Translational-rotational interaction in dynamics and thermodynamics of 2D atomic crystal with molecular impurity
The interaction between the rotational degrees of freedom of a diatomic molecular impurity and the phonon excitations of a two-dimensional atomic matrix commensurate with a substrate is investigated theoretically. It is shown, that the translational-rotational interaction changes the form of the rot...
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| Опубліковано в: : | Физика низких температур |
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| Дата: | 2003 |
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| Формат: | Стаття |
| Мова: | English |
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Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України
2003
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| Онлайн доступ: | https://nasplib.isofts.kiev.ua/handle/123456789/128916 |
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| Назва журналу: | Digital Library of Periodicals of National Academy of Sciences of Ukraine |
| Цитувати: | Translational-rotational interaction in dynamics and thermodynamics of 2D atomic crystal with molecular impurity / T.N. Antsygina, M.I. Poltavskaya, K.A. Chishko // Физика низких температур. — 2003. — Т. 29, № 9-10. — С. 961-966. — Бібліогр.: 12 назв. — англ. |
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Antsygina, T.N. Poltavskaya, M.I. Chishko, K.A. 2018-01-14T12:52:59Z 2018-01-14T12:52:59Z 2003 Translational-rotational interaction in dynamics and thermodynamics of 2D atomic crystal with molecular impurity / T.N. Antsygina, M.I. Poltavskaya, K.A. Chishko // Физика низких температур. — 2003. — Т. 29, № 9-10. — С. 961-966. — Бібліогр.: 12 назв. — англ. 0132-6414 PACS: 68.35.Dv, 68.35.Ja, 68.65.+g https://nasplib.isofts.kiev.ua/handle/123456789/128916 The interaction between the rotational degrees of freedom of a diatomic molecular impurity and the phonon excitations of a two-dimensional atomic matrix commensurate with a substrate is investigated theoretically. It is shown, that the translational-rotational interaction changes the form of the rotational kinetic energy operator as compared to the corresponding expression for a free rotator, and also renormalizes the parameters of the crystal field without change in its initial form. The contribution of the impurity rotational degrees of freedom to the low-temperature heat capacity for a dilute solution of diatomic molecules in an atomic two-dimensional matrix is calculated. The possibility of experimental observation of the effects obtained is discussed. en Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України Физика низких температур Physics in Quantum Crystals Translational-rotational interaction in dynamics and thermodynamics of 2D atomic crystal with molecular impurity Article published earlier |
| institution |
Digital Library of Periodicals of National Academy of Sciences of Ukraine |
| collection |
DSpace DC |
| title |
Translational-rotational interaction in dynamics and thermodynamics of 2D atomic crystal with molecular impurity |
| spellingShingle |
Translational-rotational interaction in dynamics and thermodynamics of 2D atomic crystal with molecular impurity Antsygina, T.N. Poltavskaya, M.I. Chishko, K.A. Physics in Quantum Crystals |
| title_short |
Translational-rotational interaction in dynamics and thermodynamics of 2D atomic crystal with molecular impurity |
| title_full |
Translational-rotational interaction in dynamics and thermodynamics of 2D atomic crystal with molecular impurity |
| title_fullStr |
Translational-rotational interaction in dynamics and thermodynamics of 2D atomic crystal with molecular impurity |
| title_full_unstemmed |
Translational-rotational interaction in dynamics and thermodynamics of 2D atomic crystal with molecular impurity |
| title_sort |
translational-rotational interaction in dynamics and thermodynamics of 2d atomic crystal with molecular impurity |
| author |
Antsygina, T.N. Poltavskaya, M.I. Chishko, K.A. |
| author_facet |
Antsygina, T.N. Poltavskaya, M.I. Chishko, K.A. |
| topic |
Physics in Quantum Crystals |
| topic_facet |
Physics in Quantum Crystals |
| publishDate |
2003 |
| language |
English |
| container_title |
Физика низких температур |
| publisher |
Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України |
| format |
Article |
| description |
The interaction between the rotational degrees of freedom of a diatomic molecular impurity and the phonon excitations of a two-dimensional atomic matrix commensurate with a substrate is investigated theoretically. It is shown, that the translational-rotational interaction changes the form of the rotational kinetic energy operator as compared to the corresponding expression for a free rotator, and also renormalizes the parameters of the crystal field without change in its initial form. The contribution of the impurity rotational degrees of freedom to the low-temperature heat capacity for a dilute solution of diatomic molecules in an atomic two-dimensional matrix is calculated. The possibility of experimental observation of the effects obtained is discussed.
|
| issn |
0132-6414 |
| url |
https://nasplib.isofts.kiev.ua/handle/123456789/128916 |
| citation_txt |
Translational-rotational interaction in dynamics and thermodynamics of 2D atomic crystal with molecular impurity / T.N. Antsygina, M.I. Poltavskaya, K.A. Chishko // Физика низких температур. — 2003. — Т. 29, № 9-10. — С. 961-966. — Бібліогр.: 12 назв. — англ. |
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2025-12-07T19:33:11Z |
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2025-12-07T19:33:11Z |
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