Chemical synthesis of nanocrystalline Ni-Zn ferrites and their magnetic characteristics

Nanocrystalline Ni₁₋ₓZnₓFe₂O₄ powders were synthesized by the citrate precursor method, and the reaction sequence during the process was examiden. Studied of the reaction sequence showed that a NiFe2O4 phase was developed as soon as the metal citric acids were thermally decomposed. In the case of Zn...

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Published in:Functional Materials
Date:2006
Main Authors: Jong-Chul Lee, Joon-Hyung Lee, Jeong-Joo Kim, Golub, V., Sang-Hee Cho, O`Connor, C.J., Caruntu, D., Cushing, B.
Format: Article
Language:English
Published: НТК «Інститут монокристалів» НАН України 2006
Online Access:https://nasplib.isofts.kiev.ua/handle/123456789/134187
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Journal Title:Digital Library of Periodicals of National Academy of Sciences of Ukraine
Cite this:Chemical synthesis of nanocrystalline Ni-Zn ferrites and their magnetic characteristics / Jong-Chul Lee, D. Caruntu, Joon-Hyung Lee, Jeong-Joo Kim, B. Cushing, V. Golub, Sang-Hee Cho, C.J.O`Connor // Functional Materials. — 2006. — Т. 13, № 3. — С. 447-456. — Бібліогр.: 24 назв. — англ.

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Digital Library of Periodicals of National Academy of Sciences of Ukraine
id nasplib_isofts_kiev_ua-123456789-134187
record_format dspace
spelling Jong-Chul Lee
Joon-Hyung Lee
Jeong-Joo Kim
Golub, V.
Sang-Hee Cho
O`Connor, C.J.
Caruntu, D.
Cushing, B.
2018-06-12T17:38:05Z
2018-06-12T17:38:05Z
2006
Chemical synthesis of nanocrystalline Ni-Zn ferrites and their magnetic characteristics / Jong-Chul Lee, D. Caruntu, Joon-Hyung Lee, Jeong-Joo Kim, B. Cushing, V. Golub, Sang-Hee Cho, C.J.O`Connor // Functional Materials. — 2006. — Т. 13, № 3. — С. 447-456. — Бібліогр.: 24 назв. — англ.
1027-5495
https://nasplib.isofts.kiev.ua/handle/123456789/134187
Nanocrystalline Ni₁₋ₓZnₓFe₂O₄ powders were synthesized by the citrate precursor method, and the reaction sequence during the process was examiden. Studied of the reaction sequence showed that a NiFe2O4 phase was developed as soon as the metal citric acids were thermally decomposed. In the case of ZnFe₂O₄, however, ZnO and Fe₂O₃ were produced first when the metal citric acids were decomposed at low temperature. A single phase of ZnFe₂O₄ was subsequently obtained when a heat treatment was conducted at 500°C for 2 h. On the other hand, in order to examine the effect of particle size on magnetic characteristics of Ni-Zn ferrites, nanocrystalline Ni₁₋ₓZnₓFe₂O₄ powders with particle sizes of approximately 7, 25 and 100 nm were prepared by coprecipitation and citrate precursor methods. The magnetic characteristics of the ultrafine (7 nm) and coarse (100 nm) nanocrystalline ferrites showed differences. These differences are attributed to cation disordering at the surfaces of particles, wich becomes increasingly dominant as the particle size decreases.
en
НТК «Інститут монокристалів» НАН України
Functional Materials
Chemical synthesis of nanocrystalline Ni-Zn ferrites and their magnetic characteristics
Хімічний синтез нанокристалічних Ni-Zn феритів та їхні магнітні характеристики
Article
published earlier
institution Digital Library of Periodicals of National Academy of Sciences of Ukraine
collection DSpace DC
title Chemical synthesis of nanocrystalline Ni-Zn ferrites and their magnetic characteristics
spellingShingle Chemical synthesis of nanocrystalline Ni-Zn ferrites and their magnetic characteristics
Jong-Chul Lee
Joon-Hyung Lee
Jeong-Joo Kim
Golub, V.
Sang-Hee Cho
O`Connor, C.J.
Caruntu, D.
Cushing, B.
title_short Chemical synthesis of nanocrystalline Ni-Zn ferrites and their magnetic characteristics
title_full Chemical synthesis of nanocrystalline Ni-Zn ferrites and their magnetic characteristics
title_fullStr Chemical synthesis of nanocrystalline Ni-Zn ferrites and their magnetic characteristics
title_full_unstemmed Chemical synthesis of nanocrystalline Ni-Zn ferrites and their magnetic characteristics
title_sort chemical synthesis of nanocrystalline ni-zn ferrites and their magnetic characteristics
author Jong-Chul Lee
Joon-Hyung Lee
Jeong-Joo Kim
Golub, V.
Sang-Hee Cho
O`Connor, C.J.
Caruntu, D.
Cushing, B.
author_facet Jong-Chul Lee
Joon-Hyung Lee
Jeong-Joo Kim
Golub, V.
Sang-Hee Cho
O`Connor, C.J.
Caruntu, D.
Cushing, B.
publishDate 2006
language English
container_title Functional Materials
publisher НТК «Інститут монокристалів» НАН України
format Article
title_alt Хімічний синтез нанокристалічних Ni-Zn феритів та їхні магнітні характеристики
description Nanocrystalline Ni₁₋ₓZnₓFe₂O₄ powders were synthesized by the citrate precursor method, and the reaction sequence during the process was examiden. Studied of the reaction sequence showed that a NiFe2O4 phase was developed as soon as the metal citric acids were thermally decomposed. In the case of ZnFe₂O₄, however, ZnO and Fe₂O₃ were produced first when the metal citric acids were decomposed at low temperature. A single phase of ZnFe₂O₄ was subsequently obtained when a heat treatment was conducted at 500°C for 2 h. On the other hand, in order to examine the effect of particle size on magnetic characteristics of Ni-Zn ferrites, nanocrystalline Ni₁₋ₓZnₓFe₂O₄ powders with particle sizes of approximately 7, 25 and 100 nm were prepared by coprecipitation and citrate precursor methods. The magnetic characteristics of the ultrafine (7 nm) and coarse (100 nm) nanocrystalline ferrites showed differences. These differences are attributed to cation disordering at the surfaces of particles, wich becomes increasingly dominant as the particle size decreases.
issn 1027-5495
url https://nasplib.isofts.kiev.ua/handle/123456789/134187
citation_txt Chemical synthesis of nanocrystalline Ni-Zn ferrites and their magnetic characteristics / Jong-Chul Lee, D. Caruntu, Joon-Hyung Lee, Jeong-Joo Kim, B. Cushing, V. Golub, Sang-Hee Cho, C.J.O`Connor // Functional Materials. — 2006. — Т. 13, № 3. — С. 447-456. — Бібліогр.: 24 назв. — англ.
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first_indexed 2025-12-07T17:10:19Z
last_indexed 2025-12-07T17:10:19Z
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