spin polarization For a given energy E and in-plane wave-vector k | | , the Bloch states in the left L and right R leads (i and j, respectively) are characterized by the wave vector component k� perpendicular to the layers and are denoted by | , , ,L kL i� � and | , , ,R kR j� �, respectively. The indices i and j indicate all possible pairs for 40 bands described by the tight-binding Hamiltonian. The transmission probability TL k R kL i R j, ,, , , ,� �� is a func- tion of the transmission amplitude t EL k R kL i R j, , | |, , , , ( , ) � �� k and group velocities in the left and right lead, vL i, ,� and vR j, ,� : T E t E L k R k L k R k L i R j L i R j , , | | , , | , , , , , , , , ( , ) ( , � � � � � � � � k k� �| , , , , ) . 2 v v R j L i � � (1) The current flowing in the rightward direction can now be written as [24] j e d k dEf E T L R BZ L L k R k k L i R j L � � � � � � � � � ( ) ( )| | , ,, , , , 2 3 2 � � , , , , , , , , , , | |( , ), � � � � � � i R j L i R j k v v E 0 k (2) where fL or respectively fR are the electron Fermi distributions in the left and right interface and i j, number the corresponding Bloch states. Plugging in the expresion given in Eq. (1) and using the time re- versal symmetry: T E T EL k R k L k R kL i R j R j L i, , | | , ,, , , , , , , , ( , ) ( , � � � �� � � ��k k | | ) , (3) we get � �j e d k dE f E f E BZ L R k k v L i R j L � � � � � � � � ( ) ( )— ( )| | ,, , , , , 2 3 2 � � � � , , , , , , , , , , | | , , , , ( , ) i R j L i R j v L k R k R j L i t E v v � � � � � � � � 0 2 k . (4) To calculate the current one has to determine the transmission probability, and thus the transmission amplitude t EL k kL i R R j, | |, , , , , ( , ) � �� k and the group ve- locities vL j, ,� of the ingoing and vR j, ,� of the outgo- ing states. These can be obtained by solving the Schr�dinger equation for the structure with appropri- ate scattering boundary conditions. In our studies, we follow closely the procedure detailed in Refs. 25 and 26, which we have generalized to the case with spin—orbit coupling. In the studies of the Zener tunneling diode, we are mostly interested in the degradation of the spin polar- ization of carriers passing from the source (Ga,Mn)As to a paramagnetic n-GaAs drain. To quantify this deg- radation, we introduce the spin polarization of the outgoing Bloch state [27] defined as P E R k R kR k R i R iR i, | | , , , ,, , ( , ) , | | , , � � � �� �k sΩ (5) where Ω is the direction of the spontaneous magneti- zation in the ferromagnetic semiconductor and s is the spin operator. Then, we can define the total spin po- larized current: j e d k dE f E f Es BZ L R k k v L i R j � � � � � � � ( ) [ ( )— ( )]| | ,, , , , 2 3 2 � � L i R j L i R j R i v L k R k R kT E P , , , , , , , , , , , , , | | ,( , ) . � � � � � � �� 0 k (6) The spin polarization of the coherently transmitted current is now equal to P j js s� . (7) This scheme follows closely some ideas introduced re- cently in studies of the spin depolarization of holes in the (Ga,Mn)As/GaAlAs/p-GaAs structures [27] and will be employed to analyze the spin polarization of current in the Zener tunnel diode. 3. Results and discussion In this Section we employ the formalism described in the previous Section to the structures studied exper- imentally. We start the discussion with the Zener tun- nel diode and further we discuss TMR structures based on (Ga,Mn)As ferromagnetic semiconductors. 258 Fizika Nizkikh Temperatur, 2007, v. 33, Nos. 2/3 P. Sankowski, P. Kacman, J.A. Majewski, and T. Dietl 3.1. Zener tunnel diode A rather high 80% spin polarization of the tunnel- ing electrons from the valence band of (Ga,Mn)As to the GaAs conduction band has been recently obtained in Zener diodes [12,28]. This opens new perspectives for applications of electron spin injection. However, the experimentally observed degree of current spin po- larization exhibits a sharp decrease with the applied bias [12,28]. In the present paper we analyze theoreti- cally the transport in the Zener diode structures as a function of the applied bias employing the developed theoretical scheme involving transfer matrix formal- ism described in Sec. 2. However, within this formal- ism, one is not able to consider the whole structure in- vestigated experimentally, because of computational constraints. Therefore, we perform the analysis of the intriguing phenomenon of current drop with applied bias in two steps. First, we model the charge transport in the entire Zener diode (corresponding to the experi- mental structure) under bias using continuum theory and a commercial simulation tool [19]. This allows self-consistent calculations of