Electronic structure of Ni-Mn-Ga magnetic shape memory alloy studied be EELS method

The evolution of 3d electronic structure associated with the martensitic transformation and ferromagnetic transition in non-stoichiometric Ni₂MnGa alloy possessing the shape magnetic memory were studied by electron-energy loss spectroscopy (EELS) and with theoretical modeling methods. The EELS spect...

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Published in:Functional Materials
Date:2006
Main Authors: Ochoa-Gamboa, R., Flores-Zuniga, H., Espinosa-Magana, F., Rios-Jara, D., Glavatskyy, I., Glavatska, N.
Format: Article
Language:English
Published: НТК «Інститут монокристалів» НАН України 2006
Online Access:https://nasplib.isofts.kiev.ua/handle/123456789/134178
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Journal Title:Digital Library of Periodicals of National Academy of Sciences of Ukraine
Cite this:Electronic structure of Ni-Mn-Ga magnetic shape memory alloy studied be EELS method / R.Ochoa-Gamboa, H.Flores-Zuniga, F.Espinosa-Magana, D.Rios-Jara, I.Glavatskyy, N.Glavatska // Functional Materials. — 2006. — Т. 13, № 3. — С. 468-473. — Бібліогр.: 22 назв. — англ.

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Digital Library of Periodicals of National Academy of Sciences of Ukraine
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author Ochoa-Gamboa, R.
Flores-Zuniga, H.
Espinosa-Magana, F.
Rios-Jara, D.
Glavatskyy, I.
Glavatska, N.
author_facet Ochoa-Gamboa, R.
Flores-Zuniga, H.
Espinosa-Magana, F.
Rios-Jara, D.
Glavatskyy, I.
Glavatska, N.
citation_txt Electronic structure of Ni-Mn-Ga magnetic shape memory alloy studied be EELS method / R.Ochoa-Gamboa, H.Flores-Zuniga, F.Espinosa-Magana, D.Rios-Jara, I.Glavatskyy, N.Glavatska // Functional Materials. — 2006. — Т. 13, № 3. — С. 468-473. — Бібліогр.: 22 назв. — англ.
collection DSpace DC
container_title Functional Materials
description The evolution of 3d electronic structure associated with the martensitic transformation and ferromagnetic transition in non-stoichiometric Ni₂MnGa alloy possessing the shape magnetic memory were studied by electron-energy loss spectroscopy (EELS) and with theoretical modeling methods. The EELS spectra of Ni-Mn-Ga crystals have been obtained under in-situ heating to study the electron structure of ferromagnetic (FM) martensite, FM austenite and paramagnetic austenite. When considering the EELS spectra, the total white lines intensity L₂₃ = L₂ + L₃ as well as as well as the L₃/L₂ ratio and conclusions have been drawn on the occupancy of the 3d state fromAs L₂₃ reflects the unoccupied density of states in 3d bands, these results indicate that no charge transfer has taken place during martensitic transformation and changes in the magnetic dipole moments at phase transitions. The experimental results have shown that the magnetic dipole moment on Ni atoms decreases at the reverse martensitic transformationwhile it increases on Mn, and the charge is observed to be redistributed between Mn and Ni in agreement with ab-initio numerical calculations.
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language English
last_indexed 2025-12-01T08:11:37Z
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publisher НТК «Інститут монокристалів» НАН України
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spelling Ochoa-Gamboa, R.
Flores-Zuniga, H.
Espinosa-Magana, F.
Rios-Jara, D.
Glavatskyy, I.
Glavatska, N.
2018-06-12T17:08:50Z
2018-06-12T17:08:50Z
2006
Electronic structure of Ni-Mn-Ga magnetic shape memory alloy studied be EELS method / R.Ochoa-Gamboa, H.Flores-Zuniga, F.Espinosa-Magana, D.Rios-Jara, I.Glavatskyy, N.Glavatska // Functional Materials. — 2006. — Т. 13, № 3. — С. 468-473. — Бібліогр.: 22 назв. — англ.
1027-5495
https://nasplib.isofts.kiev.ua/handle/123456789/134178
The evolution of 3d electronic structure associated with the martensitic transformation and ferromagnetic transition in non-stoichiometric Ni₂MnGa alloy possessing the shape magnetic memory were studied by electron-energy loss spectroscopy (EELS) and with theoretical modeling methods. The EELS spectra of Ni-Mn-Ga crystals have been obtained under in-situ heating to study the electron structure of ferromagnetic (FM) martensite, FM austenite and paramagnetic austenite. When considering the EELS spectra, the total white lines intensity L₂₃ = L₂ + L₃ as well as as well as the L₃/L₂ ratio and conclusions have been drawn on the occupancy of the 3d state fromAs L₂₃ reflects the unoccupied density of states in 3d bands, these results indicate that no charge transfer has taken place during martensitic transformation and changes in the magnetic dipole moments at phase transitions. The experimental results have shown that the magnetic dipole moment on Ni atoms decreases at the reverse martensitic transformationwhile it increases on Mn, and the charge is observed to be redistributed between Mn and Ni in agreement with ab-initio numerical calculations.
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НТК «Інститут монокристалів» НАН України
Functional Materials
Electronic structure of Ni-Mn-Ga magnetic shape memory alloy studied be EELS method
EELS Дослідження електронної структури сплаву Ni-Mn-Ga з ефектом магнітної пам'яті форми
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spellingShingle Electronic structure of Ni-Mn-Ga magnetic shape memory alloy studied be EELS method
Ochoa-Gamboa, R.
Flores-Zuniga, H.
Espinosa-Magana, F.
Rios-Jara, D.
Glavatskyy, I.
Glavatska, N.
title Electronic structure of Ni-Mn-Ga magnetic shape memory alloy studied be EELS method
title_alt EELS Дослідження електронної структури сплаву Ni-Mn-Ga з ефектом магнітної пам'яті форми
title_full Electronic structure of Ni-Mn-Ga magnetic shape memory alloy studied be EELS method
title_fullStr Electronic structure of Ni-Mn-Ga magnetic shape memory alloy studied be EELS method
title_full_unstemmed Electronic structure of Ni-Mn-Ga magnetic shape memory alloy studied be EELS method
title_short Electronic structure of Ni-Mn-Ga magnetic shape memory alloy studied be EELS method
title_sort electronic structure of ni-mn-ga magnetic shape memory alloy studied be eels method
url https://nasplib.isofts.kiev.ua/handle/123456789/134178
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