Reactions of laser-ablated aluminum atoms with nitrogen during condensation at 10 K. Infrared spectra and density functional calculations for Alx Ny molecular
Laser-ablated aluminum atoms react with dinitrogen on condensation at 10 K to form N₃ radicals and the subject molecules, which are identified by nitrogen isotopic substitution, further reactions on annealing, and comparison with isotopic frequencies computed by density functional theory. The major...
Збережено в:
| Опубліковано в: : | Физика низких температур |
|---|---|
| Дата: | 2000 |
| Автори: | , , , , |
| Формат: | Стаття |
| Мова: | Англійська |
| Опубліковано: |
Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України
2000
|
| Теми: | |
| Онлайн доступ: | https://nasplib.isofts.kiev.ua/handle/123456789/129221 |
| Теги: |
Додати тег
Немає тегів, Будьте першим, хто поставить тег для цього запису!
|
| Назва журналу: | Digital Library of Periodicals of National Academy of Sciences of Ukraine |
| Цитувати: | Reactions of laser-ablated aluminum atoms with nitrogen during condensation at 10 K. Infrared spectra and density functional calculations for Alx Ny molecular / Lester Andrews, Mingfei Zhou, George V. Chertihin, William D. Bare, Yacine Hannachi // Физика низких температур. — 2000. — Т. 26, № 9-10. — С. 992-1000. — Бібліогр.: 30 назв. — англ. |
Репозитарії
Digital Library of Periodicals of National Academy of Sciences of Ukraine| _version_ | 1862622447120941056 |
|---|---|
| author | Andrews, Lester Zhou, Mingfei Chertihin, George V. Bare, William D. Hannachi, Yacine |
| author_facet | Andrews, Lester Zhou, Mingfei Chertihin, George V. Bare, William D. Hannachi, Yacine |
| citation_txt | Reactions of laser-ablated aluminum atoms with nitrogen during condensation at 10 K. Infrared spectra and density functional calculations for Alx Ny molecular / Lester Andrews, Mingfei Zhou, George V. Chertihin, William D. Bare, Yacine Hannachi // Физика низких температур. — 2000. — Т. 26, № 9-10. — С. 992-1000. — Бібліогр.: 30 назв. — англ. |
| collection | DSpace DC |
| container_title | Физика низких температур |
| description | Laser-ablated aluminum atoms react with dinitrogen on condensation at 10 K to form N₃ radicals and the subject molecules, which are identified by nitrogen isotopic substitution, further reactions on annealing, and comparison with isotopic frequencies computed by density functional theory. The major AlN₃ product is identified from three fundamentals and a statistically mixed nitrogen isotopic octet pattern. The aluminum-rich Al₂N and Al₃N species are major products produced on annealing to allow diffusion and further reaction of trapped species. This work provides the first experimental evidence for molecular AlxNy species that may be involved in ceramic film growth.
|
| first_indexed | 2025-12-07T13:27:52Z |
| format | Article |
| fulltext | |
| id | nasplib_isofts_kiev_ua-123456789-129221 |
| institution | Digital Library of Periodicals of National Academy of Sciences of Ukraine |
| issn | 0132-6414 |
| language | English |
| last_indexed | 2025-12-07T13:27:52Z |
| publishDate | 2000 |
| publisher | Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України |
| record_format | dspace |
| spelling | Andrews, Lester Zhou, Mingfei Chertihin, George V. Bare, William D. Hannachi, Yacine 2018-01-17T19:59:43Z 2018-01-17T19:59:43Z 2000 Reactions of laser-ablated aluminum atoms with nitrogen during condensation at 10 K. Infrared spectra and density functional calculations for Alx Ny molecular / Lester Andrews, Mingfei Zhou, George V. Chertihin, William D. Bare, Yacine Hannachi // Физика низких температур. — 2000. — Т. 26, № 9-10. — С. 992-1000. — Бібліогр.: 30 назв. — англ. 0132-6414 PACS: 81.15.Fg, 82.30.Cf https://nasplib.isofts.kiev.ua/handle/123456789/129221 Laser-ablated aluminum atoms react with dinitrogen on condensation at 10 K to form N₃ radicals and the subject molecules, which are identified by nitrogen isotopic substitution, further reactions on annealing, and comparison with isotopic frequencies computed by density functional theory. The major AlN₃ product is identified from three fundamentals and a statistically mixed nitrogen isotopic octet pattern. The aluminum-rich Al₂N and Al₃N species are major products produced on annealing to allow diffusion and further reaction of trapped species. This work provides the first experimental evidence for molecular AlxNy species that may be involved in ceramic film growth. en Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України Физика низких температур Low-Temperature Physics and Chemistry in Cryomatrice Reactions of laser-ablated aluminum atoms with nitrogen during condensation at 10 K. Infrared spectra and density functional calculations for Alx Ny molecular Article published earlier |
| spellingShingle | Reactions of laser-ablated aluminum atoms with nitrogen during condensation at 10 K. Infrared spectra and density functional calculations for Alx Ny molecular Andrews, Lester Zhou, Mingfei Chertihin, George V. Bare, William D. Hannachi, Yacine Low-Temperature Physics and Chemistry in Cryomatrice |
| title | Reactions of laser-ablated aluminum atoms with nitrogen during condensation at 10 K. Infrared spectra and density functional calculations for Alx Ny molecular |
| title_full | Reactions of laser-ablated aluminum atoms with nitrogen during condensation at 10 K. Infrared spectra and density functional calculations for Alx Ny molecular |
| title_fullStr | Reactions of laser-ablated aluminum atoms with nitrogen during condensation at 10 K. Infrared spectra and density functional calculations for Alx Ny molecular |
| title_full_unstemmed | Reactions of laser-ablated aluminum atoms with nitrogen during condensation at 10 K. Infrared spectra and density functional calculations for Alx Ny molecular |
| title_short | Reactions of laser-ablated aluminum atoms with nitrogen during condensation at 10 K. Infrared spectra and density functional calculations for Alx Ny molecular |
| title_sort | reactions of laser-ablated aluminum atoms with nitrogen during condensation at 10 k. infrared spectra and density functional calculations for alx ny molecular |
| topic | Low-Temperature Physics and Chemistry in Cryomatrice |
| topic_facet | Low-Temperature Physics and Chemistry in Cryomatrice |
| url | https://nasplib.isofts.kiev.ua/handle/123456789/129221 |
| work_keys_str_mv | AT andrewslester reactionsoflaserablatedaluminumatomswithnitrogenduringcondensationat10kinfraredspectraanddensityfunctionalcalculationsforalxnymolecular AT zhoumingfei reactionsoflaserablatedaluminumatomswithnitrogenduringcondensationat10kinfraredspectraanddensityfunctionalcalculationsforalxnymolecular AT chertihingeorgev reactionsoflaserablatedaluminumatomswithnitrogenduringcondensationat10kinfraredspectraanddensityfunctionalcalculationsforalxnymolecular AT barewilliamd reactionsoflaserablatedaluminumatomswithnitrogenduringcondensationat10kinfraredspectraanddensityfunctionalcalculationsforalxnymolecular AT hannachiyacine reactionsoflaserablatedaluminumatomswithnitrogenduringcondensationat10kinfraredspectraanddensityfunctionalcalculationsforalxnymolecular |