semiconductor hetero- structures taking into account band-to-band tunnel- ing, recombination, and impact ionization. By these simulations a detailed understanding of the charge dis- tribution and the band lineup in the entire device can be achieved. Next, we consider the most essential part of the device consisting of p-Ga1�xMn xAs/n-GaAs tunnel junction using the calculated potential profile in the tight-binding Hamiltonian. According to the self-consistent calculations, the scattering region con- sists of approximately 120 monolayers of Ga1�xMn xAs and GaAs, and corresponds roughly to the depletion zone of the diode. In Fig. 1 we show the calculated potential profile in the structures used in experiments [12]. This potential profile has been ob- tained in self-consistent calculations for external re- verse bias ofV0 = 1.8 V, i.e., the voltage for which the interband tunneling process starts. This potential pro- file is the basis for the calculation of the spin-current polarization within the transfer matrix formalism. An additional component of the potential profile used in the transfer matrix formalism is the bias �V that cor- responds to the potential drop across the Zener diode when the bias on the whole spin-LED is changed. We assume a linear potential drop which fairly well ren- ders the real band bending across the p–n junction. In Fig. 2 the dependence of the current spin polar- ization on the external bias �V in the Zener tunneling diode is depicted. One can see that at low bias, the current spin polarization is of the order of 0.6, in good agreement with the experimental results (0.7–0.8). Interestingly, the current spin polarization decreases rapidly with �V. The strong dependence of current spin polarization on bias is again in agreement with the experimental findings, though a direct comparison is hampered by the fact that the exact relation be- tween �V and the total bias V applied to the device is known only from simulations. Having these obstacles in mind and to reduce computational burden, the cal- culations for higher bias (�V � 0.1 V) have been per- formed with lower accuracy. The latter is probably re- sponsible for the spread of current spin polarizations obtained in this region. It is pretty obvious that the degree of spin polariza- tion of the tunnel current may depend on these intrin- sic features of (Ga,Mn)As layers. For example, it is Vertical spin transport in semiconductor heterostructures Fizika Nizkikh Temperatur, 2007, v. 33, Nos. 2/3 259 AlGaAs AlGaAsGaAs (N+) (N) (P) (P) (P+) vb Cb Zener diode G aA s (G a, M n )A s Fig. 1. Potential profile for the entire experimental struc- ture at an external bias of V0 = 1.81 V. In the calculations of the coherent current only the Zener diode region is considered. 0.2 0 0.1 0.2 0.3 0.4 0.5 0.4 0.6 0.8 1.0 �V, V C u rr e n tp o la ri za tio n Fig. 2. The calculated current spin polarization as a func- tion of external bias for the Zener diode. well known that magnetic characteristics of (Ga,Mn)As depend strongly on both hole and manga- nese concentrations [8]. To investigate this problem, we have calculated the dependence of current spin po- larization on the hole concentration p and Mn content x. For these calculations we assume that the electron concentration is n � 1019 cm �3 as indicated by the ex- perimental results in Ref. 12. The dependencies of the current spin polarization on the hole concentration p and Mn content x � 0 08. are depicted in Fig. 3. These results show a strong decrease of the tunneling current spin polarization with the increase of hole concentra- tion. The spin injection in the Zener diode depends also crucially on the content of magnetic ions in the Ga1�xMn x layer. For x � 0 08. , we obtain the spin current polarization of the order of 60%, which agrees fairly well with the observations in [12]. Another problem in studies of spin currents is the role of anisotropy, since (Ga,Mn)As layers exhibit a variety of anisotropic properties [8,29,30]. We have also studied anisotropy effects in spin polarization of the tunneling current in the Zener diode within devel- oped the scattering formalism developed, gaining some insight into physical mechanism leading to such anisotropy [31]. 