Particle transport phenomena in low temperature solids

We review different approaches to measure the transport of F atoms and ions in rare gas matrices and compare the experimental results to simulations. Static measurements on sandwich structures and co-doped matrices yield rather long travel ranges beyond 2 nm, in accord with early classical simulatio...

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Veröffentlicht in:Физика низких температур
Datum:2003
Hauptverfasser: Bargheer, N., Schwentner, M.
Format: Artikel
Sprache:Englisch
Veröffentlicht: Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України 2003
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Online Zugang:https://nasplib.isofts.kiev.ua/handle/123456789/128812
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Zitieren:Particle transport phenomena in low temperature solids / M. Bargheer, N. Schwentner // Физика низких температур. — 2003. — Т. 29, № 3. — С. 225-236. — Бібліогр.: 42 назв. — англ.

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Digital Library of Periodicals of National Academy of Sciences of Ukraine
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author Bargheer, N.
Schwentner, M.
author_facet Bargheer, N.
Schwentner, M.
citation_txt Particle transport phenomena in low temperature solids / M. Bargheer, N. Schwentner // Физика низких температур. — 2003. — Т. 29, № 3. — С. 225-236. — Бібліогр.: 42 назв. — англ.
collection DSpace DC
container_title Физика низких температур
description We review different approaches to measure the transport of F atoms and ions in rare gas matrices and compare the experimental results to simulations. Static measurements on sandwich structures and co-doped matrices yield rather long travel ranges beyond 2 nm, in accord with early classical simulations which predict a channeling of the F atoms in rare gas matrices. Nonadiabatic simulations show a rapid energy loss, fast nonadiabatic dynamics and only short travel ranges of typically 1 unit cell. The rapid energy loss, fast nonadiabatic transitions and the timescale for direct dissociation (~ 250 fs) are verified by fs-pump-probe experiments. It remains a challenge to account for the long-range migration when nonadiabatic processes are allowed in simulations, and to measure the long distance flights directly by ultrafast spectroscopy.
first_indexed 2025-11-30T23:07:53Z
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language English
last_indexed 2025-11-30T23:07:53Z
publishDate 2003
publisher Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України
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spelling Bargheer, N.
Schwentner, M.
2018-01-14T09:00:51Z
2018-01-14T09:00:51Z
2003
Particle transport phenomena in low temperature solids / M. Bargheer, N. Schwentner // Физика низких температур. — 2003. — Т. 29, № 3. — С. 225-236. — Бібліогр.: 42 назв. — англ.
0132-6414
PACS: 72.20.Jv
https://nasplib.isofts.kiev.ua/handle/123456789/128812
We review different approaches to measure the transport of F atoms and ions in rare gas matrices and compare the experimental results to simulations. Static measurements on sandwich structures and co-doped matrices yield rather long travel ranges beyond 2 nm, in accord with early classical simulations which predict a channeling of the F atoms in rare gas matrices. Nonadiabatic simulations show a rapid energy loss, fast nonadiabatic dynamics and only short travel ranges of typically 1 unit cell. The rapid energy loss, fast nonadiabatic transitions and the timescale for direct dissociation (~ 250 fs) are verified by fs-pump-probe experiments. It remains a challenge to account for the long-range migration when nonadiabatic processes are allowed in simulations, and to measure the long distance flights directly by ultrafast spectroscopy.
en
Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України
Физика низких температур
Electronically Induced Phenomena: Low Temperature Aspects
Particle transport phenomena in low temperature solids
Article
published earlier
spellingShingle Particle transport phenomena in low temperature solids
Bargheer, N.
Schwentner, M.
Electronically Induced Phenomena: Low Temperature Aspects
title Particle transport phenomena in low temperature solids
title_full Particle transport phenomena in low temperature solids
title_fullStr Particle transport phenomena in low temperature solids
title_full_unstemmed Particle transport phenomena in low temperature solids
title_short Particle transport phenomena in low temperature solids
title_sort particle transport phenomena in low temperature solids
topic Electronically Induced Phenomena: Low Temperature Aspects
topic_facet Electronically Induced Phenomena: Low Temperature Aspects
url https://nasplib.isofts.kiev.ua/handle/123456789/128812
work_keys_str_mv AT bargheern particletransportphenomenainlowtemperaturesolids
AT schwentnerm particletransportphenomenainlowtemperaturesolids