Observation of crystallization of amorphous solid water under the conditions of secondary emission mass spectrometric experiments
A phenomenon of termination of sputtering of protonated water clusters (H2O)nH⁺ in low-temperature secondary emission mass spectrometric studies of solid water was observed in the temperature range of crystallization of amorphous solid water (ASW). In this range the mass spectra contained only H₃O⁺,...
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| Опубліковано в: : | Физика низких температур |
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| Дата: | 2003 |
| Автори: | , , , |
| Формат: | Стаття |
| Мова: | Англійська |
| Опубліковано: |
Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України
2003
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| Онлайн доступ: | https://nasplib.isofts.kiev.ua/handle/123456789/128931 |
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| Назва журналу: | Digital Library of Periodicals of National Academy of Sciences of Ukraine |
| Цитувати: | Observation of crystallization of amorphous solid water under the conditions of secondary emission mass spectrometric experiments / M.V. Kosevich, O.A. Boryak, V.S. Shelkovsky, V.V. Orlov // Физика низких температур. — 2003. — Т. 29, № 9-10. — С. 1061-1064. — Бібліогр.: 30 назв. — англ. |
Репозитарії
Digital Library of Periodicals of National Academy of Sciences of Ukraine| _version_ | 1862569450560028672 |
|---|---|
| author | Kosevich, M.V. Boryak, O.A. Shelkovsky, V.S. Orlov, V.V. |
| author_facet | Kosevich, M.V. Boryak, O.A. Shelkovsky, V.S. Orlov, V.V. |
| citation_txt | Observation of crystallization of amorphous solid water under the conditions of secondary emission mass spectrometric experiments / M.V. Kosevich, O.A. Boryak, V.S. Shelkovsky, V.V. Orlov // Физика низких температур. — 2003. — Т. 29, № 9-10. — С. 1061-1064. — Бібліогр.: 30 назв. — англ. |
| collection | DSpace DC |
| container_title | Физика низких температур |
| description | A phenomenon of termination of sputtering of protonated water clusters (H2O)nH⁺ in low-temperature secondary emission mass spectrometric studies of solid water was observed in the temperature range of crystallization of amorphous solid water (ASW). In this range the mass spectra contained only H₃O⁺, H₂O⁺•, and OH⁺ ions. The following explanation of the revealed phenomenon is suggested: the heat supplied to the ASW sample by the bombarding particles is spent on initiation of an amorphous–crystalline transition within the condensed sample but not for the transfer of the sample matter to the gas phase. At the same time heat released on crystallization causes a local rise in temperature of the crystallizing sample surface, which enhances the rate of sublimation of ice. The resulting increased concentration of subliming water molecules over the sample surface is reflected in the growth of abundance of H₂O⁺• molecular ion-radical, produced by gas-phase ionization mechanism. The appearance of a set of low-mass peaks in the course of crystallization observed for some types of ASW samples is explained by the release of gases trapped in the ASW film during its growth.
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| first_indexed | 2025-11-26T01:42:50Z |
| format | Article |
| fulltext | |
| id | nasplib_isofts_kiev_ua-123456789-128931 |
| institution | Digital Library of Periodicals of National Academy of Sciences of Ukraine |
| issn | 0132-6414 |
| language | English |
| last_indexed | 2025-11-26T01:42:50Z |
| publishDate | 2003 |
| publisher | Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України |
| record_format | dspace |
| spelling | Kosevich, M.V. Boryak, O.A. Shelkovsky, V.S. Orlov, V.V. 2018-01-14T13:08:47Z 2018-01-14T13:08:47Z 2003 Observation of crystallization of amorphous solid water under the conditions of secondary emission mass spectrometric experiments / M.V. Kosevich, O.A. Boryak, V.S. Shelkovsky, V.V. Orlov // Физика низких температур. — 2003. — Т. 29, № 9-10. — С. 1061-1064. — Бібліогр.: 30 назв. — англ. 0132-6414 PACS: 68.49.Sf, 64.70.Kb, 61.43.-j, 36.40.Wa https://nasplib.isofts.kiev.ua/handle/123456789/128931 A phenomenon of termination of sputtering of protonated water clusters (H2O)nH⁺ in low-temperature secondary emission mass spectrometric studies of solid water was observed in the temperature range of crystallization of amorphous solid water (ASW). In this range the mass spectra contained only H₃O⁺, H₂O⁺•, and OH⁺ ions. The following explanation of the revealed phenomenon is suggested: the heat supplied to the ASW sample by the bombarding particles is spent on initiation of an amorphous–crystalline transition within the condensed sample but not for the transfer of the sample matter to the gas phase. At the same time heat released on crystallization causes a local rise in temperature of the crystallizing sample surface, which enhances the rate of sublimation of ice. The resulting increased concentration of subliming water molecules over the sample surface is reflected in the growth of abundance of H₂O⁺• molecular ion-radical, produced by gas-phase ionization mechanism. The appearance of a set of low-mass peaks in the course of crystallization observed for some types of ASW samples is explained by the release of gases trapped in the ASW film during its growth. This work was partially supported by the grant INTAS-99-00478. en Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України Физика низких температур Biological Systems at Low Temperatures Observation of crystallization of amorphous solid water under the conditions of secondary emission mass spectrometric experiments Article published earlier |
| spellingShingle | Observation of crystallization of amorphous solid water under the conditions of secondary emission mass spectrometric experiments Kosevich, M.V. Boryak, O.A. Shelkovsky, V.S. Orlov, V.V. Biological Systems at Low Temperatures |
| title | Observation of crystallization of amorphous solid water under the conditions of secondary emission mass spectrometric experiments |
| title_full | Observation of crystallization of amorphous solid water under the conditions of secondary emission mass spectrometric experiments |
| title_fullStr | Observation of crystallization of amorphous solid water under the conditions of secondary emission mass spectrometric experiments |
| title_full_unstemmed | Observation of crystallization of amorphous solid water under the conditions of secondary emission mass spectrometric experiments |
| title_short | Observation of crystallization of amorphous solid water under the conditions of secondary emission mass spectrometric experiments |
| title_sort | observation of crystallization of amorphous solid water under the conditions of secondary emission mass spectrometric experiments |
| topic | Biological Systems at Low Temperatures |
| topic_facet | Biological Systems at Low Temperatures |
| url | https://nasplib.isofts.kiev.ua/handle/123456789/128931 |
| work_keys_str_mv | AT kosevichmv observationofcrystallizationofamorphoussolidwaterundertheconditionsofsecondaryemissionmassspectrometricexperiments AT boryakoa observationofcrystallizationofamorphoussolidwaterundertheconditionsofsecondaryemissionmassspectrometricexperiments AT shelkovskyvs observationofcrystallizationofamorphoussolidwaterundertheconditionsofsecondaryemissionmassspectrometricexperiments AT orlovvv observationofcrystallizationofamorphoussolidwaterundertheconditionsofsecondaryemissionmassspectrometricexperiments |