Reactions of laser-ablated aluminum atoms with nitrogen during condensation at 10 K. Infrared spectra and density functional calculations for Alx Ny molecular
Laser-ablated aluminum atoms react with dinitrogen on condensation at 10 K to form N₃ radicals and the subject molecules, which are identified by nitrogen isotopic substitution, further reactions on annealing, and comparison with isotopic frequencies computed by density functional theory. The major...
Gespeichert in:
| Veröffentlicht in: | Физика низких температур |
|---|---|
| Datum: | 2000 |
| Hauptverfasser: | , , , , |
| Format: | Artikel |
| Sprache: | English |
| Veröffentlicht: |
Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України
2000
|
| Schlagworte: | |
| Online Zugang: | https://nasplib.isofts.kiev.ua/handle/123456789/129221 |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| Назва журналу: | Digital Library of Periodicals of National Academy of Sciences of Ukraine |
| Zitieren: | Reactions of laser-ablated aluminum atoms with nitrogen during condensation at 10 K. Infrared spectra and density functional calculations for Alx Ny molecular / Lester Andrews, Mingfei Zhou, George V. Chertihin, William D. Bare, Yacine Hannachi // Физика низких температур. — 2000. — Т. 26, № 9-10. — С. 992-1000. — Бібліогр.: 30 назв. — англ. |
Institution
Digital Library of Periodicals of National Academy of Sciences of Ukraine| id |
nasplib_isofts_kiev_ua-123456789-129221 |
|---|---|
| record_format |
dspace |
| spelling |
Andrews, Lester Zhou, Mingfei Chertihin, George V. Bare, William D. Hannachi, Yacine 2018-01-17T19:59:43Z 2018-01-17T19:59:43Z 2000 Reactions of laser-ablated aluminum atoms with nitrogen during condensation at 10 K. Infrared spectra and density functional calculations for Alx Ny molecular / Lester Andrews, Mingfei Zhou, George V. Chertihin, William D. Bare, Yacine Hannachi // Физика низких температур. — 2000. — Т. 26, № 9-10. — С. 992-1000. — Бібліогр.: 30 назв. — англ. 0132-6414 PACS: 81.15.Fg, 82.30.Cf https://nasplib.isofts.kiev.ua/handle/123456789/129221 Laser-ablated aluminum atoms react with dinitrogen on condensation at 10 K to form N₃ radicals and the subject molecules, which are identified by nitrogen isotopic substitution, further reactions on annealing, and comparison with isotopic frequencies computed by density functional theory. The major AlN₃ product is identified from three fundamentals and a statistically mixed nitrogen isotopic octet pattern. The aluminum-rich Al₂N and Al₃N species are major products produced on annealing to allow diffusion and further reaction of trapped species. This work provides the first experimental evidence for molecular AlxNy species that may be involved in ceramic film growth. en Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України Физика низких температур Low-Temperature Physics and Chemistry in Cryomatrice Reactions of laser-ablated aluminum atoms with nitrogen during condensation at 10 K. Infrared spectra and density functional calculations for Alx Ny molecular Article published earlier |
| institution |
Digital Library of Periodicals of National Academy of Sciences of Ukraine |
| collection |
DSpace DC |
| title |
Reactions of laser-ablated aluminum atoms with nitrogen during condensation at 10 K. Infrared spectra and density functional calculations for Alx Ny molecular |
| spellingShingle |
Reactions of laser-ablated aluminum atoms with nitrogen during condensation at 10 K. Infrared spectra and density functional calculations for Alx Ny molecular Andrews, Lester Zhou, Mingfei Chertihin, George V. Bare, William D. Hannachi, Yacine Low-Temperature Physics and Chemistry in Cryomatrice |
| title_short |
Reactions of laser-ablated aluminum atoms with nitrogen during condensation at 10 K. Infrared spectra and density functional calculations for Alx Ny molecular |
| title_full |
Reactions of laser-ablated aluminum atoms with nitrogen during condensation at 10 K. Infrared spectra and density functional calculations for Alx Ny molecular |
| title_fullStr |
Reactions of laser-ablated aluminum atoms with nitrogen during condensation at 10 K. Infrared spectra and density functional calculations for Alx Ny molecular |
| title_full_unstemmed |
Reactions of laser-ablated aluminum atoms with nitrogen during condensation at 10 K. Infrared spectra and density functional calculations for Alx Ny molecular |
| title_sort |
reactions of laser-ablated aluminum atoms with nitrogen during condensation at 10 k. infrared spectra and density functional calculations for alx ny molecular |
| author |
Andrews, Lester Zhou, Mingfei Chertihin, George V. Bare, William D. Hannachi, Yacine |
| author_facet |
Andrews, Lester Zhou, Mingfei Chertihin, George V. Bare, William D. Hannachi, Yacine |
| topic |
Low-Temperature Physics and Chemistry in Cryomatrice |
| topic_facet |
Low-Temperature Physics and Chemistry in Cryomatrice |
| publishDate |
2000 |
| language |
English |
| container_title |
Физика низких температур |
| publisher |
Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України |
| format |
Article |
| description |
Laser-ablated aluminum atoms react with dinitrogen on condensation at 10 K to form N₃ radicals and the subject molecules, which are identified by nitrogen isotopic substitution, further reactions on annealing, and comparison with isotopic frequencies computed by density functional theory. The major AlN₃ product is identified from three fundamentals and a statistically mixed nitrogen isotopic octet pattern. The aluminum-rich Al₂N and Al₃N species are major products produced on annealing to allow diffusion and further reaction of trapped species. This work provides the first experimental evidence for molecular AlxNy species that may be involved in ceramic film growth.
|
| issn |
0132-6414 |
| url |
https://nasplib.isofts.kiev.ua/handle/123456789/129221 |
| citation_txt |
Reactions of laser-ablated aluminum atoms with nitrogen during condensation at 10 K. Infrared spectra and density functional calculations for Alx Ny molecular / Lester Andrews, Mingfei Zhou, George V. Chertihin, William D. Bare, Yacine Hannachi // Физика низких температур. — 2000. — Т. 26, № 9-10. — С. 992-1000. — Бібліогр.: 30 назв. — англ. |
| work_keys_str_mv |
AT andrewslester reactionsoflaserablatedaluminumatomswithnitrogenduringcondensationat10kinfraredspectraanddensityfunctionalcalculationsforalxnymolecular AT zhoumingfei reactionsoflaserablatedaluminumatomswithnitrogenduringcondensationat10kinfraredspectraanddensityfunctionalcalculationsforalxnymolecular AT chertihingeorgev reactionsoflaserablatedaluminumatomswithnitrogenduringcondensationat10kinfraredspectraanddensityfunctionalcalculationsforalxnymolecular AT barewilliamd reactionsoflaserablatedaluminumatomswithnitrogenduringcondensationat10kinfraredspectraanddensityfunctionalcalculationsforalxnymolecular AT hannachiyacine reactionsoflaserablatedaluminumatomswithnitrogenduringcondensationat10kinfraredspectraanddensityfunctionalcalculationsforalxnymolecular |
| first_indexed |
2025-12-07T13:27:52Z |
| last_indexed |
2025-12-07T13:27:52Z |
| _version_ |
1850856253695197184 |