Phonon spectrum and vibrational characteristics of linear nanostructures in solid matrices

The atomic dynamics of linear chains embedded in a crystalline matrix or adsorbed on its surface is studied. A linear chain formed by substitutional impurities in a surface layer and at the same time offsetting from this layer was analyzed particularly. This system models the actively studied expe...

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Veröffentlicht in:Физика низких температур
Datum:2015
Hauptverfasser: Manzhelii, E.V., Feodosyev, S.B., Gospodarev, I.A., Syrkin, E.S., Minakova, K.A.
Format: Artikel
Sprache:English
Veröffentlicht: Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України 2015
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Online Zugang:https://nasplib.isofts.kiev.ua/handle/123456789/127953
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Zitieren:Phonon spectrum and vibrational characteristics of linear nanostructures in solid matrices / E.V. Manzhelii, S.B. Feodosyev, I.A. Gospodarev, E.S. Syrkin, and K.A. Minakova // Физика низких температур. — 2015. — Т. 41, № 7. — С. 718–724. — Бібліогр.: 29 назв. — англ.

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Digital Library of Periodicals of National Academy of Sciences of Ukraine
id nasplib_isofts_kiev_ua-123456789-127953
record_format dspace
spelling Manzhelii, E.V.
Feodosyev, S.B.
Gospodarev, I.A.
Syrkin, E.S.
Minakova, K.A.
2017-12-31T16:30:45Z
2017-12-31T16:30:45Z
2015
Phonon spectrum and vibrational characteristics of linear nanostructures in solid matrices / E.V. Manzhelii, S.B. Feodosyev, I.A. Gospodarev, E.S. Syrkin, and K.A. Minakova // Физика низких температур. — 2015. — Т. 41, № 7. — С. 718–724. — Бібліогр.: 29 назв. — англ.
0132-6414
PACS: 65.80.–g, 61.72.–y, 63.20.–e
https://nasplib.isofts.kiev.ua/handle/123456789/127953
The atomic dynamics of linear chains embedded in a crystalline matrix or adsorbed on its surface is studied. A linear chain formed by substitutional impurities in a surface layer and at the same time offsetting from this layer was analyzed particularly. This system models the actively studied experimentally structures in which gas molecules are adsorbed on the walls of the bundles of carbon nanotubes located in certain medium. It is shown that the quasi-one-dimensional features are typical for the chains in which the interatomic interaction is higher than the interaction between the atoms of the chain and the atoms of the crystal matrix. On the local phonon density of atoms of the chain the transition to quasi-one-dimensional behavior has the form of the kink. In other words, it is the first (lowest-frequency) van Hove singularity, which in 3D structures (the system under consideration is generally three-dimensional) corresponds to the transition from closed to open constant-frequency (quasi-plane) surfaces. The local phonon densities of atoms in the chain have one-dimensional character at frequencies higher than the frequency of the van Hove singularity. The rms amplitude of embedded chains atoms vibrations is calculated and the behavior of the atomic vibrations contribution in the low-temperature heat capacity of the system is analyzed.
en
Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України
Физика низких температур
10th International Conference on Cryocrystals and Quantum Crystals (Final part)
Phonon spectrum and vibrational characteristics of linear nanostructures in solid matrices
Article
published earlier
institution Digital Library of Periodicals of National Academy of Sciences of Ukraine
collection DSpace DC
title Phonon spectrum and vibrational characteristics of linear nanostructures in solid matrices
spellingShingle Phonon spectrum and vibrational characteristics of linear nanostructures in solid matrices
Manzhelii, E.V.
Feodosyev, S.B.
Gospodarev, I.A.
Syrkin, E.S.
Minakova, K.A.
10th International Conference on Cryocrystals and Quantum Crystals (Final part)
title_short Phonon spectrum and vibrational characteristics of linear nanostructures in solid matrices
title_full Phonon spectrum and vibrational characteristics of linear nanostructures in solid matrices
title_fullStr Phonon spectrum and vibrational characteristics of linear nanostructures in solid matrices
title_full_unstemmed Phonon spectrum and vibrational characteristics of linear nanostructures in solid matrices
title_sort phonon spectrum and vibrational characteristics of linear nanostructures in solid matrices
author Manzhelii, E.V.
Feodosyev, S.B.
Gospodarev, I.A.
Syrkin, E.S.
Minakova, K.A.
author_facet Manzhelii, E.V.
Feodosyev, S.B.
Gospodarev, I.A.
Syrkin, E.S.
Minakova, K.A.
topic 10th International Conference on Cryocrystals and Quantum Crystals (Final part)
topic_facet 10th International Conference on Cryocrystals and Quantum Crystals (Final part)
publishDate 2015
language English
container_title Физика низких температур
publisher Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України
format Article
description The atomic dynamics of linear chains embedded in a crystalline matrix or adsorbed on its surface is studied. A linear chain formed by substitutional impurities in a surface layer and at the same time offsetting from this layer was analyzed particularly. This system models the actively studied experimentally structures in which gas molecules are adsorbed on the walls of the bundles of carbon nanotubes located in certain medium. It is shown that the quasi-one-dimensional features are typical for the chains in which the interatomic interaction is higher than the interaction between the atoms of the chain and the atoms of the crystal matrix. On the local phonon density of atoms of the chain the transition to quasi-one-dimensional behavior has the form of the kink. In other words, it is the first (lowest-frequency) van Hove singularity, which in 3D structures (the system under consideration is generally three-dimensional) corresponds to the transition from closed to open constant-frequency (quasi-plane) surfaces. The local phonon densities of atoms in the chain have one-dimensional character at frequencies higher than the frequency of the van Hove singularity. The rms amplitude of embedded chains atoms vibrations is calculated and the behavior of the atomic vibrations contribution in the low-temperature heat capacity of the system is analyzed.
issn 0132-6414
url https://nasplib.isofts.kiev.ua/handle/123456789/127953
citation_txt Phonon spectrum and vibrational characteristics of linear nanostructures in solid matrices / E.V. Manzhelii, S.B. Feodosyev, I.A. Gospodarev, E.S. Syrkin, and K.A. Minakova // Физика низких температур. — 2015. — Т. 41, № 7. — С. 718–724. — Бібліогр.: 29 назв. — англ.
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AT syrkines phononspectrumandvibrationalcharacteristicsoflinearnanostructuresinsolidmatrices
AT minakovaka phononspectrumandvibrationalcharacteristicsoflinearnanostructuresinsolidmatrices
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