Matrix-isolation FTIR study of azidoacetone and azidoacetonitrile

• Veröffentlicht in: Физика низких температур
• Datum: 2003
• ISSN: 0132-6414
• Hauptverfasser: Frankowski, Marcin, Algarra, Manuel, Rodrigues, Paula, Barros, Maria T., D.S. Cordeiro, M. Natália, Fox, Brigitte S., Smith-Gicklhorn, Alice M., Beyer, Martin K., Costa, Maria L., Bondybey, Vladimir E.
• Format: Artikel
• Sprache: Englisch
• Veröffentlicht: Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України 2003
• Schlagworte: Spectroscopy in Cryocrystals and Matrices
• Online Zugang: https://nasplib.isofts.kiev.ua/handle/123456789/128943
• Назва журналу: Digital Library of Periodicals of National Academy of Sciences of Ukraine
• Zitieren: Matrix-isolation FTIR study of azidoacetone and azidoacetonitrile / Marcin Frankowski, Manuel Algarra, Paula Rodrigues, Maria T. Barros, M. Natália D.S. Cordeiro, Brigitte S. Fox, Alice M. Smith-Gicklhorn, Martin K. Beyer, Maria L. Costa, Vladimir E. Bondybey // Физика низких температур. — 2003. — Т. 29, № 9-10. — С. 1140-1146. — Бібліогр.: 14 назв. — англ.

Azidoacetonitrile (N₃CH₂CN) and azidoacetone (N₃CH₂COCH₃) were studied by matrix-isolation FTIR spectroscopy in solid neon, argon and nitrogen. The IR spectra calculated using the density fuctional theoretical method are discussed in comparison with the experimental data. Significant broadening of the recorded azide bands indicate an awkward fit of these compounds into the solid environment. The strongest absorption is observed for both compounds in the regions of asymmetric and symmetric stretches of the N₃ azide group. Strong band splittings in the N₃ asymmetric stretch region can be most likely explained by very strong Fermi resonances with the CN stretch and combinations and overtones of the numerous lower frequency vibrational modes.