Magnetic phase transitions in the system La₁₋xBixMnO₃₊λ
The crystal structure and magnetic properties of the La₁₋xBixMnO₃₊λ system (0⩽x⩽1;λ⩽0.08) are studied as functions of the oxygen and bismuth contents. In oxidized samples La₁₋xBixMnO₃₊λ a phase transition from a ferromagnetic state (rhombohedric phase) to a state of the spin glass type (quasitetrago...
Збережено в:
| Опубліковано в: : | Физика низких температур |
|---|---|
| Дата: | 2002 |
| Автори: | , , , |
| Формат: | Стаття |
| Мова: | Англійська |
| Опубліковано: |
Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України
2002
|
| Теми: | |
| Онлайн доступ: | https://nasplib.isofts.kiev.ua/handle/123456789/130236 |
| Теги: |
Додати тег
Немає тегів, Будьте першим, хто поставить тег для цього запису!
|
| Назва журналу: | Digital Library of Periodicals of National Academy of Sciences of Ukraine |
| Цитувати: | Magnetic phase transitions in the system La₁₋xBixMnO₃₊λ / I.O. Troyanchuk, O.S. Mantytskaja, H.Szymczak, M.Yu. Shvedun // Физика низких температур. — 2002. — Т. 28, № 7. — С. 790-795. — Бібліогр.: 28 назв. — англ. |
Репозитарії
Digital Library of Periodicals of National Academy of Sciences of Ukraine| _version_ | 1862577374701289472 |
|---|---|
| author | Troyanchuk, I.O. Mantytskaja, O.S. Szymczak, H. Shvedun, M.Yu. |
| author_facet | Troyanchuk, I.O. Mantytskaja, O.S. Szymczak, H. Shvedun, M.Yu. |
| citation_txt | Magnetic phase transitions in the system La₁₋xBixMnO₃₊λ / I.O. Troyanchuk, O.S. Mantytskaja, H.Szymczak, M.Yu. Shvedun // Физика низких температур. — 2002. — Т. 28, № 7. — С. 790-795. — Бібліогр.: 28 назв. — англ. |
| collection | DSpace DC |
| container_title | Физика низких температур |
| description | The crystal structure and magnetic properties of the La₁₋xBixMnO₃₊λ system (0⩽x⩽1;λ⩽0.08) are studied as functions of the oxygen and bismuth contents. In oxidized samples La₁₋xBixMnO₃₊λ a phase transition from a ferromagnetic state (rhombohedric phase) to a state of the spin glass type (quasitetragonal phase) is observed with increase of the bismuth concentration. The reduced samples La₁₋xBixMnO₃ are weak ferromagnets down to x⩽0.6 and then transform into a ferromagnetic state. It is supposed that the Bi³⁺ ions stabilize the dx2−y2 orbitals in the nearest Mn³⁺ ions whereas the dz2 orbitals of the La³⁺ ions are stabilized. The orbitally disordered phases and dx2−y2-orbitally ordered phases are ferromagnetic, the dz2-orbitally ordered phases show antiferromagnetic ordering, and the state of the orbital glass type corresponds to a state of the spin glass type.
The crystal structure and magnetic properties of the La₁₋xBixMnO₃₊λ system (0⩽x⩽1;λ⩽0.08) are studied as functions of the oxygen and bismuth contents. In oxidized samples La₁₋xBixMnO₃₊λ a phase transition from a ferromagnetic state (rhombohedric phase) to a state of the spin glass type (quasitetragonal phase) is observed with increase of the bismuth concentration. The reduced samples La₁₋xBixMnO₃ are weak ferromagnets down to x⩽0.6 and then transform into a ferromagnetic state. It is supposed that the Bi³⁺ ions stabilize the dx2−y2 orbitals in the nearest Mn³⁺ ions whereas the dz2 orbitals of the La³⁺ ions are stabilized. The orbitally disordered phases and dx2−y2-orbitally ordered phases are ferromagnetic, the dz2-orbitally ordered phases show antiferromagnetic ordering, and the state of the orbital glass type corresponds to a state of the spin glass type.
