Role of the orientational subsystem in the expansion of pure CF₆, CHCl₃, C₆H₆, CCl₄ and N₂O with Kr impurity

The linear expansion coefficients of solid bulk samples of N₂O with Kr 5% impurity are measured by an absolute dilatometric method in comparison with pure N₂O in the temperature range 80–150 K. An additional unusual orientational effect is discussed. An analysis of the data from measurements of the...

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Published in:Физика низких температур
Date:2003
Main Authors: Zholonko, N.N., Tsibulin, V.V., Sarwar, I.
Format: Article
Language:English
Published: Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України 2003
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Online Access:https://nasplib.isofts.kiev.ua/handle/123456789/128924
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Journal Title:Digital Library of Periodicals of National Academy of Sciences of Ukraine
Cite this:Role of the orientational subsystem in the expansion of pure CF₆, CHCl₃, C₆H₆, CCl₄ and N₂O with Kr impurity / N.N. Zholonko, V.V. Tsibulin, I. Sarwar // Физика низких температур. — 2003. — Т. 29, № 9-10. — С. 1018-1020. — Бібліогр.: 16 назв. — англ.

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Digital Library of Periodicals of National Academy of Sciences of Ukraine
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author Zholonko, N.N.
Tsibulin, V.V.
Sarwar, I.
author_facet Zholonko, N.N.
Tsibulin, V.V.
Sarwar, I.
citation_txt Role of the orientational subsystem in the expansion of pure CF₆, CHCl₃, C₆H₆, CCl₄ and N₂O with Kr impurity / N.N. Zholonko, V.V. Tsibulin, I. Sarwar // Физика низких температур. — 2003. — Т. 29, № 9-10. — С. 1018-1020. — Бібліогр.: 16 назв. — англ.
collection DSpace DC
container_title Физика низких температур
description The linear expansion coefficients of solid bulk samples of N₂O with Kr 5% impurity are measured by an absolute dilatometric method in comparison with pure N₂O in the temperature range 80–150 K. An additional unusual orientational effect is discussed. An analysis of the data from measurements of the linear expansion coefficients of pure solid SF₆, CHCl₃,C₆H₆, CCl₄ in comparison with solid Xe in the temperature range 80–170 K is carried out in order to determine the role of molecules` orientational disordering in the thermal expansion of the given condensed systems. The results are discussed in connection with the problem of determining the contribution of orientational subsystems with different types of molecular symmetry to the total thermal expansion and its behavior in various temperature intervals of solid phase existence.
first_indexed 2025-12-01T11:27:48Z
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language English
last_indexed 2025-12-01T11:27:48Z
publishDate 2003
publisher Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України
record_format dspace
spelling Zholonko, N.N.
Tsibulin, V.V.
Sarwar, I.
2018-01-14T13:01:45Z
2018-01-14T13:01:45Z
2003
Role of the orientational subsystem in the expansion of pure CF₆, CHCl₃, C₆H₆, CCl₄ and N₂O with Kr impurity / N.N. Zholonko, V.V. Tsibulin, I. Sarwar // Физика низких температур. — 2003. — Т. 29, № 9-10. — С. 1018-1020. — Бібліогр.: 16 назв. — англ.
0132-6414
PACS: 65.70.+y
https://nasplib.isofts.kiev.ua/handle/123456789/128924
The linear expansion coefficients of solid bulk samples of N₂O with Kr 5% impurity are measured by an absolute dilatometric method in comparison with pure N₂O in the temperature range 80–150 K. An additional unusual orientational effect is discussed. An analysis of the data from measurements of the linear expansion coefficients of pure solid SF₆, CHCl₃,C₆H₆, CCl₄ in comparison with solid Xe in the temperature range 80–170 K is carried out in order to determine the role of molecules` orientational disordering in the thermal expansion of the given condensed systems. The results are discussed in connection with the problem of determining the contribution of orientational subsystems with different types of molecular symmetry to the total thermal expansion and its behavior in various temperature intervals of solid phase existence.
en
Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України
Физика низких температур
Low-Temperature Thermodynamics and Structure
Role of the orientational subsystem in the expansion of pure CF₆, CHCl₃, C₆H₆, CCl₄ and N₂O with Kr impurity
Article
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spellingShingle Role of the orientational subsystem in the expansion of pure CF₆, CHCl₃, C₆H₆, CCl₄ and N₂O with Kr impurity
Zholonko, N.N.
Tsibulin, V.V.
Sarwar, I.
Low-Temperature Thermodynamics and Structure
title Role of the orientational subsystem in the expansion of pure CF₆, CHCl₃, C₆H₆, CCl₄ and N₂O with Kr impurity
title_full Role of the orientational subsystem in the expansion of pure CF₆, CHCl₃, C₆H₆, CCl₄ and N₂O with Kr impurity
title_fullStr Role of the orientational subsystem in the expansion of pure CF₆, CHCl₃, C₆H₆, CCl₄ and N₂O with Kr impurity
title_full_unstemmed Role of the orientational subsystem in the expansion of pure CF₆, CHCl₃, C₆H₆, CCl₄ and N₂O with Kr impurity
title_short Role of the orientational subsystem in the expansion of pure CF₆, CHCl₃, C₆H₆, CCl₄ and N₂O with Kr impurity
title_sort role of the orientational subsystem in the expansion of pure cf₆, chcl₃, c₆h₆, ccl₄ and n₂o with kr impurity
topic Low-Temperature Thermodynamics and Structure
topic_facet Low-Temperature Thermodynamics and Structure
url https://nasplib.isofts.kiev.ua/handle/123456789/128924
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