Peculiarities of thermal expansion of quasi-two-dimensional organic conductor κ-(BEDT–TTF)₂Cu[N(CN)₂]Cl
Linear coefficient of thermal expansion α( T) of single crystal (BEDT–TTF)₂Cu[N(CN)₂]Cl was studied along the crystal layers using the method of precise capacitive dilatometry in the temperature range 2–285 K. It is positive in this direction over the entire temperature range. Anomalies of thermal e...
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| Published in: | Физика низких температур |
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| Date: | 2016 |
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| Language: | English |
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Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України
2016
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| Online Access: | https://nasplib.isofts.kiev.ua/handle/123456789/129299 |
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| Journal Title: | Digital Library of Periodicals of National Academy of Sciences of Ukraine |
| Cite this: | Peculiarities of thermal expansion of quasi-two-dimensional organic conductor κ-(BEDT–TTF)₂Cu[N(CN)₂]Cl / A.V. Dolbin, M.V. Khlistuck, V.B. Eselson, V.G. Gavrilko, N.A. Vinnikov, R.M. Basnukaeva, V.V. Danchuk, V.A. Konstantinov, Y. Nakazawa // Физика низких температур. — 2016. — Т. 42, № 9. — С. 1007-1012. — Бібліогр.: 24 назв. — англ. |
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Digital Library of Periodicals of National Academy of Sciences of Ukraine| _version_ | 1862718591675138048 |
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| author | Dolbin, A.V. Khlistuck, M.V. Eselson, V.B. Gavrilko, V.G. Vinnikov, N.A. Basnukaeva, R.M. Danchuk, V.V. Konstantinov, V.A. Nakazawa, Y. |
| author_facet | Dolbin, A.V. Khlistuck, M.V. Eselson, V.B. Gavrilko, V.G. Vinnikov, N.A. Basnukaeva, R.M. Danchuk, V.V. Konstantinov, V.A. Nakazawa, Y. |
| citation_txt | Peculiarities of thermal expansion of quasi-two-dimensional organic conductor κ-(BEDT–TTF)₂Cu[N(CN)₂]Cl / A.V. Dolbin, M.V. Khlistuck, V.B. Eselson, V.G. Gavrilko, N.A. Vinnikov, R.M. Basnukaeva, V.V. Danchuk, V.A. Konstantinov, Y. Nakazawa // Физика низких температур. — 2016. — Т. 42, № 9. — С. 1007-1012. — Бібліогр.: 24 назв. — англ. |
| collection | DSpace DC |
| container_title | Физика низких температур |
| description | Linear coefficient of thermal expansion α( T) of single crystal (BEDT–TTF)₂Cu[N(CN)₂]Cl was studied along the crystal layers using the method of precise capacitive dilatometry in the temperature range 2–285 K. It is positive in this direction over the entire temperature range. Anomalies of thermal expansion were observed at 29–30 K and 74–80 K. The anomaly near 30 K is, apparently, due to the transition between the paramagnetic phase and the antiferromagnetic insulator state. Peak of α( T) at 78 K corresponds to a phase transition related to orientational disordering of ethylene groups in dimers of BEDT–TTF. A broad maximum of α(T) in the temperature range 40–70 K, is apparently explained by fluctuations of charge within the dimers, and by spin fluctuations, which first increase with increasing temperature, and then decrease in process of thermal disordering of dimers.
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| first_indexed | 2025-12-07T18:15:59Z |
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| id | nasplib_isofts_kiev_ua-123456789-129299 |
| institution | Digital Library of Periodicals of National Academy of Sciences of Ukraine |
| issn | 0132-6414 |
| language | English |
| last_indexed | 2025-12-07T18:15:59Z |
| publishDate | 2016 |
| publisher | Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України |
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| spelling | Dolbin, A.V. Khlistuck, M.V. Eselson, V.B. Gavrilko, V.G. Vinnikov, N.A. Basnukaeva, R.M. Danchuk, V.V. Konstantinov, V.A. Nakazawa, Y. 2018-01-18T17:45:29Z 2018-01-18T17:45:29Z 2016 Peculiarities of thermal expansion of quasi-two-dimensional organic conductor κ-(BEDT–TTF)₂Cu[N(CN)₂]Cl / A.V. Dolbin, M.V. Khlistuck, V.B. Eselson, V.G. Gavrilko, N.A. Vinnikov, R.M. Basnukaeva, V.V. Danchuk, V.A. Konstantinov, Y. Nakazawa // Физика низких температур. — 2016. — Т. 42, № 9. — С. 1007-1012. — Бібліогр.: 24 назв. — англ. 0132-6414 PACS: 65.40.De, 63.22.Np https://nasplib.isofts.kiev.ua/handle/123456789/129299 Linear coefficient of thermal expansion α( T) of single crystal (BEDT–TTF)₂Cu[N(CN)₂]Cl was studied along the crystal layers using the method of precise capacitive dilatometry in the temperature range 2–285 K. It is positive in this direction over the entire temperature range. Anomalies of thermal expansion were observed at 29–30 K and 74–80 K. The anomaly near 30 K is, apparently, due to the transition between the paramagnetic phase and the antiferromagnetic insulator state. Peak of α( T) at 78 K corresponds to a phase transition related to orientational disordering of ethylene groups in dimers of BEDT–TTF. A broad maximum of α(T) in the temperature range 40–70 K, is apparently explained by fluctuations of charge within the dimers, and by spin fluctuations, which first increase with increasing temperature, and then decrease in process of thermal disordering of dimers. The authors thank Prof. A.I. Prokhvatilov for the fruitful
 discussion. en Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України Физика низких температур Низкоразмерные и неупорядоченные системы Peculiarities of thermal expansion of quasi-two-dimensional organic conductor κ-(BEDT–TTF)₂Cu[N(CN)₂]Cl Article published earlier |
| spellingShingle | Peculiarities of thermal expansion of quasi-two-dimensional organic conductor κ-(BEDT–TTF)₂Cu[N(CN)₂]Cl Dolbin, A.V. Khlistuck, M.V. Eselson, V.B. Gavrilko, V.G. Vinnikov, N.A. Basnukaeva, R.M. Danchuk, V.V. Konstantinov, V.A. Nakazawa, Y. Низкоразмерные и неупорядоченные системы |
| title | Peculiarities of thermal expansion of quasi-two-dimensional organic conductor κ-(BEDT–TTF)₂Cu[N(CN)₂]Cl |
| title_full | Peculiarities of thermal expansion of quasi-two-dimensional organic conductor κ-(BEDT–TTF)₂Cu[N(CN)₂]Cl |
| title_fullStr | Peculiarities of thermal expansion of quasi-two-dimensional organic conductor κ-(BEDT–TTF)₂Cu[N(CN)₂]Cl |
| title_full_unstemmed | Peculiarities of thermal expansion of quasi-two-dimensional organic conductor κ-(BEDT–TTF)₂Cu[N(CN)₂]Cl |
| title_short | Peculiarities of thermal expansion of quasi-two-dimensional organic conductor κ-(BEDT–TTF)₂Cu[N(CN)₂]Cl |
| title_sort | peculiarities of thermal expansion of quasi-two-dimensional organic conductor κ-(bedt–ttf)₂cu[n(cn)₂]cl |
| topic | Низкоразмерные и неупорядоченные системы |
| topic_facet | Низкоразмерные и неупорядоченные системы |
| url | https://nasplib.isofts.kiev.ua/handle/123456789/129299 |
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