|
| first_indexed | 2025-11-26T15:23:23Z |
| format | Article |
| fulltext | |
| id | nasplib_isofts_kiev_ua-123456789-130236 |
| institution | Digital Library of Periodicals of National Academy of Sciences of Ukraine |
| issn | 0132-6414 |
| language | English |
| last_indexed | 2025-11-26T15:23:23Z |
| publishDate | 2002 |
| publisher | Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України |
| record_format | dspace |
| spelling | Troyanchuk, I.O. Mantytskaja, O.S. Szymczak, H. Shvedun, M.Yu. 2018-02-09T10:59:15Z 2018-02-09T10:59:15Z 2002 Magnetic phase transitions in the system La₁₋xBixMnO₃₊λ / I.O. Troyanchuk, O.S. Mantytskaja, H.Szymczak, M.Yu. Shvedun // Физика низких температур. — 2002. — Т. 28, № 7. — С. 790-795. — Бібліогр.: 28 назв. — англ. 0132-6414 PACS: 72.15.Gd, 75.30.Kz, 75.70.Pa https://nasplib.isofts.kiev.ua/handle/123456789/130236 The crystal structure and magnetic properties of the La₁₋xBixMnO₃₊λ system (0⩽x⩽1;λ⩽0.08) are studied as functions of the oxygen and bismuth contents. In oxidized samples La₁₋xBixMnO₃₊λ a phase transition from a ferromagnetic state (rhombohedric phase) to a state of the spin glass type (quasitetragonal phase) is observed with increase of the bismuth concentration. The reduced samples La₁₋xBixMnO₃ are weak ferromagnets down to x⩽0.6 and then transform into a ferromagnetic state. It is supposed that the Bi³⁺ ions stabilize the dx2−y2 orbitals in the nearest Mn³⁺ ions whereas the dz2 orbitals of the La³⁺ ions are stabilized. The orbitally disordered phases and dx2−y2-orbitally ordered phases are ferromagnetic, the dz2-orbitally ordered phases show antiferromagnetic ordering, and the state of the orbital glass type corresponds to a state of the spin glass type. The crystal structure and magnetic properties of the La₁₋xBixMnO₃₊λ system (0⩽x⩽1;λ⩽0.08) are studied as functions of the oxygen and bismuth contents. In oxidized samples La₁₋xBixMnO₃₊λ a phase transition from a ferromagnetic state (rhombohedric phase) to a state of the spin glass type (quasitetragonal phase) is observed with increase of the bismuth concentration. The reduced samples La₁₋xBixMnO₃ are weak ferromagnets down to x⩽0.6 and then transform into a ferromagnetic state. It is supposed that the Bi³⁺ ions stabilize the dx2−y2 orbitals in the nearest Mn³⁺ ions whereas the dz2 orbitals of the La³⁺ ions are stabilized. The orbitally disordered phases and dx2−y2-orbitally ordered phases are ferromagnetic, the dz2-orbitally ordered phases show antiferromagnetic ordering, and the state of the orbital glass type corresponds to a state of the spin glass type. This work was supported in part by the Belarus
 Fund of Basic Research (Project F00-223). en Фізико-технічний інститут низьких температур ім. Б.І. Вєркіна НАН України Физика низких температур Дефекты в кристаллах Magnetic phase transitions in the system La₁₋xBixMnO₃₊λ Article published earlier |
| spellingShingle | Magnetic phase transitions in the system La₁₋xBixMnO₃₊λ Troyanchuk, I.O. Mantytskaja, O.S. Szymczak, H. Shvedun, M.Yu. Дефекты в кристаллах |
| title | Magnetic phase transitions in the system La₁₋xBixMnO₃₊λ |
| title_full | Magnetic phase transitions in the system La₁₋xBixMnO₃₊λ |
| title_fullStr | Magnetic phase transitions in the system La₁₋xBixMnO₃₊λ |
| title_full_unstemmed | Magnetic phase transitions in the system La₁₋xBixMnO₃₊λ |
| title_short | Magnetic phase transitions in the system La₁₋xBixMnO₃₊λ |
| title_sort | magnetic phase transitions in the system la₁₋xbixmno₃₊λ |
| topic | Дефекты в кристаллах |
| topic_facet | Дефекты в кристаллах |
| url | https://nasplib.isofts.kiev.ua/handle/123456789/130236 |
| work_keys_str_mv | AT troyanchukio magneticphasetransitionsinthesystemla1xbixmno3λ AT mantytskajaos magneticphasetransitionsinthesystemla1xbixmno3λ AT szymczakh magneticphasetransitionsinthesystemla1xbixmno3λ AT shvedunmyu magneticphasetransitionsinthesystemla1xbixmno3λ |