Influence of rotational motion of molecules on the thermal conductivity of solid SF₆, CHCl₃, C₆H₆, and CCl₄
The thermal conductivity of solid SF₆, CHCI₃, C₆H₆, and CCl₄ was investigated by the linear-flow method under saturated vapor pressures in the temperature range from 80 K to the corresponding melting temperatures and then recalculated for a constant density of the samples. The contributions of the p...
Gespeichert in:
| Veröffentlicht in: | Физика низких температур |
|---|---|
| Datum: | 2003 |
| Hauptverfasser: | , , |
| Format: | Artikel |
| Sprache: | Englisch |
| Veröffentlicht: |
Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України
2003
|
| Schlagworte: | |
| Online Zugang: | https://nasplib.isofts.kiev.ua/handle/123456789/128926 |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| Назва журналу: | Digital Library of Periodicals of National Academy of Sciences of Ukraine |
| Zitieren: | Influence of rotational motion of molecules on the thermal conductivity of solid SF₆, CHCl₃, C₆H₆, and CCl₄ / O.I. Purskii, N.N. Zholonko, V.A. Konstantinov // Физика низких температур. — 2003. — Т. 29, № 9-10. — С. 1021-1026. — Бібліогр.: 31 назв. — англ. |
Institution
Digital Library of Periodicals of National Academy of Sciences of Ukraine| _version_ | 1862744569401049088 |
|---|---|
| author | Purskii, O.I. Zholonko, N.N. Konstantinov, V.A. |
| author_facet | Purskii, O.I. Zholonko, N.N. Konstantinov, V.A. |
| citation_txt | Influence of rotational motion of molecules on the thermal conductivity of solid SF₆, CHCl₃, C₆H₆, and CCl₄ / O.I. Purskii, N.N. Zholonko, V.A. Konstantinov // Физика низких температур. — 2003. — Т. 29, № 9-10. — С. 1021-1026. — Бібліогр.: 31 назв. — англ. |
| collection | DSpace DC |
| container_title | Физика низких температур |
| description | The thermal conductivity of solid SF₆, CHCI₃, C₆H₆, and CCl₄ was investigated by the linear-flow method under saturated vapor pressures in the temperature range from 80 K to the corresponding melting temperatures and then recalculated for a constant density of the samples. The contributions of the phonon–phonon and phonon–rotation interactions to the total thermal resistance were separated using the modified method of reduced coordinates. It is shown that the phonon–rotation contribution to the thermal resistance of the crystals decreases as the rotational motion of the molecules attains more freedom.
|
| first_indexed | 2025-12-07T20:36:41Z |
| format | Article |
| fulltext | |
| id | nasplib_isofts_kiev_ua-123456789-128926 |
| institution | Digital Library of Periodicals of National Academy of Sciences of Ukraine |
| issn | 0132-6414 |
| language | English |
| last_indexed | 2025-12-07T20:36:41Z |
| publishDate | 2003 |
| publisher | Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України |
| record_format | dspace |
| spelling | Purskii, O.I. Zholonko, N.N. Konstantinov, V.A. 2018-01-14T13:03:04Z 2018-01-14T13:03:04Z 2003 Influence of rotational motion of molecules on the thermal conductivity of solid SF₆, CHCl₃, C₆H₆, and CCl₄ / O.I. Purskii, N.N. Zholonko, V.A. Konstantinov // Физика низких температур. — 2003. — Т. 29, № 9-10. — С. 1021-1026. — Бібліогр.: 31 назв. — англ. 0132-6414 PACS: 66.70.+f;, 63.20.Ls;, 44.50.+f https://nasplib.isofts.kiev.ua/handle/123456789/128926 The thermal conductivity of solid SF₆, CHCI₃, C₆H₆, and CCl₄ was investigated by the linear-flow method under saturated vapor pressures in the temperature range from 80 K to the corresponding melting temperatures and then recalculated for a constant density of the samples. The contributions of the phonon–phonon and phonon–rotation interactions to the total thermal resistance were separated using the modified method of reduced coordinates. It is shown that the phonon–rotation contribution to the thermal resistance of the crystals decreases as the rotational motion of the molecules attains more freedom. en Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України Физика низких температур Low-Temperature Thermodynamics and Structure Influence of rotational motion of molecules on the thermal conductivity of solid SF₆, CHCl₃, C₆H₆, and CCl₄ Article published earlier |
| spellingShingle | Influence of rotational motion of molecules on the thermal conductivity of solid SF₆, CHCl₃, C₆H₆, and CCl₄ Purskii, O.I. Zholonko, N.N. Konstantinov, V.A. Low-Temperature Thermodynamics and Structure |
| title | Influence of rotational motion of molecules on the thermal conductivity of solid SF₆, CHCl₃, C₆H₆, and CCl₄ |
| title_full | Influence of rotational motion of molecules on the thermal conductivity of solid SF₆, CHCl₃, C₆H₆, and CCl₄ |
| title_fullStr | Influence of rotational motion of molecules on the thermal conductivity of solid SF₆, CHCl₃, C₆H₆, and CCl₄ |
| title_full_unstemmed | Influence of rotational motion of molecules on the thermal conductivity of solid SF₆, CHCl₃, C₆H₆, and CCl₄ |
| title_short | Influence of rotational motion of molecules on the thermal conductivity of solid SF₆, CHCl₃, C₆H₆, and CCl₄ |
| title_sort | influence of rotational motion of molecules on the thermal conductivity of solid sf₆, chcl₃, c₆h₆, and ccl₄ |
| topic | Low-Temperature Thermodynamics and Structure |
| topic_facet | Low-Temperature Thermodynamics and Structure |
| url | https://nasplib.isofts.kiev.ua/handle/123456789/128926 |
| work_keys_str_mv | AT purskiioi influenceofrotationalmotionofmoleculesonthethermalconductivityofsolidsf6chcl3c6h6andccl4 AT zholonkonn influenceofrotationalmotionofmoleculesonthethermalconductivityofsolidsf6chcl3c6h6andccl4 AT konstantinovva influenceofrotationalmotionofmoleculesonthethermalconductivityofsolidsf6chcl3c6h6andccl4 |