Ionization and hydrolysis of dinitrogen pentoxide in low-temperature solids
Solid layers of interest for the chemistry of polar stratospheric clouds were investigated. Mixtures of covalent N₂O₅ and water in various molar ratios are deposited from vapor phase on a cold 12 K substrate. By repeatedly recording Fourier transform infrared spectra of the samples during gradual wa...
Saved in:
| Published in: | Физика низких температур |
|---|---|
| Date: | 2001 |
| Main Authors: | , , |
| Format: | Article |
| Language: | English |
| Published: |
Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України
2001
|
| Subjects: | |
| Online Access: | https://nasplib.isofts.kiev.ua/handle/123456789/129024 |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| Journal Title: | Digital Library of Periodicals of National Academy of Sciences of Ukraine |
| Cite this: | Ionization and hydrolysis of dinitrogen pentoxide in low-temperature solids / J.Agreiter, 
 
 M.Frankowski, V.E. Bondybey // Физика низких температур. — 2001. — Т. 27, № 9-10. — С. 
 
 1202-1207. — Бібліогр.: 19 назв. — англ. |
Institution
Digital Library of Periodicals of National Academy of Sciences of Ukraine| _version_ | 1862672740308221952 |
|---|---|
| author | Agreiter, J. Frankowski, M. Bondybey, V.E. |
| author_facet | Agreiter, J. Frankowski, M. Bondybey, V.E. |
| citation_txt | Ionization and hydrolysis of dinitrogen pentoxide in low-temperature solids / J.Agreiter, 
 
 M.Frankowski, V.E. Bondybey // Физика низких температур. — 2001. — Т. 27, № 9-10. — С. 
 
 1202-1207. — Бібліогр.: 19 назв. — англ. |
| collection | DSpace DC |
| container_title | Физика низких температур |
| description | Solid layers of interest for the chemistry of polar stratospheric clouds were investigated. Mixtures of covalent N₂O₅ and water in various molar ratios are deposited from vapor phase on a cold 12 K substrate. By repeatedly recording Fourier transform infrared spectra of the samples during gradual warm up to 200 K over a period of several hours the hydrolysis process can be followed. At each concentration the process is found to proceed in several distinct steps with sharp temperature thresholds. In samples containing only small amounts of water the covalent N₂O₅ is first around 110 K converted to an ionic nitronium nitrate, and only in a subsequent step NO₂+NO₃- reacts to nitric acid.
|
| first_indexed | 2025-12-07T15:37:05Z |
| format | Article |
| fulltext | |
| id | nasplib_isofts_kiev_ua-123456789-129024 |
| institution | Digital Library of Periodicals of National Academy of Sciences of Ukraine |
| issn | 0132-6414 |
| language | English |
| last_indexed | 2025-12-07T15:37:05Z |
| publishDate | 2001 |
| publisher | Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України |
| record_format | dspace |
| spelling | Agreiter, J. Frankowski, M. Bondybey, V.E. 2018-01-15T13:26:10Z 2018-01-15T13:26:10Z 2001 Ionization and hydrolysis of dinitrogen pentoxide in low-temperature solids / J.Agreiter, 
 
 M.Frankowski, V.E. Bondybey // Физика низких температур. — 2001. — Т. 27, № 9-10. — С. 
 
 1202-1207. — Бібліогр.: 19 назв. — англ. 0132-6414 PACS: 78.30.-j https://nasplib.isofts.kiev.ua/handle/123456789/129024 Solid layers of interest for the chemistry of polar stratospheric clouds were investigated. Mixtures of covalent N₂O₅ and water in various molar ratios are deposited from vapor phase on a cold 12 K substrate. By repeatedly recording Fourier transform infrared spectra of the samples during gradual warm up to 200 K over a period of several hours the hydrolysis process can be followed. At each concentration the process is found to proceed in several distinct steps with sharp temperature thresholds. In samples containing only small amounts of water the covalent N₂O₅ is first around 110 K converted to an ionic nitronium nitrate, and only in a subsequent step NO₂+NO₃- reacts to nitric acid. en Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України Физика низких температур Статьи, посвященные столетию со дня рождения Л. В. Шубникова Ionization and hydrolysis of dinitrogen pentoxide in low-temperature solids Article published earlier |
| spellingShingle | Ionization and hydrolysis of dinitrogen pentoxide in low-temperature solids Agreiter, J. Frankowski, M. Bondybey, V.E. Статьи, посвященные столетию со дня рождения Л. В. Шубникова |
| title | Ionization and hydrolysis of dinitrogen pentoxide in low-temperature solids |
| title_full | Ionization and hydrolysis of dinitrogen pentoxide in low-temperature solids |
| title_fullStr | Ionization and hydrolysis of dinitrogen pentoxide in low-temperature solids |
| title_full_unstemmed | Ionization and hydrolysis of dinitrogen pentoxide in low-temperature solids |
| title_short | Ionization and hydrolysis of dinitrogen pentoxide in low-temperature solids |
| title_sort | ionization and hydrolysis of dinitrogen pentoxide in low-temperature solids |
| topic | Статьи, посвященные столетию со дня рождения Л. В. Шубникова |
| topic_facet | Статьи, посвященные столетию со дня рождения Л. В. Шубникова |
| url | https://nasplib.isofts.kiev.ua/handle/123456789/129024 |
| work_keys_str_mv | AT agreiterj ionizationandhydrolysisofdinitrogenpentoxideinlowtemperaturesolids AT frankowskim ionizationandhydrolysisofdinitrogenpentoxideinlowtemperaturesolids AT bondybeyve ionizationandhydrolysisofdinitrogenpentoxideinlowtemperaturesolids |