3.2. Tunneling magnetoresistance Now we demonstrate how the whole TMR semicon- ductor structures can be modeled by the formalism de- veloped. In our calculations of the TMR effect we con- sider the structure consisting of three layers. The two half-infinite leads are build made of ferromagnetic p-type Ga1�xMn xAs. The middle, scattering region is composed of the nonmagnetic GaAs, which forms a barrier for the holes. We compare the tunneling currents in two configurations, i.e., with parallel (ferromagnetic — FM) and the antiparallel (anti- ferromagnetic — AFM) alignments of the spontane- ous magnetizations in the leads. We define the TMR as TMR � I I I FM AFM AFM — , (8) where IFM and IAFM are the currents in the FM and AFM configurations of the spontaneous magneti- zations in the leads, respectively. In Fig. 4,a the TMR values obtained, for a given (8%) Mn content and a set of different hole concentrations in the FM layers are plotted as a function of the applied bias. As can easily be seen from the Fig. 4, TMR depends strongly on the hole concentration. As TMR is deter- mined primarily by the spin polarization of the carri- ers at the Fermi level, this is in agreement with the result of Ref. 8 stating that the higher the hole con- centration the smaller is the polarization at the Fermi level. For p � 3 5 1020. cm �3, which is the typical hole concentration in (Ga,Mn)As samples with high Mn content [32], a TMR of about 250% has been ob- tained. Recent experiments show that in Ga1�xMn xAs samples the Fermi energy of the hole liquid remains equal about 220 meV for a wide range of Mn content and that the hole concentration depends very little on x [33] — thus, in the following we have calculated a TMR for different x in the magnetic layers, while the hole concentration in these regions is kept equal to p � 3 5 1020. cm �3. The results of this study are pre- sented in Fig. 4,b. Surprisigly enough, our simple model fully repro- duces the experimental data: for structures with 8% of 260 Fizika Nizkikh Temperatur, 2007, v. 33, Nos. 2/3 P. Sankowski, P. Kacman, J.A. Majewski, and T. Dietl 1001 0 0.2 0.4 0.6 0.8 1.0 a 0 0.04 0.08 b C u rr e n ts p in p o la ri za tio n x 10 0.2 0.4 0.6 0.8 1.0 C u rr e n ts p in p o la ri za tio n p, 10 cm19 –3 Fig. 3. Spin current polarization in p-Ga1�xMnxAs/n-GaAs as a function of hole concentration p for x � 008. (a); Mn content x for p � �35 1020. cm�3 (b). The bias applied to the structure is V � 005. V. 1 2 3 4 5 6 7 2.5 2.0 1.5 1.0 0.5 1 10 100 0 0.04 0.08 x 3.0 T M R T M R p, 10 cm19 –3 a b Fig. 4. TMR in Ga1�xMnxAs/GaAs/Ga1�xMnxAs as a function of hole concentration p for fixed Mn content x � 008. (a); as a function of Mn content for fixed hole concentration p � �35 1020. cm�3 (b). The bias applied to the structure is V � 005. V. Mn we obtain the TMR of the order of 250%, as ob- served recently by Chiba et al. [15]; for 4% Mn the calculations lead to a TMR of the order of 60%, in per- fect agreement with the experimental observations [13,34]. Therefore, our calculations seem to suggest that for obtaining high TMR, large exchange split- tings, i.e., high concentrations content of magnetic ions, are needed. Unfortunately, the presented in Fig. 4 dependence suggests that the attempts to in- crease the hole concentration in (Ga,Mn)As, in order to obtain higher Curie temperature, may result in much smaller TMR in the structure. 4. Summary We have analyzed the vertical coherent spin transport in (Ga,Mn)As-based heterostructures using a tight-binding model together with the Landauer—B�ttiker formalism. Our studies reproduce quantitatively the recently observed high TMR in (Ga,Mn)As/(Al,Ga)As/(Ga,Mn)As trilayers. Within the formalism we are able to study spin polar- ization of the current. The theoretical calculations of (Ga,Mn)As/(Al,Ga)As Zener diodes demonstrate large spin polarization of the injected current in excel- lent agreement with experimental results. The model reproduces as well the experimentally observed strong dependence of the spin polarization of the injected current and TMR effect on the applied bias voltage, both in Zener and TMR heterostructures. It should be pointed out that our calculations do not take into ac- count, e.g., the interfacial roughness or the scattering on impurities or defects, magnons, and other physical effects that were previously ascribed to this intriguing bias dependence. Instead, the formalism employed de- scribes carefully the electronic structure of the heterostructure, especially at the interfaces. In con- trast to the standard ( )k p -method, the scattering for- malism based on the tight-binding scheme takes into account all the effects resulting from the electric field in the depletion zone, in particular Rashba and Dresselhaus terms which are essential for the lost of spin polarization. These features make the approach particularly suited for studying phenomena related to spin-polarized tunneling. This work was partly supported by the EC project NANOSPIN (FP6-2002-IST-015728). 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