The vibrational relaxation of CO₂ isolated in solid argon
For description of the vibrational relaxation of CO₂ molecules embedded in Ar matrix the model based on multiphonon transitions is applied. Rates for the VT and VV processes are determined from a fitting of simulated and experimental data. The calculations confirmed that radiative processes influenc...
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| Published in: | Физика низких температур |
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| Date: | 2003 |
| Main Authors: | , , |
| Format: | Article |
| Language: | English |
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Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України
2003
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| Online Access: | https://nasplib.isofts.kiev.ua/handle/123456789/128942 |
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| Journal Title: | Digital Library of Periodicals of National Academy of Sciences of Ukraine |
| Cite this: | The vibrational relaxation of CO₂ isolated in solid argon / A. Cenian, G. Grigorian, G. Śliwiński // Физика низких температур. — 2003. — Т. 29, № 9-10. — С. 1135-1139. — Бібліогр.: 15 назв. — англ. |
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Digital Library of Periodicals of National Academy of Sciences of Ukraine| _version_ | 1862569452891013120 |
|---|---|
| author | Cenian, A. Grigorian, G. Śliwiński, G. |
| author_facet | Cenian, A. Grigorian, G. Śliwiński, G. |
| citation_txt | The vibrational relaxation of CO₂ isolated in solid argon / A. Cenian, G. Grigorian, G. Śliwiński // Физика низких температур. — 2003. — Т. 29, № 9-10. — С. 1135-1139. — Бібліогр.: 15 назв. — англ. |
| collection | DSpace DC |
| container_title | Физика низких температур |
| description | For description of the vibrational relaxation of CO₂ molecules embedded in Ar matrix the model based on multiphonon transitions is applied. Rates for the VT and VV processes are determined from a fitting of simulated and experimental data. The calculations confirmed that radiative processes influence significantly the vibrational energy relaxation of CO₂ embedded in solid Ar, e.g., the determined rate for energy transfer between n₃ and n₂. mode is significantly lower than that predicted under assumption of the nonradiative relaxation.
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| first_indexed | 2025-11-26T01:42:50Z |
| format | Article |
| fulltext | |
| id | nasplib_isofts_kiev_ua-123456789-128942 |
| institution | Digital Library of Periodicals of National Academy of Sciences of Ukraine |
| issn | 0132-6414 |
| language | English |
| last_indexed | 2025-11-26T01:42:50Z |
| publishDate | 2003 |
| publisher | Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України |
| record_format | dspace |
| spelling | Cenian, A. Grigorian, G. Śliwiński, G. 2018-01-14T13:21:33Z 2018-01-14T13:21:33Z 2003 The vibrational relaxation of CO₂ isolated in solid argon / A. Cenian, G. Grigorian, G. Śliwiński // Физика низких температур. — 2003. — Т. 29, № 9-10. — С. 1135-1139. — Бібліогр.: 15 назв. — англ. 0132-6414 PACS: 67.40.Fd https://nasplib.isofts.kiev.ua/handle/123456789/128942 For description of the vibrational relaxation of CO₂ molecules embedded in Ar matrix the model based on multiphonon transitions is applied. Rates for the VT and VV processes are determined from a fitting of simulated and experimental data. The calculations confirmed that radiative processes influence significantly the vibrational energy relaxation of CO₂ embedded in solid Ar, e.g., the determined rate for energy transfer between n₃ and n₂. mode is significantly lower than that predicted under assumption of the nonradiative relaxation. en Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України Физика низких температур Spectroscopy in Cryocrystals and Matrices The vibrational relaxation of CO₂ isolated in solid argon Article published earlier |
| spellingShingle | The vibrational relaxation of CO₂ isolated in solid argon Cenian, A. Grigorian, G. Śliwiński, G. Spectroscopy in Cryocrystals and Matrices |
| title | The vibrational relaxation of CO₂ isolated in solid argon |
| title_full | The vibrational relaxation of CO₂ isolated in solid argon |
| title_fullStr | The vibrational relaxation of CO₂ isolated in solid argon |
| title_full_unstemmed | The vibrational relaxation of CO₂ isolated in solid argon |
| title_short | The vibrational relaxation of CO₂ isolated in solid argon |
| title_sort | vibrational relaxation of co₂ isolated in solid argon |
| topic | Spectroscopy in Cryocrystals and Matrices |
| topic_facet | Spectroscopy in Cryocrystals and Matrices |
| url | https://nasplib.isofts.kiev.ua/handle/123456789/128942 |
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