Charge-ordering induces magnetic axes rotation in organic materials (TMTTF)₂X (with X = SbF₆, AsF₆, and PF₆)
We have performed a comprehensive EPR investigation of the quasi-one-dimensional organic systems (TMTTF)₂X with centrosymmetrical anions X (X = SbF₆, AsF₆, and PF₆). We observe a strong rotation of g-factor principal axes when the temperature decreases below charge-ordering temperature TCO. The po...
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| Опубліковано в: : | Физика низких температур |
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| Дата: | 2015 |
| Автори: | , , , , |
| Формат: | Стаття |
| Мова: | English |
| Опубліковано: |
Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України
2015
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| Онлайн доступ: | https://nasplib.isofts.kiev.ua/handle/123456789/128242 |
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| Назва журналу: | Digital Library of Periodicals of National Academy of Sciences of Ukraine |
| Цитувати: | Charge-ordering induces magnetic axes rotation in organic materials (TMTTF)₂X (with X = SbF₆, AsF₆, and PF₆) / C.-E. Dutoit, S. Bertaina, M. Orio, M. Dressel, A. Stepanov // Физика низких температур. — 2015. — Т. 41, № 11. — С. 1206–1208. — Бібліогр.: 16 назв. — англ. |
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Digital Library of Periodicals of National Academy of Sciences of Ukraine| id |
nasplib_isofts_kiev_ua-123456789-128242 |
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Dutoit, C.-E. Bertaina, S. Orio, M. Dressel, M. Stepanov, A. 2018-01-07T14:22:27Z 2018-01-07T14:22:27Z 2015 Charge-ordering induces magnetic axes rotation in organic materials (TMTTF)₂X (with X = SbF₆, AsF₆, and PF₆) / C.-E. Dutoit, S. Bertaina, M. Orio, M. Dressel, A. Stepanov // Физика низких температур. — 2015. — Т. 41, № 11. — С. 1206–1208. — Бібліогр.: 16 назв. — англ. 0132-6414 PACS: 71.27.+a, 75.85.+t, 76.30.–v https://nasplib.isofts.kiev.ua/handle/123456789/128242 We have performed a comprehensive EPR investigation of the quasi-one-dimensional organic systems (TMTTF)₂X with centrosymmetrical anions X (X = SbF₆, AsF₆, and PF₆). We observe a strong rotation of g-factor principal axes when the temperature decreases below charge-ordering temperature TCO. The possible origin of this rotation is analyzed on the basis of quantum chemical calculations performed using density functional theory method. A good agreement between theory and experiment is found. This work was supported by CNRS's research federation RENARD (FR3443) for EPR facilities. en Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України Физика низких температур Кpаткие сообщения Charge-ordering induces magnetic axes rotation in organic materials (TMTTF)₂X (with X = SbF₆, AsF₆, and PF₆) Article published earlier |
| institution |
Digital Library of Periodicals of National Academy of Sciences of Ukraine |
| collection |
DSpace DC |
| title |
Charge-ordering induces magnetic axes rotation in organic materials (TMTTF)₂X (with X = SbF₆, AsF₆, and PF₆) |
| spellingShingle |
Charge-ordering induces magnetic axes rotation in organic materials (TMTTF)₂X (with X = SbF₆, AsF₆, and PF₆) Dutoit, C.-E. Bertaina, S. Orio, M. Dressel, M. Stepanov, A. Кpаткие сообщения |
| title_short |
Charge-ordering induces magnetic axes rotation in organic materials (TMTTF)₂X (with X = SbF₆, AsF₆, and PF₆) |
| title_full |
Charge-ordering induces magnetic axes rotation in organic materials (TMTTF)₂X (with X = SbF₆, AsF₆, and PF₆) |
| title_fullStr |
Charge-ordering induces magnetic axes rotation in organic materials (TMTTF)₂X (with X = SbF₆, AsF₆, and PF₆) |
| title_full_unstemmed |
Charge-ordering induces magnetic axes rotation in organic materials (TMTTF)₂X (with X = SbF₆, AsF₆, and PF₆) |
| title_sort |
charge-ordering induces magnetic axes rotation in organic materials (tmttf)₂x (with x = sbf₆, asf₆, and pf₆) |
| author |
Dutoit, C.-E. Bertaina, S. Orio, M. Dressel, M. Stepanov, A. |
| author_facet |
Dutoit, C.-E. Bertaina, S. Orio, M. Dressel, M. Stepanov, A. |
| topic |
Кpаткие сообщения |
| topic_facet |
Кpаткие сообщения |
| publishDate |
2015 |
| language |
English |
| container_title |
Физика низких температур |
| publisher |
Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України |
| format |
Article |
| description |
We have performed a comprehensive EPR investigation of the quasi-one-dimensional organic systems
(TMTTF)₂X with centrosymmetrical anions X (X = SbF₆, AsF₆, and PF₆). We observe a strong rotation of g-factor
principal axes when the temperature decreases below charge-ordering temperature TCO. The possible origin of
this rotation is analyzed on the basis of quantum chemical calculations performed using density functional theory
method. A good agreement between theory and experiment is found.
|
| issn |
0132-6414 |
| url |
https://nasplib.isofts.kiev.ua/handle/123456789/128242 |
| citation_txt |
Charge-ordering induces magnetic axes rotation in organic materials (TMTTF)₂X (with X = SbF₆, AsF₆, and PF₆) / C.-E. Dutoit, S. Bertaina, M. Orio, M. Dressel, A. Stepanov // Физика низких температур. — 2015. — Т. 41, № 11. — С. 1206–1208. — Бібліогр.: 16 назв. — англ. |
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2025-12-07T20:36:40Z |
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2025-12-07T20:36:40Z |
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