Translational-rotational interaction in dynamics and thermodynamics of 2D atomic crystal with molecular impurity

The interaction between the rotational degrees of freedom of a diatomic molecular impurity and the phonon excitations of a two-dimensional atomic matrix commensurate with a substrate is investigated theoretically. It is shown, that the translational-rotational interaction changes the form of the rot...

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Veröffentlicht in:Физика низких температур
Datum:2003
Hauptverfasser: Antsygina, T.N., Poltavskaya, M.I., Chishko, K.A.
Format: Artikel
Sprache:Englisch
Veröffentlicht: Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України 2003
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Online Zugang:https://nasplib.isofts.kiev.ua/handle/123456789/128916
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Zitieren:Translational-rotational interaction in dynamics and thermodynamics of 2D atomic crystal with molecular impurity / T.N. Antsygina, M.I. Poltavskaya, K.A. Chishko // Физика низких температур. — 2003. — Т. 29, № 9-10. — С. 961-966. — Бібліогр.: 12 назв. — англ.

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Digital Library of Periodicals of National Academy of Sciences of Ukraine
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author Antsygina, T.N.
Poltavskaya, M.I.
Chishko, K.A.
author_facet Antsygina, T.N.
Poltavskaya, M.I.
Chishko, K.A.
citation_txt Translational-rotational interaction in dynamics and thermodynamics of 2D atomic crystal with molecular impurity / T.N. Antsygina, M.I. Poltavskaya, K.A. Chishko // Физика низких температур. — 2003. — Т. 29, № 9-10. — С. 961-966. — Бібліогр.: 12 назв. — англ.
collection DSpace DC
container_title Физика низких температур
description The interaction between the rotational degrees of freedom of a diatomic molecular impurity and the phonon excitations of a two-dimensional atomic matrix commensurate with a substrate is investigated theoretically. It is shown, that the translational-rotational interaction changes the form of the rotational kinetic energy operator as compared to the corresponding expression for a free rotator, and also renormalizes the parameters of the crystal field without change in its initial form. The contribution of the impurity rotational degrees of freedom to the low-temperature heat capacity for a dilute solution of diatomic molecules in an atomic two-dimensional matrix is calculated. The possibility of experimental observation of the effects obtained is discussed.
first_indexed 2025-12-07T19:33:11Z
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institution Digital Library of Periodicals of National Academy of Sciences of Ukraine
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language English
last_indexed 2025-12-07T19:33:11Z
publishDate 2003
publisher Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України
record_format dspace
spelling Antsygina, T.N.
Poltavskaya, M.I.
Chishko, K.A.
2018-01-14T12:52:59Z
2018-01-14T12:52:59Z
2003
Translational-rotational interaction in dynamics and thermodynamics of 2D atomic crystal with molecular impurity / T.N. Antsygina, M.I. Poltavskaya, K.A. Chishko // Физика низких температур. — 2003. — Т. 29, № 9-10. — С. 961-966. — Бібліогр.: 12 назв. — англ.
0132-6414
PACS: 68.35.Dv, 68.35.Ja, 68.65.+g
https://nasplib.isofts.kiev.ua/handle/123456789/128916
The interaction between the rotational degrees of freedom of a diatomic molecular impurity and the phonon excitations of a two-dimensional atomic matrix commensurate with a substrate is investigated theoretically. It is shown, that the translational-rotational interaction changes the form of the rotational kinetic energy operator as compared to the corresponding expression for a free rotator, and also renormalizes the parameters of the crystal field without change in its initial form. The contribution of the impurity rotational degrees of freedom to the low-temperature heat capacity for a dilute solution of diatomic molecules in an atomic two-dimensional matrix is calculated. The possibility of experimental observation of the effects obtained is discussed.
en
Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України
Физика низких температур
Physics in Quantum Crystals
Translational-rotational interaction in dynamics and thermodynamics of 2D atomic crystal with molecular impurity
Article
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spellingShingle Translational-rotational interaction in dynamics and thermodynamics of 2D atomic crystal with molecular impurity
Antsygina, T.N.
Poltavskaya, M.I.
Chishko, K.A.
Physics in Quantum Crystals
title Translational-rotational interaction in dynamics and thermodynamics of 2D atomic crystal with molecular impurity
title_full Translational-rotational interaction in dynamics and thermodynamics of 2D atomic crystal with molecular impurity
title_fullStr Translational-rotational interaction in dynamics and thermodynamics of 2D atomic crystal with molecular impurity
title_full_unstemmed Translational-rotational interaction in dynamics and thermodynamics of 2D atomic crystal with molecular impurity
title_short Translational-rotational interaction in dynamics and thermodynamics of 2D atomic crystal with molecular impurity
title_sort translational-rotational interaction in dynamics and thermodynamics of 2d atomic crystal with molecular impurity
topic Physics in Quantum Crystals
topic_facet Physics in Quantum Crystals
url https://nasplib.isofts.kiev.ua/handle/123456789/128916
work_keys_str_mv AT antsyginatn translationalrotationalinteractionindynamicsandthermodynamicsof2datomiccrystalwithmolecularimpurity
AT poltavskayami translationalrotationalinteractionindynamicsandthermodynamicsof2datomiccrystalwithmolecularimpurity
AT chishkoka translationalrotationalinteractionindynamicsandthermodynamicsof2datomiccrystalwithmolecularimpurity