Experimental analysis of ¹³CO₂ infrared stimulated

Vibrational stimulated emissions of CO₂ trapped in low temperature argon matrices have been found experimentally not only in the 16 mm region (v₂ manifold) but also at 10 mm (v₃ - v₁ transition) in the double trapping site of concentrated samples. A detailed experimental description of these emissio...

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Veröffentlicht in:Физика низких температур
Datum:2000
Hauptverfasser: Chabbi, H., Dahoo, P.R., Dubost, H., Gauthier-Roy, B., Vasserot, A.-M., Abouaf-Marguin, L.
Format: Artikel
Sprache:Englisch
Veröffentlicht: Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України 2000
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Online Zugang:https://nasplib.isofts.kiev.ua/handle/123456789/129219
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Назва журналу:Digital Library of Periodicals of National Academy of Sciences of Ukraine
Zitieren:Experimental analysis of ¹³CO₂ infrared stimulated / H. Chabbi, P.R. Dahoo, H. Dubost, B. Gauthier-Roy, A.-M. Vasserot, L. Abouaf-Marguin // Физика низких температур. — 2000. — Т. 26, № 9-10. — С. 972-980. — Бібліогр.: 17 назв. — англ.

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Digital Library of Periodicals of National Academy of Sciences of Ukraine
Beschreibung
Zusammenfassung:Vibrational stimulated emissions of CO₂ trapped in low temperature argon matrices have been found experimentally not only in the 16 mm region (v₂ manifold) but also at 10 mm (v₃ - v₁ transition) in the double trapping site of concentrated samples. A detailed experimental description of these emissions is reported, including spectral analysis, time-resolved studies, laser energy dependence, and concentration and temperature effects. The characteristics of the emissions are discussed, giving some insight into the nonradiative intramolecular V–V transfers from the laser excited level v₃=1 towards the v₂ manifold, and inside this manifold.
ISSN:0132-6414