Influence of rotational motion of molecules on the thermal conductivity of solid SF₆, CHCl₃, C₆H₆, and CCl₄

The thermal conductivity of solid SF₆, CHCI₃, C₆H₆, and CCl₄ was investigated by the linear-flow method under saturated vapor pressures in the temperature range from 80 K to the corresponding melting temperatures and then recalculated for a constant density of the samples. The contributions of the p...

Full description

Saved in:
Bibliographic Details
Published in:Физика низких температур
Date:2003
Main Authors: Purskii, O.I., Zholonko, N.N., Konstantinov, V.A.
Format: Article
Language:English
Published: Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України 2003
Subjects:
Online Access:https://nasplib.isofts.kiev.ua/handle/123456789/128926
Tags: Add Tag
No Tags, Be the first to tag this record!
Journal Title:Digital Library of Periodicals of National Academy of Sciences of Ukraine
Cite this:Influence of rotational motion of molecules on the thermal conductivity of solid SF₆, CHCl₃, C₆H₆, and CCl₄ / O.I. Purskii, N.N. Zholonko, V.A. Konstantinov // Физика низких температур. — 2003. — Т. 29, № 9-10. — С. 1021-1026. — Бібліогр.: 31 назв. — англ.

Institution

Digital Library of Periodicals of National Academy of Sciences of Ukraine
id nasplib_isofts_kiev_ua-123456789-128926
record_format dspace
spelling Purskii, O.I.
Zholonko, N.N.
Konstantinov, V.A.
2018-01-14T13:03:04Z
2018-01-14T13:03:04Z
2003
Influence of rotational motion of molecules on the thermal conductivity of solid SF₆, CHCl₃, C₆H₆, and CCl₄ / O.I. Purskii, N.N. Zholonko, V.A. Konstantinov // Физика низких температур. — 2003. — Т. 29, № 9-10. — С. 1021-1026. — Бібліогр.: 31 назв. — англ.
0132-6414
PACS: 66.70.+f;, 63.20.Ls;, 44.50.+f
https://nasplib.isofts.kiev.ua/handle/123456789/128926
The thermal conductivity of solid SF₆, CHCI₃, C₆H₆, and CCl₄ was investigated by the linear-flow method under saturated vapor pressures in the temperature range from 80 K to the corresponding melting temperatures and then recalculated for a constant density of the samples. The contributions of the phonon–phonon and phonon–rotation interactions to the total thermal resistance were separated using the modified method of reduced coordinates. It is shown that the phonon–rotation contribution to the thermal resistance of the crystals decreases as the rotational motion of the molecules attains more freedom.
en
Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України
Физика низких температур
Low-Temperature Thermodynamics and Structure
Influence of rotational motion of molecules on the thermal conductivity of solid SF₆, CHCl₃, C₆H₆, and CCl₄
Article
published earlier
institution Digital Library of Periodicals of National Academy of Sciences of Ukraine
collection DSpace DC
title Influence of rotational motion of molecules on the thermal conductivity of solid SF₆, CHCl₃, C₆H₆, and CCl₄
spellingShingle Influence of rotational motion of molecules on the thermal conductivity of solid SF₆, CHCl₃, C₆H₆, and CCl₄
Purskii, O.I.
Zholonko, N.N.
Konstantinov, V.A.
Low-Temperature Thermodynamics and Structure
title_short Influence of rotational motion of molecules on the thermal conductivity of solid SF₆, CHCl₃, C₆H₆, and CCl₄
title_full Influence of rotational motion of molecules on the thermal conductivity of solid SF₆, CHCl₃, C₆H₆, and CCl₄
title_fullStr Influence of rotational motion of molecules on the thermal conductivity of solid SF₆, CHCl₃, C₆H₆, and CCl₄
title_full_unstemmed Influence of rotational motion of molecules on the thermal conductivity of solid SF₆, CHCl₃, C₆H₆, and CCl₄
title_sort influence of rotational motion of molecules on the thermal conductivity of solid sf₆, chcl₃, c₆h₆, and ccl₄
author Purskii, O.I.
Zholonko, N.N.
Konstantinov, V.A.
author_facet Purskii, O.I.
Zholonko, N.N.
Konstantinov, V.A.
topic Low-Temperature Thermodynamics and Structure
topic_facet Low-Temperature Thermodynamics and Structure
publishDate 2003
language English
container_title Физика низких температур
publisher Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України
format Article
description The thermal conductivity of solid SF₆, CHCI₃, C₆H₆, and CCl₄ was investigated by the linear-flow method under saturated vapor pressures in the temperature range from 80 K to the corresponding melting temperatures and then recalculated for a constant density of the samples. The contributions of the phonon–phonon and phonon–rotation interactions to the total thermal resistance were separated using the modified method of reduced coordinates. It is shown that the phonon–rotation contribution to the thermal resistance of the crystals decreases as the rotational motion of the molecules attains more freedom.
issn 0132-6414
url https://nasplib.isofts.kiev.ua/handle/123456789/128926
citation_txt Influence of rotational motion of molecules on the thermal conductivity of solid SF₆, CHCl₃, C₆H₆, and CCl₄ / O.I. Purskii, N.N. Zholonko, V.A. Konstantinov // Физика низких температур. — 2003. — Т. 29, № 9-10. — С. 1021-1026. — Бібліогр.: 31 назв. — англ.
work_keys_str_mv AT purskiioi influenceofrotationalmotionofmoleculesonthethermalconductivityofsolidsf6chcl3c6h6andccl4
AT zholonkonn influenceofrotationalmotionofmoleculesonthethermalconductivityofsolidsf6chcl3c6h6andccl4
AT konstantinovva influenceofrotationalmotionofmoleculesonthethermalconductivityofsolidsf6chcl3c6h6andccl4
first_indexed 2025-12-07T20:36:41Z
last_indexed 2025-12-07T20:36:41Z
_version_ 1850883232790216704